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公开(公告)号：US08829227B2
公开(公告)日：2014-09-09
申请号：US11911641
申请日：2006-05-24
申请人： Brady Compton , John Lyford, IV , Nicolaas Anthony De Munck , Aad Gerrit Oskam , Allen David Godwin , Leendert Johannes Van Dop
发明人： Brady Compton , John Lyford, IV , Nicolaas Anthony De Munck , Aad Gerrit Oskam , Allen David Godwin , Leendert Johannes Van Dop
CPC分类号： C07C67/56 , C07C2601/14 , C08K5/10 , Y02P20/582 , C07C69/44 , C07C69/80 , C07C69/78 , C07C69/76 , C07C69/60 , C07C69/75
摘要： Esters produced by the catalyzed reaction of alcohols and acids or anhydrides are neutralized by treatment with an aqueous alkaline alkali metal salt solution in an amount that provides less than a stoichiometric amount of alkali metal salt in relation to the acidity of the crude ester and the amount of water present during the treatment is from 0.8 to 1.4 wt % of water based on the weight of crude ester. When using titanium as the esterification catalyst, the ester resulting from this process contains less than 0.01 ppm by weight of titanium residue, so that it is storage stable when stored in the presence of an antioxidant.
摘要翻译： 通过醇和酸或酸酐的催化反应制备的酯通过用碱金属碱金属盐水溶液处理而中和，其量相对于粗酯的酸度提供小于化学计量量的碱金属盐， 在处理期间存在的水是基于粗酯重量的0.8至1.4重量％的水。 当使用钛作为酯化催化剂时，由该方法得到的酯含有小于0.01重量ppm的钛残基，因此在存在抗氧化剂时储存稳定。
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公开(公告)号：US20080275267A1
公开(公告)日：2008-11-06
申请号：US11911641
申请日：2006-05-24
申请人： Brady Compton , John Lyford , Nicolaas Anthony De Munck , Aad Gerrit Oskam , Allen David Godwin , Leendert Johannes Van Dop
发明人： Brady Compton , John Lyford , Nicolaas Anthony De Munck , Aad Gerrit Oskam , Allen David Godwin , Leendert Johannes Van Dop
IPC分类号： C07C67/58
CPC分类号： C07C67/56 , C07C2601/14 , C08K5/10 , Y02P20/582 , C07C69/44 , C07C69/80 , C07C69/78 , C07C69/76 , C07C69/60 , C07C69/75
摘要： Esters produced by the catalyzed reaction of alcohols and acids or anhydrides are neutralized by treatment with an aqueous alkaline alkali metal salt solution in an amount that provides less than a stoichiometric amount of alkali metal salt in relation to the acidity of the crude ester and the amount of water present during the treatment is from 0.8 to 1.4 wt % of water based on the weight of crude ester. When using titanium as the esterification catalyst, the ester resulting from this process contains less than 0.01 ppm by weight of titanium residue, so that it is storage stable when stored in the presence of an antioxidant.
摘要翻译： 通过醇和酸或酸酐的催化反应制备的酯通过用碱金属碱金属盐水溶液处理而中和，其量相对于粗酯的酸度提供小于化学计量量的碱金属盐， 在处理期间存在的水是基于粗酯重量的0.8至1.4重量％的水。 当使用钛作为酯化催化剂时，由该方法得到的酯含有小于0.01重量ppm的钛残基，因此在存在抗氧化剂时储存稳定。
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公开(公告)号：US08729289B2
公开(公告)日：2014-05-20
申请号：US12526735
申请日：2008-03-07
申请人： Nicolaas Anthony De Munck , Allen David Godwin , Thomas Marshall Larson , Paul H. Daniels , Didier Naert
发明人： Nicolaas Anthony De Munck , Allen David Godwin , Thomas Marshall Larson , Paul H. Daniels , Didier Naert
IPC分类号： C07C69/74
CPC分类号： C07C67/303 , B01J19/0033 , B01J2219/00031 , B01J2219/00033 , B01J2219/00038 , C07C67/08 , C07C67/56 , C07C2601/14 , C08K5/10 , C07C69/80 , C07C69/78 , C07C69/75 , C08L27/06
摘要： A method for performing a flying grade switch in an ester production process, which preferably is operated in semi-continuous mode, maximizes plant equipment productivity while minimizing product cross-contamination. Mixed ester products of the process containing a C9-C11 alkyl or isodecyl benzoate together with a higher molecular weight di-alkyl phthalate or cyclohexanoate, bring performance advantages such as improved permanence in plasticized PVC articles or improved processability in manufacturing these articles.
摘要翻译： 优选在半连续模式下操作的酯生产过程中执行飞行级开关的方法使得设备生产率最大化，同时最小化产品交叉污染。 包含C9-C11烷基或异癸基苯甲酸酯与较高分子量邻苯二甲酸二烷基酯或环己酸酯的方法的混合酯产物带来性能优点，例如改善塑化PVC制品的耐久性或改善制造这些制品的可加工性。
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公开(公告)号：US20100108940A1
公开(公告)日：2010-05-06
申请号：US12526735
申请日：2008-03-07
申请人： Nicolaas Anthony De Munck , Allen David Godwin , Thomas Marshall Larson , Paul H. Daniels , Didier Naert
发明人： Nicolaas Anthony De Munck , Allen David Godwin , Thomas Marshall Larson , Paul H. Daniels , Didier Naert
CPC分类号： C07C67/303 , B01J19/0033 , B01J2219/00031 , B01J2219/00033 , B01J2219/00038 , C07C67/08 , C07C67/56 , C07C2601/14 , C08K5/10 , C07C69/80 , C07C69/78 , C07C69/75 , C08L27/06
摘要： A method for performing a flying grade switch in an ester production process, which preferably is operated in semi-continuous mode, maximises plant equipment productivity while minimizing product cross-contamination. Mixed ester products of the process containing a C9-C11 alkyl or isodecyl benzoate together with a higher molecular weight di-alkyl phthalate or cyclohexanoate, bring performance advantages such as improved permanence in plasticised PVC articles or improved processability in manufacturing these articles.
摘要翻译： 优选在半连续模式下操作的酯生产过程中执行飞行级开关的方法使得设备生产率最大化，同时最小化产品交叉污染。 包含C9-C11烷基或异癸基苯甲酸酯与较高分子量邻苯二甲酸二烷基酯或环己酸酯的方法的混合酯产物具有性能优点，例如改善塑化PVC制品的耐久性或改善制造这些制品的加工性能。
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5.发明授权Oil based polyols or diacids esterified with oxo-acids or oxo-alcohols for producing plasticizers 有权用含氧酸或羰基醇酯化的油基多元醇或二酸用于生产增塑剂公开(公告)号：US08329795B2
公开(公告)日：2012-12-11
申请号：US12830606
申请日：2010-07-06
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
IPC分类号： C08K5/00
CPC分类号： C07C67/08 , C07C5/32 , C07C29/147 , C07C45/50 , C07C51/16 , C07C67/26 , C07C69/28 , C07C69/75 , C07C2601/14 , C07C2603/68 , C08K5/10 , C07C35/08 , C07C47/32 , C07C61/08
摘要： Oxo-diesters of cyclic olefins, methods of making them and their use as plasticizers in polymer compositions are disclosed.
摘要翻译： 公开了环烯烃的氧代二酯，其制备方法及其作为增塑剂在聚合物组合物中的用途。
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6.发明申请METHODS OF MAKING 6-HYDROXYHEXANOPHENONE AND 5-BENZOYLPENTANOIC ACID AND MONO OR DIESTERS THEREOF 审中-公开制备6-羟基六氢呋喃酮和5-苯甲酰基戊酸及其单体或二氧化钛的方法公开(公告)号：US20120035308A1
公开(公告)日：2012-02-09
申请号：US13197253
申请日：2011-08-03
申请人： Kun Wang , Jihad Mohammed Dakka , Edmund John Mozeleski , Francisco Manuel Benitez , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova , Stephen Zushma
发明人： Kun Wang , Jihad Mohammed Dakka , Edmund John Mozeleski , Francisco Manuel Benitez , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova , Stephen Zushma
IPC分类号： C08K5/12 , C07C45/28 , C08K5/101 , C07C67/40 , C07C67/08 , C07C69/612 , C07C69/716
CPC分类号： C07C45/53 , C07C51/235 , C07C67/08 , C07C67/29 , C07C67/31 , C07C69/24 , C07C69/738 , C07C407/00 , C07C2601/14 , C08K5/10 , C07C49/82 , C07C409/14 , C07C59/84 , C07C69/732 , C07C69/73 , C07C69/28
摘要： Mono- or diester plasticizers of the formula: wherein A is either —OC(O)R′ or ═O, and X is either —COC(O)R or —C(O)OR, and R and R′ are C3 to C13 alkyl, which are the same or different, formed from cyclohexylbenzene and processes of making them.
摘要翻译： 单或二酯增塑剂，其通式为：其中A为-OC（O）R'或= O，X为-COC（O）R或-C（O）OR，R和R'为C 3〜 C13烷基，它们是相同或不同的，由环己基苯形成及其制备方法。
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公开(公告)号：US06355711B1
公开(公告)日：2002-03-12
申请号：US09282992
申请日：1999-03-31
IPC分类号： C08K509
摘要： A plasticizer ester prepared from the catalytic reaction of (1) at least one branched C7-C11 oxo alcohol prepared from C6-C10 olefins via hydroformylation and having at least 50% methyl branching at the beta carbon, and (2) at least one acid or anhydride.
摘要翻译： 由（1）由C 6 -C 10烯烃经由加氢甲酰化制备并在β碳上具有至少50％甲基支化的至少一种支化C 7 -C 11羰基合成醇的催化反应制备的增塑剂酯，和（2）至少一种酸 或酸酐。
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公开(公告)号：US06307093B1
公开(公告)日：2001-10-23
申请号：US09448996
申请日：1999-11-24
申请人： Allen David Godwin , Richard Henry Schlosberg , Frank Hershkowitz , Michael G Matturro , Gabor Kiss , Kirk Christian Nadler , Philippe Louis Buess , Richard C Miller , Paul William Allen , Harry William Deckman , Raf Caers , Edmund John Mozeleski , Robert P Reynolds
发明人： Allen David Godwin , Richard Henry Schlosberg , Frank Hershkowitz , Michael G Matturro , Gabor Kiss , Kirk Christian Nadler , Philippe Louis Buess , Richard C Miller , Paul William Allen , Harry William Deckman , Raf Caers , Edmund John Mozeleski , Robert P Reynolds
IPC分类号： C07C6900
摘要： Esters of branched C9 alcohols suitable as plasticizers are formed by esterification of a C9 alcohol produced by the aldol condensation from propanal and a C6 aldehyde and hydrogenation, the propanal optionally having been made from natural gas streams.
摘要翻译： 适合作为增塑剂的分支C 9醇的酯通过由丙醛和C 6醛醛醛缩合产生的C 9醇酯化并氢化而形成，丙醛任选地由天然气流制成。
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公开(公告)号：US08568846B2
公开(公告)日：2013-10-29
申请号：US12880586
申请日：2010-09-13
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
CPC分类号： C07C67/38 , C08K5/103 , Y10T428/139 , Y10T442/20 , C07C69/30
摘要： Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译： 提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。 在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成 新烷基酯增塑剂。 这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。
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公开(公告)号：US20130035431A1
公开(公告)日：2013-02-07
申请号：US13198851
申请日：2011-08-05
申请人： Jihad Mohammed Dakka , Stephen Zushma , Christine A. Costello , Edmund John Mozeleski , Diana S. Smirnova , Allen David Godwin , Pierre J. Osterrieth , Jörg Friedrich Wilhelm Weber , Paul Hamden Daniels , Thomas M. Larson , Catherine A. Faler
发明人： Jihad Mohammed Dakka , Stephen Zushma , Christine A. Costello , Edmund John Mozeleski , Diana S. Smirnova , Allen David Godwin , Pierre J. Osterrieth , Jörg Friedrich Wilhelm Weber , Paul Hamden Daniels , Thomas M. Larson , Catherine A. Faler
IPC分类号： C08K5/12 , C07C69/736 , C07C67/08 , C07C67/343 , C08L33/00 , C08L67/00 , C08L75/04 , C08L31/04 , C08L21/00 , C07C69/612 , C08L27/06
CPC分类号： C07C67/08 , C07C67/343 , C07C69/612 , C07C69/734 , C08K5/0016 , C08K5/11
摘要： Provided are compounds of the formula: wherein m=0-3 and n=0-3, and R1 represents CxH2x wherein x=0 to 4 or cyclohexane; R2 represents H, a C1-C6 alkyl group at any of the ortho-, meta- or para-positions, a residue including heteroatoms chosen from O, N, and S, or mixtures thereof; and R3 and R4 represent hydrocarbon residues of OXO-C5-C9 alcohols which are different isomers of equal carbon number or different in carbon number. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
摘要翻译： 提供下式的化合物：其中m = 0-3且n = 0-3，并且R1表示CxH2x，其中x = 0至4或环己烷; R 2表示H，任何邻位，间位或对位的C 1 -C 6烷基，包括选自O，N和S的杂原子的残基或其混合物; 并且R 3和R 4代表相同碳数或碳数不同的不同异构体的OXO-C5-C9醇的烃残基。 还提供了制备含有所述化合物的化合物和增塑聚合物组合物的方法。
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