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公开(公告)号：US09334171B2
公开(公告)日：2016-05-10
申请号：US13163377
申请日：2011-06-17
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Hiroyuki Imai , Bin Xie , Haiyan Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Hiroyuki Imai , Bin Xie , Haiyan Zhang
IPC分类号： C01B39/48 , B01J29/70 , C01B39/46 , B01J20/18 , B01J20/28 , C07C1/20 , C10G3/00 , C10G11/18 , C10G25/03 , C01B37/02 , B01D53/94
CPC分类号： C01B39/46 , B01D53/9418 , B01D2251/2067 , B01D2253/108 , B01D2253/3425 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9207 , B01D2257/402 , B01D2257/404 , B01D2257/406 , B01D2258/012 , B01J20/186 , B01J20/28011 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J29/70 , B01J2229/186 , C01B37/02 , C01B39/48 , C01P2006/12 , C07C1/20 , C07C2529/70 , C07C2529/80 , C10G3/49 , C10G11/18 , C10G25/03 , C10G2300/405 , C10G2300/70 , Y02C20/10 , Y02P20/153 , Y02P20/52 , Y02P30/20
摘要： A process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X203, wherein said process comprises preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, and wherein the crystallized mixture contains 0.1 wt.-% or less, more preferably 0.01 wt.-% or less of one or more metals M based on 100 wt.-% of YO2, wherein even more preferably the crystallized mixture contains no metal M, wherein M stands for sodium and/or potassium, wherein preferably M stands for the group of alkali and alkaline earth metals.
摘要翻译： 一种制备具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括制备包含一种或多种YO 2，一种或多种溶剂和任选地包含晶种的源的混合物; 并使混合物结晶; 其中Y是四价元素，X是三价元素，并且其中所述结晶混合物含有基于100重量％的0.1重量％或更少，更优选0.01重量％或更少的一种或多种金属M， 的YO 2，其中甚至更优选结晶的混合物不含金属M，其中M代表钠和/或钾，其中优选M代表碱金属和碱土金属。
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公开(公告)号：US20120004465A1
公开(公告)日：2012-01-05
申请号：US13254015
申请日：2010-03-03
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Hermann Gies , Dirk de Vos , Xinhe Bao , Weiping Zhang , Takashi Tatsumi
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Hermann Gies , Dirk de Vos , Xinhe Bao , Weiping Zhang , Takashi Tatsumi
IPC分类号： C07C209/00 , C01B33/26 , C01B35/10 , C01B33/20
CPC分类号： C01B33/20 , B01J21/16 , B01J29/061 , B01J29/70 , B01J35/002 , C01B33/38 , C01B37/00 , C01B39/02 , C01B39/04 , C07C1/20 , C07C209/16 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C211/04
摘要： A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.
摘要翻译： 一种制备同晶取代的层状硅酸盐的方法，包括（1）提供含有二氧化硅或其前体的混合物，至少一种允许层状硅酸盐结晶的结构导向剂（SDA）和水; （2）在水热条件下加热根据（1）获得的混合物; （3）至少一种源至少一种适用于同晶取代的元素; （4）在水热条件下加热根据（3）获得的混合物。
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公开(公告)号：US20120016045A1
公开(公告)日：2012-01-19
申请号：US13254022
申请日：2010-03-03
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Dirk de Vos , Xinhe Bao , Weiping Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Dirk de Vos , Xinhe Bao , Weiping Zhang
CPC分类号： C01B33/20 , B01J20/10 , B01J20/30 , B01J21/16 , B01J29/049 , C01B33/38 , C01B37/00 , C01B37/02 , C01B39/02 , C01B39/04
摘要： The present invention relates to a process for the preparation of a layered silicate containing at least silicon and oxygen, comprising (1) providing a mixture containing silica and/or at least one silica precursor, water, at least one tetraalkylammonium compound selected from the group consisting of diethyldimethylammonium compound, a triethylmethylammonium compound, and a mixture of a diethyldimethylammonium and a triethylmethylammonium compound, and at least one base, and optionally at least one suitable seeding material; and (2) heating of the mixture obtained according to (1) under autogenous pressure (hydrothermal conditions) to a temperature in the range of from to 120 to 160° C. for a period in the range of from 5 to 10 days to give a suspension containing the layered silicate.
摘要翻译： 本发明涉及一种制备至少含硅和氧的层状硅酸盐的方法，其包括（1）提供含有二氧化硅和/或至少一种二氧化硅前体的混合物，水，至少一种选自以下的四烷基铵化合物 由二乙基二甲基铵化合物，三乙基甲基铵化合物和二乙基二甲基铵和三乙基甲基铵化合物的混合物组成，以及至少一种碱和任选的至少一种合适的接种材料; 和（2）根据（1）获得的混合物在自生压力（水热条件）下加热至120至160℃的温度范围为5至10天，得到 含有层状硅酸盐的悬浮液。
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4.发明申请Zeolitic Materials of the LEV-Type Structure And Methods For Their Production 审中-公开LEV型结构的沸石材料及其生产方法公开(公告)号：US20110313226A1
公开(公告)日：2011-12-22
申请号：US13163430
申请日：2011-06-17
申请人： Bilge Yilmaz , Ulrich Müller , Bibiana Andrea Betancur Moreno , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Meike Pfaff , Bin Xie , Haiyan Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Bibiana Andrea Betancur Moreno , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Meike Pfaff , Bin Xie , Haiyan Zhang
CPC分类号： C01B39/48 , B01D2253/108 , B01D2255/50 , B01J20/186 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J20/3042 , B01J29/70 , C01B37/02 , C01B39/46 , C10G3/49 , C10G11/18 , C10G25/03 , C10G2300/405 , C10G2300/70 , Y02P30/20
摘要： Described is a process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises: (1) preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and (2) crystallizing the mixture obtained in step (1);wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein the molar ratio of the total amount of the one or more solvents to the total amount of the one or more sources for YO2 based on YO2 is 9.5 or less, and wherein for crystallization temperatures of 175° C. or higher in step (2), the duration of crystallization at those temperatures is less than 14 d, as well as to a zeolitic material, preferably being obtainable or obtained according to the inventive process, said zeolitic material having an LEV-type framework structure comprising YO2 and X2O3, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the zeolitic material displays an Y:X atomic ratio of from 1 to 9.4.
摘要翻译： 描述了一种生产具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括：（1）制备包含一种或多种YO 2，一种或多种溶剂的来源的混合物，以及 任选地包含晶种; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中沸石材料任选地包含一种或多种碱金属M，其中一种或多种溶剂的总量与一种或多种溶剂的总量的摩尔比 基于YO 2的YO 2的来源为9.5或更低，并且其中对于步骤（2）中的结晶温度为175℃或更高的温度，在这些温度下的结晶持续时间小于14天，以及沸石材料， 所述沸石材料具有包含YO 2和X 2 O 3的LEV型骨架结构，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述沸石材料显示Y：X原子 比例为1〜9.4。
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公开(公告)号：US20110312486A1
公开(公告)日：2011-12-22
申请号：US13163377
申请日：2011-06-17
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Hiroyuki Imai , Bin Xie , Haiyan Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Hiroyuki Imai , Bin Xie , Haiyan Zhang
CPC分类号： C01B39/46 , B01D53/9418 , B01D2251/2067 , B01D2253/108 , B01D2253/3425 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9207 , B01D2257/402 , B01D2257/404 , B01D2257/406 , B01D2258/012 , B01J20/186 , B01J20/28011 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J29/70 , B01J2229/186 , C01B37/02 , C01B39/48 , C01P2006/12 , C07C1/20 , C07C2529/70 , C07C2529/80 , C10G3/49 , C10G11/18 , C10G25/03 , C10G2300/405 , C10G2300/70 , Y02C20/10 , Y02P20/153 , Y02P20/52 , Y02P30/20
摘要： Described is a process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, and X is a trivalent element, and wherein the mixture crystallized in step (2) contains 3 wt.-% or less of one or more metals M based on 100 wt-% of YO2, preferably 1 wt.-% or less, more preferably 0.5 wt.-% or less, more preferably 0.1 wt.-% or less, more preferably 0.05 wt.-% or less, more preferably 0.01 wt.-% or less, more preferably 0.005 wt.-% or less, more preferably 0.001 wt.-% or less, more preferably 0.0005 wt.-% or less, more preferably 0.0001 wt.-% or less of one or more metals M based on 100 wt.-% of YO2, wherein even more preferably the mixture crystallized in step (2) contains no metal M, wherein M stands for sodium or potassium, preferably for sodium and potassium, more preferably for the group of alkali metals, wherein even more preferably M stands for the group of alkali and alkaline earth metals.
摘要翻译： 描述了一种制备具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括（1）制备包含一种或多种YO 2，一种或多种溶剂来源的混合物， 包括晶种; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，并且其中步骤（2）中结晶的混合物含有基于100重量％的YO 2，优选1重量％的3重量％或更少的一种或多种金属M 更优选为0.5重量％以下，更优选为0.1重量％以下，更优选为0.05重量％以下，更优选为0.01重量％以下，更优选为0.005重量％ 更优选0.001重量％以下，更优选0.0005重量％以下，更优选0.0001重量％以下的一种或多种金属M，基于100重量％的YO 2 其中甚至更优选在步骤（2）中结晶的混合物不含金属M，其中M代表钠或钾，优选钠和钾，更优选碱金属组，其中甚至更优选M代表基团 的碱金属和碱土金属。
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6.发明授权Process for the production of a core/shell zeolitic material having a CHA framework structure 有权制备具有CHA骨架结构的核/壳沸石材料的方法公开(公告)号：US09334170B2
公开(公告)日：2016-05-10
申请号：US13616834
申请日：2012-09-14
申请人： Bilge Yilmaz , Ulrich Müller , Feng-Shou Xiao , Takashi Tatsumi , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert , Limin Ren , Chengguan Yang
发明人： Bilge Yilmaz , Ulrich Müller , Feng-Shou Xiao , Takashi Tatsumi , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert , Limin Ren , Chengguan Yang
IPC分类号： C01B39/00 , B01J29/85 , B01J37/02 , B01J29/00 , B01J29/84 , B01J29/83 , C01B39/54 , C01B37/08 , C01B39/48 , B01J29/70 , B01J35/00 , B01J35/02 , B01J35/10 , C07C1/20 , C10G11/18 , C10G3/00 , B01D53/02 , B01D53/94
CPC分类号： C01B39/00 , B01D53/02 , B01D53/9418 , B01D2255/2025 , B01D2255/20707 , B01D2255/20715 , B01D2255/2092 , B01D2255/2094 , B01D2255/50 , B01J29/005 , B01J29/7015 , B01J29/83 , B01J29/84 , B01J29/85 , B01J35/002 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1066 , B01J37/02 , B01J37/0221 , B01J37/023 , B01J2229/62 , C01B37/08 , C01B39/48 , C01B39/54 , C01P2002/72 , C01P2004/03 , C01P2006/12 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G11/18 , Y02P20/52 , Y02P30/20 , C07C11/02
摘要： The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of (1) providing a mixture comprising one or more sources for Z2O5, one or more sources for X2O3, optionally one or more structure directing agents, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO2, X2O3, and optionally Z2O5, and wherein the seed crystals have a diameter of 450 nm or greater; (2) crystallizing the mixture provided in (1) to afford zeolite crystals comprising a core of seed crystal provided in step (1) and a shell crystallized on the seed crystal; wherein Z is a pentavalent element, Y is a tetravalent element, and X is a trivalent element.
摘要翻译： 本发明涉及一种制备具有CHA骨架结构的沸石材料的方法，所述沸石材料包含具有核 - 壳结构的沸石晶体，其中所述方法包括以下步骤：（1）提供包含一种或多种 Z 2 O 5的源，X 2 O 3，任选的一种或多种结构导向剂的一种或多种来源，以及具有CHA骨架结构的晶种，其中晶种的CHA骨架结构包含YO 2，X 2 O 3和任选的Z 2 O 5，并且其中所述种子 晶体的直径为450nm以上; （2）使（1）中提供的混合物结晶，得到包含步骤（1）中提供的晶种核心的沸石晶体和在晶种上结晶的壳; 其中Z为五价元素，Y为四价元素，X为三价元素。
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公开(公告)号：US09181145B2
公开(公告)日：2015-11-10
申请号：US13438408
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , C07C15/073 , C07C15/02
摘要： The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
摘要翻译： 本发明涉及一种有机化合物的烷基化方法，包括：（a）提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂，其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3，其中Y是 四价元素，X是三价元素，（b）在一个或多个烷基化剂存在下，在一个或多个烷基化剂存在下使催化剂与一种或多种可烷基化的有机化合物接触，以获得一种或多种烷基化有机化合物，其中所述一种或多种烷基化有机化合物， 更多的沸石材料可以从不使用有机模板作为结构导向剂的合成方法获得。
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公开(公告)号：US20120259141A1
公开(公告)日：2012-10-11
申请号：US13438316
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Takashi Tatsumi , Feng-Shou Xiao , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Takashi Tatsumi , Feng-Shou Xiao , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
CPC分类号： C01B39/46 , B01J29/7007 , C01B39/026
摘要： The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.
摘要翻译： 本发明涉及一种制备具有BEA骨架结构的沸石材料的方法，包括以下步骤：（i）提供一种或多种具有BEA骨架结构的沸石材料，其中BEA骨架结构包含YO 2和X 2 O 3，其中 Y是四价元素，X是三价元素; （ii）使步骤（i）中提供的一种或多种沸石材料从BEA骨架结构中除去至少一部分X，优选四面体配位的X的步骤; 其中步骤（i）中提供的一种或多种沸石材料的Y：X摩尔比分别在1至50的范围内。
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公开(公告)号：US20120259148A1
公开(公告)日：2012-10-11
申请号：US13438408
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , C07C15/073 , C07C15/02
摘要： The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
摘要翻译： 本发明涉及一种有机化合物的烷基化方法，包括：（a）提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂，其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3，其中Y是 四价元素，X是三价元素，（b）在一个或多个烷基化剂存在下，在一个或多个烷基化剂存在下使催化剂与一种或多种可烷基化的有机化合物接触，以获得一种或多种烷基化有机化合物，其中所述一种或多种烷基化有机化合物， 更多的沸石材料可以从不使用有机模板作为结构导向剂的合成方法获得。
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公开(公告)号：US20110319251A1
公开(公告)日：2011-12-29
申请号：US13254046
申请日：2010-03-03
申请人： Bilge Yilmaz , Ulrich Müller , Feng-Shou Xiao , Hermann Gies , Xinhe Bao , Dirk De Vos , Takashi Tatsumi , Weiping Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Feng-Shou Xiao , Hermann Gies , Xinhe Bao , Dirk De Vos , Takashi Tatsumi , Weiping Zhang
IPC分类号： B01J29/00 , C04B35/622 , C01B35/00 , C01B33/20 , C01B33/26
CPC分类号： C01B37/005 , C01B37/02 , C04B35/16 , C04B2235/3217 , C04B2235/3232 , C04B2235/3239 , C04B2235/3244 , C04B2235/3251 , C04B2235/3272 , C04B2235/3286 , C04B2235/3287 , C04B2235/3293 , C04B2235/3409 , C04B2235/3427 , C04B2235/441 , C04B2235/5409 , C04B2235/602 , C04B2235/6021
摘要： The present invention relates to a process for the preparation of an isomorphously substituted RUB-36 silicate comprising (1) providing a mixture containing silica, preferably amorphous silica, and/or at least one silica precursor, water, at least one suitable structure directing agent, (2) heating the mixture obtained according to (1) under hydrothermal conditions to give a suspension containing an RUB-36 silicate, (3) separating the RUB-36 silicate, wherein (a) either the mixture according to (1) contains at least one element suitable for isomorphous substitution and/or (b) the separated RUB-36 silicate according to (3) is subjected to isomorphous substitution.
摘要翻译： 本发明涉及一种制备同晶取代的RUB-36硅酸盐的方法，其包括（1）提供含有二氧化硅，优选无定形二氧化硅和/或至少一种二氧化硅前体，水，至少一种合适的结构导向剂 ，（2）在水热条件下加热根据（1）获得的混合物，得到含有RUB-36硅酸盐的悬浮液，（3）分离RUB-36硅酸盐，其中（a）根据（1）的混合物含有 适于同晶取代的至少一种元素和/或（b）根据（3）的分离的RUB-36硅酸盐进行同晶取代。
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