POLYMERS OF THYLENE OXIDE AND CARBON DIOXIDE
    3.
    发明申请
    POLYMERS OF THYLENE OXIDE AND CARBON DIOXIDE 审中-公开
    二氧化硫和二氧化碳的聚合物

    公开(公告)号:US20150353680A1

    公开(公告)日:2015-12-10

    申请号:US14627733

    申请日:2015-02-20

    IPC分类号: C08G64/34 C07F15/06

    摘要: The present disclosure is directed, in part, to methods of synthesizing a poly(ethylene carbonate) polymer from the reaction of ethylene oxide (EO) and carbon dioxide (CO2) in the presence of a metal complex. The present disclosure also provides novel metal complexes. In one aspect, the metal complex is of the formula (I), wherein R1, R2, R3, M, X and Ring A are as defined herein.

    摘要翻译: 本公开部分地涉及在金属络合物的存在下从环氧乙烷(EO)和二氧化碳(CO 2)的反应合成聚(碳酸亚乙酯)聚合物的方法。 本公开还提供新的金属络合物。 在一个方面,金属络合物是式(I),其中R 1,R 2,R 3,M,X和环A如本文所定义。

    ISOTACTIC POLYETHERS AND BIMETALLIC CATALYSTS, METHODS OF MAKING SAME, AND USES THEREOF

    公开(公告)号:US20170335061A1

    公开(公告)日:2017-11-23

    申请号:US15525731

    申请日:2015-11-11

    IPC分类号: C08G65/12 C07F11/00

    摘要: Provided are compositions comprising isotactic polyethers. Methods of making isotactic polyethers, and uses thereof are also disclosed. Also provided are bimetallic complexes that can be used as catalyst. Methods of making isotactic polyethers and bimetallic complexes and uses thereof are also disclosed. For example, a racemic bimetallic (salalen)CrCl polymerization catalyst was prepared and used alkyl diol, PO-oligomer triols, and aPPO and PCL diols as CSAs in order to produce α,ω-hydroxy telechelic iPPO. These telechelic polymers have controlled molecular weights and are semicrystalline. Amorphous α,ω-hydroxy telechelic PPO can also be produced by increasing the reaction temperature in conjunction with the use of CSAs.

    SOLID POLYMER ELECTROLYTE COMPOSITION
    9.
    发明申请
    SOLID POLYMER ELECTROLYTE COMPOSITION 审中-公开
    固体聚合物电解质组合物

    公开(公告)号:US20160276706A1

    公开(公告)日:2016-09-22

    申请号:US15030173

    申请日:2014-10-20

    摘要: A polymer electrolyte composition includes a hard polymer segment covalently bound to an ionically-conducting segment, and a salt that includes an element M selected from an alkali metal, an alkaline earth metal, zinc, and aluminum. The hard polymer segment has a glass transition temperature (Tg) greater than or equal to 110° C., or a melting temperature (Tm) greater than 110° C. The ionically-conducting segment has a molecular weight of 800 to 10,000 g/mol. The polymer electrolyte composition has an ionic conductivity for an M ion greater than or equal to 1×10−8 S/cm at 25° C. Methods for the preparation of the polymer electrolyte composition are also provided, as are articles (e.g., electrochemical cells and energy storage devices) that contain the polymer electrolyte composition.

    摘要翻译: 聚合物电解质组合物包括与离子导电链段共价结合的硬聚合物链段和包含选自碱金属,碱土金属,锌和铝的元素M的盐。 硬聚合物链段具有大于或等于110℃的玻璃化转变温度(Tg)或大于110℃的熔融温度(Tm)。离子导电链段的分子量为800至10,000g / mol。 聚合物电解质组合物在25℃下具有大于或等于1×10 -8 S / cm的M离子的离子电导率。还提供制备聚合物电解质组合物的方法,如制品(例如,电化学 电池和能量存储装置)。

    POLYMERS OF ETHYLENE OXIDE AND CARBON DIOXIDE
    10.
    发明申请
    POLYMERS OF ETHYLENE OXIDE AND CARBON DIOXIDE 审中-公开
    乙烯氧化物和二氧化碳的聚合物

    公开(公告)号:US20140066591A1

    公开(公告)日:2014-03-06

    申请号:US13915320

    申请日:2013-06-11

    IPC分类号: C08G64/34

    摘要: The present disclosure is directed, in part, to methods of synthesizing a poly(ethylene carbonate) polymer from the reaction of ethylene oxide (EO) and carbon dioxide (CO2) in the presence of a metal complex. The present disclosure also provides novel metal complexes. In one aspect, the metal complex is of the formula (I), wherein R1, R2, R3, M, X and Ring A are as defined herein.

    摘要翻译: 本公开部分地涉及在金属络合物的存在下从环氧乙烷(EO)和二氧化碳(CO 2)的反应合成聚(碳酸亚乙酯)聚合物的方法。 本公开还提供新的金属络合物。 在一个方面,金属络合物是式(I),其中R 1,R 2,R 3,M,X和环A如本文所定义。