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公开(公告)号:US07038098B2
公开(公告)日:2006-05-02
申请号:US10491906
申请日:2002-10-14
CPC分类号: C07C5/48 , C07C5/327 , C07C5/333 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/74 , C07C15/46
摘要: C2–C30-alkanes are dehydrogenated in a process in which (i) ethylbenzene is dehydrogenated to styrene in a first part process to give a hydrogen-containing offgas stream, and (ii) one or more C2–C30-alkanes are dehydrogenated in the presence of a heterogeneous catalyst in one or more reaction zones in a second part process to give the corresponding olefins, with a hydrogen-containing gas stream being mixed into the reaction gas mixture of the dehydrogenation in at least one reaction zone, wherein at least part of the hydrogen-containing offgas stream obtained in the dehydrogenation of ethylbenzene is mixed into the reaction gas mixture of the alkane dehydrogenation.
摘要翻译: 在第一部分方法中,(ⅰ)乙苯脱氢成苯乙烯的方法中,将C 2 -C 30烷基脱氢,得到含氢废气流, 和(ii)一种或多种C 2 -C 30 - 烷烃在非均相催化剂存在下在一个或多个反应区中在第二部分方法中脱氢,得到 将相应的烯烃与含氢气流混合到至少一个反应区中的脱氢反应气体混合物中,其中在乙苯脱氢中获得的至少部分含氢废气流混合到反应器 烷烃脱气的气体混合物。
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公开(公告)号:US07285685B2
公开(公告)日:2007-10-23
申请号:US10565730
申请日:2004-07-22
IPC分类号: C07C45/65
CPC分类号: C07C45/65 , B01J23/626 , B01J23/96 , B01J38/14 , Y02P20/584 , C07C49/597
摘要: Process for preparing alpha, beta-unsaturated acyclic or cyclic carbonyl compounds by dehydrogenation of the corresponding saturated carbonyl compounds in the gas phase over a heterogeneous dehydrogenation catalyst comprising platinum and/or palladium and tin on an oxidic support.
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3.
公开(公告)号:US07193121B2
公开(公告)日:2007-03-20
申请号:US10501876
申请日:2003-02-17
IPC分类号: C07C5/32
CPC分类号: C07C5/367 , C07C2/52 , C07C13/20 , C07C15/073 , C07C15/46
摘要: The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.
摘要翻译: 本发明涉及一种制备4-乙烯基环己烯的方法,其包括步骤(A)提供含正丁烷的进料气流,(B)将含正丁烷的进料气流进料至至少一个脱氢区和 将正丁醇脱氢成丁二烯,得到包含丁二烯,正丁烷,可能的1-丁烯和2-丁烯以及可能的水蒸气和其他二次成分的产物流,(C)如果适当,将脱离后的产物流从分离出来 水蒸气和次要成分,进入二聚化区域并催化二聚丁二烯,得到包含4-乙烯基环己烯,正丁烷和可能的1-丁烯,2-丁烯和未反应的丁二烯的产物流,和(D)将4-乙烯基环己烯从 来自二聚和再循环的正丁烷和可能的1-丁烯,2-丁烯和未反应的丁二烯的产物流到脱氢区。
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公开(公告)号:US07034195B2
公开(公告)日:2006-04-25
申请号:US10516920
申请日:2003-07-10
IPC分类号: C07C5/333
CPC分类号: C07C5/3335 , C07C5/3337 , C07C11/167
摘要: The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译: 本发明涉及一种从正丁烷制备丁二烯的方法,包括步骤(A)提供含正丁烷的原料气流,(B)将含正丁烷的进料气流进料到第一脱氢区和非氧化反应 将正丁烷催化脱氢为1-丁烯,2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷,1-丁烯和2-丁烯的第一产物气流,(C) 将包含或不具有丁二烯和次要组分的正丁烷,1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯,得到包含丁二烯的第二产物气流 正丁烷和蒸汽,具有或没有二级组分,(D)从第二产物气流回收丁二烯。
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公开(公告)号:US06900363B2
公开(公告)日:2005-05-31
申请号:US10497598
申请日:2002-12-04
IPC分类号: C07C17/02 , C07C17/15 , C07C17/152 , C07C17/156 , C07C17/158 , C07C17/25 , C07C17/38 , C07C19/045 , C07C21/06
CPC分类号: C07C17/02 , C07C17/156 , C07C19/045
摘要: A process for preparing 1,2-dichloroethane which comprises (A) feeding an ethane-containing feed gas stream into a dehydrogenation zone and dehydrogenating ethane to ethane to give a product gas stream comprising ethane, ethane and secondary constituents, (B) feeding the ethan- and ethene-containing dehydrogenation product gas stream as a single stream or a plurality of substreams, optionally after having separated off secondary constituents, into one or more chlorination zones, chlorinating ethene to 1,2-dichloroethane to give one or more product gas streams comprising 1,2-dichloroethane, ethane and possibly further secondary constituents, isolating 1,2-dichloroethane and one or more ethane-containing circulating gas streams and recirculating the ethane-containing circulating gas stream or streams to the ethane dehydrogenation.
摘要翻译: 一种制备1,2-二氯乙烷的方法,其包括(A)将含乙烷的原料气流送入脱氢区并将乙烷脱氢为乙烷,得到包含乙烷,乙烷和第二组分的产物气流,(B) 含有乙烯和乙烯的脱氢产物气流作为单一流或多个子流,任选地在分离出次级成分后,形成一个或多个氯化区,将乙烯氯化成1,2-二氯乙烷,得到一种或多种产物气体 包含1,2-二氯乙烷,乙烷和可能的其它二级成分的物流,分离1,2-二氯乙烷和一种或多种含乙烷的循环气流,并将含乙烷的循环气流或物流再循环到乙烷脱氢。
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6.
公开(公告)号:US07850842B2
公开(公告)日:2010-12-14
申请号:US10513041
申请日:2003-05-02
申请人: Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
发明人: Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
CPC分类号: C07C5/3332 , B01J21/066 , B01J23/002 , B01J23/63 , B01J35/002 , B01J35/10 , B01J35/109 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C2521/06 , Y02P20/52 , C07C11/06 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要: The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.
摘要翻译: 本发明涉及制备催化剂载体的方法,其中如果需要,二氧化锆粉末与粘合剂混合,如果需要,成孔剂如果需要,可以使用酸,水,并且如果需要,可提供另外的添加剂以得到可捏合组合物和组合物 均化,成型以产生成形体,干燥和煅烧,其中粘合剂是单体,低聚或聚合的有机硅化合物。 合适的粘合剂是单体,低聚或聚合硅烷,烷氧基硅烷,芳氧基硅烷,丙烯酰氧硅烷,肟基硅烷,卤代硅烷,氨基硅烷,氨基硅烷,酰胺基硅烷,硅氮烷或硅氧烷。 本发明还提供了以这种方式制备的催化剂载体,包含载体的催化剂及其作为脱氢催化剂的用途。
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公开(公告)号:US20060122436A1
公开(公告)日:2006-06-08
申请号:US10533959
申请日:2003-11-03
IPC分类号: C07C45/50
CPC分类号: C07C45/72 , C07C5/42 , C07C29/141 , C07C45/50 , Y02P20/125 , C07C31/125 , C07C47/02 , C07C11/06 , C07C11/08
摘要: Process for preparing saturated aliphatic Cn-aldehydes and Cn-1-alkanes, where n is from 4 to 20, which comprises a) providing a feed gas stream comprising one or more Cn-1-alkanes, b) subjecting the Cn-1-alkanes to a catalytic dehydrogenation to give a product gas stream comprising unreacted Cn-1-alkanes, one or more Cn-1-alkenes and secondary constituents, c) at least partly hydroformylating the Cn-1-alkenes in the presence of the Cn-1-alkanes and possibly the secondary constituents by means of carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to give the Cn-aldehydes, d) separating the product mixture obtained to give a stream comprising the Cn-aldehydes and a stream comprising Cn-1-alkanes and possibly secondary constituents, e) recirculating at least part of the gas stream comprising the Cn-1-alkanes and possibly the secondary constituents as recycle gas stream to the catalytic alkane dehydrogenation (step b)).
摘要翻译: 制备饱和脂肪族C n - 醛和C n-1-N烷烃的方法,其中n为4至20,其包括a)提供包含一种 或更多的C 1〜n烷烃,b)使C 1 -C 12烷烃进行催化脱氢,得到包含未反应的C n的产物气流 -1个 - 烷烃,一个或多个C n-1 - 烯烃和第二组分,c)至少部分地将C 1 -C 6 - 亚烷基 在加氢甲酰化催化剂存在下,通过一氧化碳和氢气存在C n-1 - 烷烃并且可能存在第二成分,得到C 1 -C 6烷基 ,d)将得到的产物混合物分离得到包含C 1 -C 4烷基的物流和包含C 1〜N 2烷烃的物流,并且可能是二级成分,e)循环 气流的至少一部分包含C n-1 - 烷烃,并且可能是二级的 y成分作为催化烷烃脱氢的再循环气流(步骤b))。
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8.
公开(公告)号:US20060099138A1
公开(公告)日:2006-05-11
申请号:US10532725
申请日:2003-10-27
IPC分类号: C01B7/00
CPC分类号: C01B7/0718 , C01B7/04 , C01B7/0743 , C07C263/10 , C07C265/14 , C07C265/06
摘要: Process for preparing chlorine from hydrochloric acid, which comprises the steps: a) providing a hydrochloric acid feed stream I; b) providing a hydrochloric acid recycle stream II; c) separating off a hydrogen chloride stream IV from the hydrochloric acid feed stream I and the hydrochloric acid recycle stream II in a distillation step; d) feeding the hydrogen chloride stream IV, an oxygen-containing steam V and, if desired, an oxygen-containing recycle stream Va into an oxidation zone and oxidizing hydrogen chloride to chlorine in the presence of a catalyst to give a product gas stream VI comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor; e) separating off hydrogen chloride and water from the product gas stream VI in an absorption step to give a gas stream VII and the hydrochloric acid recycle stream II; f) if desired, drying the gas stream VII; g) separating off an oxygen-containing stream from the gas stream VII and, if desired, recirculating at least part of this as oxygen-containing recycle stream Va to the oxidation zone, leaving a chlorine-containing product stream VIII; h) if desired, further purifying the chlorine-containing product stream VIII.
摘要翻译: 从盐酸制备氯的方法,其包括以下步骤:a)提供盐酸进料流I; b)提供盐酸循环流II; c)在蒸馏步骤中,从盐酸进料流I和盐酸循环流II中分离出氯化氢料流IV; d)将氯化氢流IV,含氧蒸汽V以及如果需要的话将含氧再循环流Va加入氧化区,并在催化剂存在下将氯化氢氧化成氯,得到产物气流VI 包括氯,未反应的氧,未反应的氯化氢和水蒸气; e)在吸收步骤中从产物气流VI中分离氯化氢和水,得到气流VII和盐酸再循环流II; f)如果需要,干燥气流VII; g)从气流VII中分离含氧物流,如果需要,将其至少部分再循环为含氧再循环流Va至氧化区,留下含氯产物流VIII; h)如果需要,进一步纯化含氯产物流VIII。
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公开(公告)号:US07468463B2
公开(公告)日:2008-12-23
申请号:US10591925
申请日:2005-03-04
申请人: Thorsten Johann , Oliver Löber , Eike Johannes Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
发明人: Thorsten Johann , Oliver Löber , Eike Johannes Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
IPC分类号: C07C45/65
CPC分类号: C07C45/002 , C07B2200/07 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C49/403 , C07C49/395 , C07C47/02 , C07C49/647
摘要: The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.
摘要翻译: 本发明涉及一种制备具有3至25个碳原子的光学活性醛或酮的方法和至少一种可消化的立体中心,通过在催化剂存在下在气相中相应的光学活性伯或仲醇的催化脱氢 。
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公开(公告)号:US20070191644A1
公开(公告)日:2007-08-16
申请号:US10591925
申请日:2005-03-04
申请人: Thorsten Johann , Oliver Lober , Eike Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
发明人: Thorsten Johann , Oliver Lober , Eike Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
CPC分类号: C07C45/002 , C07B2200/07 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C49/403 , C07C49/395 , C07C47/02 , C07C49/647
摘要: The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.
摘要翻译: 本发明涉及一种制备具有3至25个碳原子的光学活性醛或酮的方法和至少一种可消化的立体中心,通过在催化剂存在下在气相中相应的光学活性伯或仲醇的催化脱氢 。
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