摘要:
The invention relates to a molecular sieve composition, a process of preparing same and use thereof in the production of lower olefins. The molecular sieve composition comprises an aluminophosphate molecular sieve and a CO adsorbing component, both of which are present independently of each other. When the molecular sieve composition is used as a catalyst for producing lower olefins using synthesis gas as a raw material, the molecular sieve composition has the advantages of high selectivity to lower olefins and the like.
摘要:
Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 μm, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.
摘要:
A method of wax oil hydrocracking includes the steps of pre-hydrotreating wax oil to obtain a pre-hydrotreated material flow; controlling the pre-hydrotreated material flow and a hydrogen-containing material flow to contact with a first hydrocracking catalyst to obtain a first hydrocracked material flow, and dividing the first hydrocracked material flow into a first hydrocracked material flow A and a first hydrocracked material flow B; controlling the flow B and a hydrogen-containing material flow to contact with a second hydrocracking catalyst to obtain a second hydrocracked material flow, and then separating and fractionating the second hydrocracked material flow to obtain a hydrocracked tail oil product; controlling the flow A, at least a part of the hydrocracked tail oil product, and a hydrogen-containing material flow to contact with a hydrogenation isocracking catalyst to obtain a hydrogenation isocracked material flow, and then separating and fractionating the obtained hydrogenation isocracked material flow.
摘要:
The present invention relates to a hydrocracking catalyst, a process for preparing the same and use thereof The present catalyst comprises a cracking component and a hydrogenation component, wherein the cracking component comprises from 0 to 20 wt. % of a molecular sieve and from 20 wt. % to 60 wt. % of an amorphous silica-alumina, the hydrogenation component comprises at least one hydrogenation metal in a total amount of from 34 wt. % to 75 wt. % calculated by the mass of oxides, each amount is based on the total weight of the catalyst. The present catalyst is prepared by directly mixing an acidic component powder material with an impregnating solution, impregnating, filtering, drying, molding, and drying and calcining.
摘要:
The present invention discloses a modified Y molecular sieve, a preparation method and a use of the modified Y molecular sieve, a supported catalyst, and a hydrocracking method. The silica-alumina mole ratio in the surface layer of the modified Y molecular sieve is 20-100:1, and the silica-alumina mole ratio in the body phase of the modified Y molecular sieve is 8-30:1. When a hydrocracking catalyst prepared from the modified Y molecular sieve is used for hydrocracking, the hydrocracking catalyst has higher reactivity and higher nitrogen tolerance. The hydrocracking catalyst prepared from the modified Y molecular sieve is suitable for use for increasing the yield of diesel oil, increasing the yield of chemical materials, and catalyzed hydrogenation conversion of diesel oil, etc.
摘要:
Disclosed are a beta molecular sieve, a preparation method therefor, and a hydrogenation catalyst containing same. The properties of the beta molecular sieve are as follows: the molar ratio of SiO2/Al2O3 is 30-150, the non-framework aluminum accounts for not more than 2% of the total aluminum, and the silicon atoms coordinated in a Si(OAl) structure account for not less than 95% of the silicon atoms in the framework structure. The preparation method comprises: contacting the raw material powder of the beta molecular sieve with normal pressure and dynamic water vapour, and then with ammonium fluosilicate. The beta molecular sieve of the present invention has the features of a uniform skeleton structure of silicon and aluminum, an appropriate acidity, and a reasonable pore structure, and is suitable as an acidic component of a hydro-upgrading catalyst and a hydro-cracking catalyst for diesel oil.
摘要翻译:公开了一种β分子筛及其制备方法和含有它的氢化催化剂。 β分子筛的性质如下:SiO 2 / Al 2 O 3的摩尔比为30-150,非骨架铝占总铝的不超过2%,硅原子在Si(OAl)中配位 )结构占框架结构中不少于95%的硅原子。 该制备方法包括:将β分子筛的原料粉与常压和动态水蒸气接触,然后与氟硅酸铵接触。 本发明的β分子筛具有硅和铝均匀骨架结构的特征,适宜的酸度和合理的孔结构,适合作为加氢改质催化剂和加氢裂解催化剂的酸性成分 用于柴油。
摘要:
Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 μm, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.