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1.发明授权Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer and polymeric foams formed from such blends 有权溴化丁二烯/乙烯基芳族共聚物，这种共聚物与乙烯基芳族聚合物的共混物和由这种共混物形成的聚合物泡沫公开(公告)号：US07851558B2
公开(公告)日：2010-12-14
申请号：US12091346
申请日：2006-10-23
申请人： Bruce A. King , William G. Stobby , Daniel J. Murray , Anteneh Z. Worku , Inken Beulich , Sheila M. Tinetti , Stephen F. Hahn , Ray E. Drumright
发明人： Bruce A. King , William G. Stobby , Daniel J. Murray , Anteneh Z. Worku , Inken Beulich , Sheila M. Tinetti , Stephen F. Hahn , Ray E. Drumright
IPC分类号： C08F236/06 , C08L9/00
CPC分类号： C08C19/12 , C08F8/20 , C08J9/16 , C08J2325/04 , C08J2453/00 , C08F297/04
摘要： A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.
摘要翻译： 热稳定的溴化丁二烯共聚物如溴化苯乙烯/丁二烯嵌段共聚物，溴化无规苯乙烯/丁二烯共聚物或溴化苯乙烯/丁二烯接枝共聚物，溴代丁二烯共聚物的制备，溴化丁二烯共聚物用作阻燃添加剂和聚合物 包含发泡和非发泡的组合物，其包含阻燃量的溴化丁二烯共聚物。
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2.发明申请Brominated Butadiene/Vinyl Aromatic Copolymers, Blends of Such Copolymers with a Vinyl Aromatic Polymer and Polymeric Foams Formed From Such Blends 有权溴化丁二烯/乙烯基芳族共聚物，这种共聚物与乙烯基芳族聚合物的共混物和由这种共混物形成的聚合物泡沫公开(公告)号：US20080287559A1
公开(公告)日：2008-11-20
申请号：US12091346
申请日：2006-10-23
申请人： Bruce A. King , William G. Stobby , Daniel J. Murray , Anteneh Z. Worku , Inken Beulich , Sheila M. Tinetti , Stephen F. Hahn , Ray E. Drumright
发明人： Bruce A. King , William G. Stobby , Daniel J. Murray , Anteneh Z. Worku , Inken Beulich , Sheila M. Tinetti , Stephen F. Hahn , Ray E. Drumright
IPC分类号： C08F236/06 , C08F236/10 , C08L9/06 , C08L9/00
CPC分类号： C08C19/12 , C08F8/20 , C08J9/16 , C08J2325/04 , C08J2453/00 , C08F297/04
摘要： A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.
摘要翻译： 热稳定的溴化丁二烯共聚物如溴化苯乙烯/丁二烯嵌段共聚物，溴化无规苯乙烯/丁二烯共聚物或溴化苯乙烯/丁二烯接枝共聚物，溴代丁二烯共聚物的制备，溴化丁二烯共聚物用作阻燃添加剂和聚合物 包含发泡和非发泡的组合物，其包含阻燃量的溴化丁二烯共聚物。
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3.发明授权公开(公告)号：US08242183B2
公开(公告)日：2012-08-14
申请号：US12866848
申请日：2009-01-30
CPC分类号： C08L25/04 , C08F8/20 , C08F293/005 , C08L33/20 , C08L35/02 , C08L35/06 , C08L45/00 , C08L53/00 , C08L53/02 , C08L55/02 , C08L61/06 , C08L61/14 , C08L65/00 , C08L67/00 , C08L2666/04 , C08L2666/16 , C08L2666/18 , C08L2666/02
摘要： Certain brominated polymers compounds are effective FR additives for combustible organic polymers. These FR additives include: i) a copolymer having styrene and 2,3-dibromopropylmaleimide repeating units; ii) a brominated polyester having aliphatically bound bromine; iii) an allyl ether of a ring-brominated novolac resin; iv) a 3-bromo-2-hydroxypropyl ether of a novolac resin; v) a 2,3-dibromopropyl ether of a cresol novolac resin; and vi) a brominated ROMP polymer or copolymer.
摘要翻译： 某些溴化聚合物化合物是可燃有机聚合物的有效FR添加剂。 这些FR添加剂包括：i）具有苯乙烯和2,3-二溴丙基马来酰亚胺重复单元的共聚物; ii）具有脂族结合溴的溴化聚酯; iii）环溴代酚醛清漆树脂的烯丙基醚; iv）酚醛清漆树脂的3-溴-2-羟丙基醚; v）甲酚酚醛清漆树脂的2,3-二溴丙醚; 和vi）溴化ROMP聚合物或共聚物。
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公开(公告)号：US08058332B2
公开(公告)日：2011-11-15
申请号：US12906203
申请日：2010-10-18
申请人： Ravi B. Shankar , David R. Wilson , William J. Kruper , Bruce A. King , Michelle L. Hudack , Chun Wang , Ted A. Morgan , Inken Beulich , Daniel J. Murray , William Gerald Stobby , Mark W. Beach , Ing Feng Hu
发明人： Ravi B. Shankar , David R. Wilson , William J. Kruper , Bruce A. King , Michelle L. Hudack , Chun Wang , Ted A. Morgan , Inken Beulich , Daniel J. Murray , William Gerald Stobby , Mark W. Beach , Ing Feng Hu
IPC分类号： C07F9/6574 , C07F9/02 , C08K5/49 , C08J9/32
CPC分类号： C07F9/1653 , C07F9/173 , C07F9/657136 , C07F9/657154 , C07F9/657181 , C08K5/5398
摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。
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公开(公告)号：US20110034573A1
公开(公告)日：2011-02-10
申请号：US12906203
申请日：2010-10-18
申请人： Ravi B. Shankar , David R. Wilson , William J. Kruper , Bruce A. King , Michelle L. Hudack , Chun Wang , Ted A. Morgan , Inken Beulich , Daniel J. Murray , William Gerald Stobby , Mark W. Beach , Ing Feng Hu
发明人： Ravi B. Shankar , David R. Wilson , William J. Kruper , Bruce A. King , Michelle L. Hudack , Chun Wang , Ted A. Morgan , Inken Beulich , Daniel J. Murray , William Gerald Stobby , Mark W. Beach , Ing Feng Hu
IPC分类号： C08J9/00 , C08K5/5398 , C07F9/06 , C08K5/3462
CPC分类号： C07F9/1653 , C07F9/173 , C07F9/657136 , C07F9/657154 , C07F9/657181 , C08K5/5398
摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。
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公开(公告)号：US20080153950A1
公开(公告)日：2008-06-26
申请号：US12004345
申请日：2007-12-20
申请人： Ravi B. Shankar , William J. Kruper , David R. Wilson , Bruce A. King , Michelle L. Hudack , Daniel J. Murray , Chun Wang , William Gerald Stobby , Ted A. Morgan , Mark W. Beach , Inken Beulich , Ing Feng Hu
发明人： Ravi B. Shankar , William J. Kruper , David R. Wilson , Bruce A. King , Michelle L. Hudack , Daniel J. Murray , Chun Wang , William Gerald Stobby , Ted A. Morgan , Mark W. Beach , Inken Beulich , Ing Feng Hu
IPC分类号： C08K5/5398 , C08K5/51 , C07F9/6571
CPC分类号： C07F9/1653 , C07F9/173 , C07F9/657136 , C07F9/657154 , C07F9/657181 , C08K5/5398
摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。
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7.发明申请公开(公告)号：US20100317757A1
公开(公告)日：2010-12-16
申请号：US12866848
申请日：2009-01-30
申请人： Bruce A. King , Anteneh Worku , William G. Stobby
发明人： Bruce A. King , Anteneh Worku , William G. Stobby
CPC分类号： C08L25/04 , C08F8/20 , C08F293/005 , C08L33/20 , C08L35/02 , C08L35/06 , C08L45/00 , C08L53/00 , C08L53/02 , C08L55/02 , C08L61/06 , C08L61/14 , C08L65/00 , C08L67/00 , C08L2666/04 , C08L2666/16 , C08L2666/18 , C08L2666/02
摘要： Certain brominated polymers compounds are effective FR additives for combustible organic polymers. These FR additives include: i) a copolymer having styrene and 2,3-dibromopropylmaleimide repeating units; ii) a brominated polyester having aliphatically bound bromine; iii) an allyl ether of a ring-brominated novolac resin; iv) a 3-bromo-2-hydroxypropyl ether of a novolac resin; v) a 2,3-dibromopropyl ether of a cresol novolac resin; and vi) a brominated ROMP polymer or copolymer.
摘要翻译： 某些溴化聚合物化合物是可燃有机聚合物的有效FR添加剂。 这些FR添加剂包括：i）具有苯乙烯和2,3-二溴丙基马来酰亚胺重复单元的共聚物; ii）具有脂族结合溴的溴化聚酯; iii）环溴代酚醛清漆树脂的烯丙基醚; iv）酚醛清漆树脂的3-溴-2-羟丙基醚; v）甲酚酚醛清漆树脂的2,3-二溴丙醚; 和vi）溴化ROMP聚合物或共聚物。
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公开(公告)号：US08202945B2
公开(公告)日：2012-06-19
申请号：US12375679
申请日：2007-08-14
CPC分类号： C08C19/12 , C08F8/20 , Y02P20/582 , C08F297/04
摘要： Butadiene copolymers are brominated using certain quaternary ammonium tribromides as the brominating agent. The bromination process proceeds easily under mild conditions, and produces a brominated product that has excellent thermal stability.
摘要翻译： 使用某些季铵三溴化物作为溴化剂溴化丁二烯共聚物。 溴化过程在温和条件下容易进行，并产生具有优异热稳定性的溴化产物。
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公开(公告)号：US20090292079A1
公开(公告)日：2009-11-26
申请号：US12375656
申请日：2007-08-14
申请人： Daniel J. Murray , David B. Gorman , John W. Hull, JR. , William J. Kruper, JR. , Ted A. Morgan , Bruce A. King , Ronald B. Leng
发明人： Daniel J. Murray , David B. Gorman , John W. Hull, JR. , William J. Kruper, JR. , Ted A. Morgan , Bruce A. King , Ronald B. Leng
IPC分类号： C08F8/22
CPC分类号： C08C19/14 , C08F8/22 , C08F297/04
摘要： Butadiene copolymers are brominated in solution using bromine as the brominating agent. The bromination is conducted in the presence of an excess of an aliphatic alcohol, relative to the amount of bromine that is used. The bromination proceeds rapidly at mild conditions, and is selective in that only aliphatic carbon-carbon double bonds are brominated, and unwanted bromination at tertiary carbon atoms is largely or completely avoided. The resulting brominated polymers are characterized in having very good thermal stability.
摘要翻译： 丁二烯共聚物在溶液中溴化，使用溴作为溴化剂。 相对于所使用的溴的量，溴化在过量的脂族醇存在下进行。 溴化在温和条件下迅速进行，并且是选择性的，因为只有脂肪族碳 - 碳双键被溴化，并且大量或完全避免了叔碳原子的不期望的溴化。 得到的溴化聚合物的特征在于具有非常好的热稳定性。
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公开(公告)号：US20100331497A1
公开(公告)日：2010-12-30
申请号：US12825591
申请日：2010-06-29
申请人： Erin B. Vogel , Shari L. Kram , Daniel J. Murray , Bruce A. King
发明人： Erin B. Vogel , Shari L. Kram , Daniel J. Murray , Bruce A. King
CPC分类号： C08C19/06 , C08C19/12 , C08C19/14 , C08F8/08 , C08F2800/20 , C08J9/12 , C08J2201/03 , C08J2205/052 , C08J2325/06 , C08J2453/02 , C09K21/14 , C08F8/20 , C08F297/04
摘要： Brominated and epoxidized organic compounds are useful flame retardants for polymers such as polystyrene. The organic compounds contain both bromine and oxirane groups, and have molecular weights of at least 1500. The brominated and epoxidized organic compounds can be prepared by sequentially brominating and epoxiding (in either order) a starting compound that contains multiple non-conjugated carbon-carbon double bonds.
摘要翻译： 溴化和环氧化的有机化合物是聚合物如聚苯乙烯的有用的阻燃剂。 有机化合物含有溴和环氧乙烷基团，分子量至少为1500.溴化和环氧化的有机化合物可以通过依次溴化和环氧化（以任一顺序）制备含有多个非共轭碳 - 碳的起始化合物 双重债券。
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