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1.发明授权公开(公告)号：US09133297B2
公开(公告)日：2015-09-15
申请号：US11434286
申请日：2006-05-15
申请人： Bi Le-Khac , Karl W. Haider , Ramesh Subramanian , Charles A. Gambino , James Edward Kassner , Hu Xiaowei , William J. Sim
发明人： Bi Le-Khac , Karl W. Haider , Ramesh Subramanian , Charles A. Gambino , James Edward Kassner , Hu Xiaowei , William J. Sim
IPC分类号： C08G18/79 , C08G18/81 , C08G18/42 , C08G18/68 , C08G18/08 , C09D175/16 , C08F2/48 , C08G18/66
CPC分类号： C08G18/0823 , C08G18/4252 , C08G18/6625 , C08G18/68 , C08G18/792 , C08G18/8175 , C09D175/16
摘要： Provided are ultraviolet (UV)-curable polyols and polyurethane compositions made by reacting the inventive polyol with an isocyanate. The inventive ultraviolet (UV)-curable polyol is made by co-polymerizing an alkylene oxide, an unsaturated carboxylic acid or anhydride and a hydroxy functional compound in the presence of a double metal cyanide (DMC) complex catalyst such that the polyol has an ultra-low level of unsaturation. The inventive polyols may be used to produce prepolymers, which in turn may be useful in making thin films which in turn may provide such items as medical examination gloves and scientific gloves. The inventive ultraviolet (UV)-curable polyurethane compositions may also find use in or as coatings, adhesives, sealants, elastomers and the like.
摘要翻译： 提供紫外线（UV）可固化的多元醇和通过使本发明多元醇与异氰酸酯反应制备的聚氨酯组合物。 本发明的紫外线（UV）可固化多元醇是通过在双金属氰化物（DMC）配位催化剂的存在下使烯化氧，不饱和羧酸或酸酐和羟基官能化合物共聚而制得的，使得多元醇具有超 低于不饱和度。 本发明的多元醇可以用于制备预聚物，其又可用于制备薄膜，其又可以提供诸如医疗检查手套和科学手套的物品。 本发明的紫外线（UV）可固化聚氨酯组合物也可用于或作为涂料，粘合剂，密封剂，弹性体等。
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公开(公告)号：US07041708B2
公开(公告)日：2006-05-09
申请号：US10976684
申请日：2004-10-29
CPC分类号： C08G18/6795 , C08G18/4866 , C08G18/792 , C09D175/16 , Y10T428/2896 , Y10T428/31551 , Y10T428/31569 , Y10T428/31573
摘要： Ultraviolet (UV)-curable polyurethane compositions are provided which are made by reacting an isocyanate with an ultraviolet (UV)-curable polyol that is made by co-polymerizing an alkylene oxide, an unsaturated carboxylic acid or anhydride and a hydroxy functional compound and which has an ultra-low level of unsaturation. The inventive ultraviolet (UV)-curable polyurethane compositions may find use in or as coatings, adhesives, sealants, elastomers and the like.
摘要翻译： 提供了紫外线（UV）可固化的聚氨酯组合物，其通过使异氰酸酯与通过使烯化氧，不饱和羧酸或酸酐和羟基官能化合物共聚而制备的紫外线（UV）可固化的多元醇 具有超低的不饱和度。 本发明的紫外线（UV）可固化聚氨酯组合物可用于或作为涂料，粘合剂，密封剂，弹性体等。
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公开(公告)号：US20130023599A1
公开(公告)日：2013-01-24
申请号：US13627127
申请日：2012-09-26
申请人： Yu-Ling Hsiao , Richard G. Skorpenske , Bryan D. Kaushiva , Kenneth G. McDaniel , Jose F. Pazos , Stanley L. Hager , Karl W. Haider
发明人： Yu-Ling Hsiao , Richard G. Skorpenske , Bryan D. Kaushiva , Kenneth G. McDaniel , Jose F. Pazos , Stanley L. Hager , Karl W. Haider
IPC分类号： C07C51/367 , C08G18/68
CPC分类号： C08G18/4891 , C08G18/4866 , C08G2101/0008 , C08G2101/005
摘要： The present invention provides polyurethane foams and elastomers made with an alkoxylated vegetable oil hydroxylate replacing at least a portion of the typically used petroleum-based polyol(s). Also provided are processes for making the inventive foams and elastomers and for making alkoxylated vegetable oil hydroxylates. The alkoxylated vegetable oil hydroxylates are environmentally-friendly, bio-based polyols which advantageously also offer the potential of improved hydrophobicity in polyurethane foams and elastomers. The inventive polyurethane foams and elastomers may find use in a wide variety of products such as automobile interior parts, polyurethane structural foams, floor coatings and athletic running tracks.
摘要翻译： 本发明提供用烷氧基化植物油羟基化物制备的聚氨酯泡沫和弹性体，代替至少一部分通常使用的石油基多元醇。 还提供了制备本发明的泡沫和弹性体以及用于制备烷氧基化植物油羟基化物的方法。 烷氧基化植物油羟基化物是环境友好的基于生物的多元醇，其有利地还提供聚氨酯泡沫和弹性体中改善的疏水性的潜力。 本发明的聚氨酯泡沫和弹性体可以用于各种各样的产品，例如汽车内部部件，聚氨酯结构泡沫，地板涂料和运动跑道。
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4.发明申请公开(公告)号：US20100331517A1
公开(公告)日：2010-12-30
申请号：US12880231
申请日：2010-09-13
IPC分类号： C08G64/02
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 Wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001Wt的存在下。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。
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5.发明授权公开(公告)号：US06762214B1
公开(公告)日：2004-07-13
申请号：US10391312
申请日：2003-03-18
IPC分类号： C08G1828
CPC分类号： C08G18/482 , C08G18/4018 , C08G18/5024 , C08G65/2627 , C08G65/2648 , C08G2101/0025 , C08G2101/005
摘要： The present invention relates to a process for the preparation of rigid foams comprising reacting a polyisocyanate component with an isocyanate-reactive component in the present of a blowing agent. Suitable isocyanate-reactive components for the presently claimed invention comprises polyether polyols having an OH number of from 200 to 800 and containing from 3 to 8 hydroxyl groups wherein the level of alkalinity present in the polyether polyol is equivalent to a hydroxide ion level of from about 0.006% to about 0.21% by weight.
摘要翻译： 本发明涉及一种用于制备刚性泡沫的方法，包括使多异氰酸酯组分与发泡剂中的异氰酸酯反应性组分反应。 用于本发明要求保护的发明的合适的异氰酸酯反应性组分包含OH数为200至800并包含3至8个羟基的聚醚多元醇，其中存在于聚醚多元醇中的碱度水平等于氢氧根离子水平为约 0.006重量％至约0.21重量％。
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6.发明授权Composition and process for preparation of thermoplastic polyurethanes (TPU based on a polybutadiene soft segment) 失效用于制备热塑性聚氨酯的组合物和方法（基于聚丁二烯软链段的TPU）
公开(公告)号：US06166166A
公开(公告)日：2000-12-26
申请号：US140208
申请日：1998-08-26
申请人： Ronald P. Taylor , Jack C. Chan , Karl W. Haider , E. Haakan Jonsson , Uli W. Franz , Mark A. Peters
发明人： Ronald P. Taylor , Jack C. Chan , Karl W. Haider , E. Haakan Jonsson , Uli W. Franz , Mark A. Peters
CPC分类号： C08G18/6204 , C08G18/0895 , C08G18/10 , C08G18/3206
摘要： A process for making a thermoplastic polyurethane material comprising the steps of casting an NCO-terminated prepolymer with 1,4-butanediol to form a casting composition; extruding the casting composition to form at least one strand of a polyurethane elastomer; pelletizing the at least one strand of said polyurethane elastomer to form at least one pellet; and processing the at least one pellet to form a thermoplastic article.
摘要翻译： 一种制备热塑性聚氨酯材料的方法，包括以下步骤：用1,4-丁二醇浇铸NCO封端的预聚物以形成铸塑组合物; 挤出所述浇铸组合物以形成至少一股聚氨酯弹性体链; 造粒所述聚氨酯弹性体的至少一股，形成至少一个丸粒; 以及处理所述至少一个颗粒以形成热塑性制品。
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公开(公告)号：US20160347900A1
公开(公告)日：2016-12-01
申请号：US15166948
申请日：2016-05-27
申请人： Matthew BECKER , Robert A. Weiss , Zachary Kurtiss Zander , Don S. Wardius , Karl W. Haider , Bruce D. Lawrey
发明人： Matthew BECKER , Robert A. Weiss , Zachary Kurtiss Zander , Don S. Wardius , Karl W. Haider , Bruce D. Lawrey
CPC分类号： C08G18/10 , C08G18/0814 , C08G18/0828 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/603 , C08G18/7671 , C08G18/3206 , C08G18/3857 , C08G18/3855
摘要： In one or more embodiments, the present invention provides a novel approach to the addition of plasticizers for softening TPUs, i.e., lowering the durometer and the melt viscosity. This approach involves incorporating bonded sulfonate groups with quaternary ammonium counterions into the TPU. In one or more embodiments of the present invention, the softening of TPU is achieved by incorporating an ionic diol, such as N,N-bis (2-hydoxyethyl)-2-aminoethane-sulfonic acid (BES), coupled with various bulky alkyl ammonium cations, during the chain extension step of the TPU synthesis. It is believed that that steric hindrance of the bulky quaternary ammonium groups weakens the dipole-dipole interactions of the sulfonate groups and/or lowers the crystallinity of the hard block, thereby creating additional free volume that softens the polymer and lowers the melt viscosity.
摘要翻译： 在一个或多个实施方案中，本发明提供了添加用于软化TPU的增塑剂的新方法，即降低硬度和熔融粘度。 这种方法包括将键合的磺酸盐基团与季铵抗衡离子结合到TPU中。 在本发明的一个或多个实施方案中，TPU的软化通过加入离子二醇，例如N，N-双（2-羟乙基）-2-氨基乙磺酸（BES），与各种大体积烷基 在TPU合成的扩链步骤期间，铵阳离子。 据信大体积季铵基团的空间位阻削弱了磺酸盐基团的偶极 - 偶极相互作用和/或降低了硬块的结晶度，从而产生了使聚合物软化并降低了熔体粘度的额外的自由体积。
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公开(公告)号：US07834082B2
公开(公告)日：2010-11-16
申请号：US11654173
申请日：2007-01-17
申请人： Karl W. Haider , James Y. J. Chung , Jeffrey F. Dormish , Rick V. Starcher , Irene L. Yano , Edwin R. Hortelano
发明人： Karl W. Haider , James Y. J. Chung , Jeffrey F. Dormish , Rick V. Starcher , Irene L. Yano , Edwin R. Hortelano
IPC分类号： C08L83/00
摘要： A method of making a polyether-polydialkylsiloxane block copolymer is provided. The method comprises providing a mixture comprising at least one alkylene oxide and at least one silanol-terminated polydialkylsiloxane; and polymerizing the mixture in the presence of a double metal cyanide complex catalyst, and optionally in the presence of an aprotic solvent and/or an antioxidant. A polyether-polydialkylsiloxane block copolymer having a molecular weight of 150-50,000 g/mole and having a polydispersity index of 1.0 to 1.5 made by the above method is also provided.
摘要翻译： 提供了制备聚醚 - 聚二烷基硅氧烷嵌段共聚物的方法。 该方法包括提供包含至少一种烯化氧和至少一种硅烷醇封端的聚二烷基硅氧烷的混合物; 并在双金属氰化物配合物催化剂的存在下，任选地在非质子溶剂和/或抗氧化剂的存在下使混合物聚合。 还提供了通过上述方法制备的分子量为150-50,000g / mol并具有1.0至1.5的多分散指数的聚醚 - 聚二烷基硅氧烷嵌段共聚物。
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9.发明申请Process for the production of polyoxyalkylene containing polyols from phenol condensation products 有权用于由苯酚缩合产物生产含聚氧化烯的多元醇的方法公开(公告)号：US20070299234A1
公开(公告)日：2007-12-27
申请号：US11473686
申请日：2006-06-23
申请人： Karl W. Haider , Stanley L. Hager , Jack R. Reese
发明人： Karl W. Haider , Stanley L. Hager , Jack R. Reese
CPC分类号： C08G65/2663
摘要： This invention relates to a one-stage process for the production of polyoxyalkylene containing polyols having equivalent weights of about 150 to about 6000 and functionalities of about 2 to 8. The process comprises (1) mixing (a) an organic compound having a hydroxyl functionality of about 2 to about 8 and an equivalent weight of about 35 to about 575, with (b) a hydroxyl functional compound having an equivalent weight of about 100 to about 6000 and a functionality of about 2 to 8; and (2) alkoxylating the mixture with (c) one or more alkylene oxides, in the presence of (d) one or more double metal cyanide catalysts. Suitable compounds to be used as (a) the organic compound having a hydroxyl functionality of about 2 to about 8 and an equivalent weight of about 35 to about 575 in the present invention include bisphenol-A, Bisphenol TMC, tetrabromobisphenol A, and novolak phenolic resins.
摘要翻译： 本发明涉及用于生产具有约150至约6000当量和约2至8的官能度的含聚氧化烯的多元醇的一步法。该方法包括（1）将（a）具有羟基官能度的有机化合物 约2至约8，当量为约35至约575，和（b）当量为约100至约6000，官能度为约2至8的羟基官能化合物; 和（2）在（d）一种或多种双金属氰化物催化剂的存在下，使（c）一种或多种烯化氧烷化该混合物。 用作本发明中（a）羟基官能度为约2至约8，当量约35至约575的有机化合物的合适化合物包括双酚A，双酚TMC，四溴双酚A和酚醛清漆酚 树脂。
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公开(公告)号：US06869543B2
公开(公告)日：2005-03-22
申请号：US10372361
申请日：2003-02-21
CPC分类号： C08G18/5027 , C08G18/4018 , C08G65/2621 , C08G65/2627 , C08G65/30 , C08G2101/0025 , C08L2205/05
摘要： Clear, amine-initiated polyether polyols are made by epoxidizing an amine in the presence of an alkali metal hydroxide catalyst. By reducing the amount of catalyst used during the polyol synthesis and by adding the catalyst after between 5 and 30% of the total amount of at least one alkylene oxide has been added, after lactic acid neutralization, gives a short chain polyol that has foam processing characteristics similar to the conventional sulfuric acid neutralized polyol. The polyols produced in this manner are particularly useful for the production of polyurethane and polyisocyanurate foams.
摘要翻译： 通过在碱金属氢氧化物催化剂存在下使胺环氧化，制备了胺引发的聚醚多元醇。 通过减少在多元醇合成期间使用的催化剂的量，并且通过在加入至少一种环氧烷的总量的5至30％之后加入催化剂，在乳酸中和之后，得到具有泡沫加工的短链多元醇 特征与常规硫酸中和的多元醇相似。 以这种方式制备的多元醇特别可用于生产聚氨酯和聚异氰脲酸酯泡沫。
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