公开(公告)号：US5741925A

公开(公告)日：1998-04-21

申请号：US782132

申请日：1997-01-13

申请人： Chung-Ling Mao ,  Francis Joseph Waller ,  Kenneth Merle Kem

发明人： Chung-Ling Mao ,  Francis Joseph Waller ,  Kenneth Merle Kem

IPC分类号： C07C67/03 ,  C07C67/10 ,  C07C69/74

CPC分类号： C07C67/10

摘要： Vinyl naphthenate monomer mixtures are prepared by transvinylation of naphthenic acid in the presence of a catalyst of a palladium carboxylate complexed with one or more aryl N-containing ligands and distilling the resulting vinyl naphthenate monomers in the presence of the catalyst at pot temperatures exceeding 80.degree. C. The catalyst is stable and can be re-used over several transvinylation reaction runs.

摘要翻译： 环烷酸乙烯酯单体混合物是通过在与一种或多种含芳基N配位体络合的羧酸钯的催化剂存在下，通过环烷酸的转化来制备的，并在催化剂存在下，在釜温超过80℃下蒸馏生成的环烷酸乙烯酯单体 C.催化剂是稳定的，可以在几个转化反应中重复使用。

公开(公告)号：US06426151B1

公开(公告)日：2002-07-30

申请号：US09243776

申请日：1999-02-03

申请人： Chung-Ling Mao ,  Kenneth Merle Kem

发明人： Chung-Ling Mao ,  Kenneth Merle Kem

IPC分类号： B32B2708

CPC分类号： C08F220/18 ,  C08F218/10 ,  C08F220/06 ,  C08F220/12 ,  C08F220/14 ,  C09J133/06 ,  C09J133/062 ,  C09J2201/606 ,  Y10T156/10 ,  Y10T428/31928

摘要： The present invention is directed to improved flexibilized, plasticized polyvinyl chloride films bonded with a substrate by means of an aqueous based pressure sensitive acrylic adhesive emulsion polymers. Conventional emulsion based pressure sensitive adhesives were comprised of a copolymer comprised of polymerized units of acrylic esters and ethylenically unsaturated monomers, the copolymer having a Tg of from −15 to −70° C. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in the incorporation of polymerized units of a vinyl C8-13 ester of a neo-acid into the adhesive. The vinyl ester is formed from a mixture of propylene oligomers and such vinyl ester is represented by the chemical formula: C8-13H7-27CO2CH═CH2. Preferably, the adhesive includes units of methyl methacrylate, butyl acrylate of 2-ethylhexyl acrylate and a carboxylic acid selected from acrylic acid or methacrylic acid.

摘要翻译： 本发明涉及通过基于水性的压敏丙烯酸粘合剂乳液聚合物与基材结合的改进的柔性增塑的聚氯乙烯膜。 常规的基于乳液的压敏粘合剂由包含丙烯酸酯和烯键式不饱和单体的聚合单元的共聚物组成，共聚物的Tg为-15至-70℃。水性乳液聚合压敏粘合剂的改进 存在于将新酸的乙烯基C8-13酯的聚合单元并入粘合剂中。 乙烯基酯由丙烯低聚物的混合物形成，这种乙烯基酯由下列化学式表示：C8-13H7-27CO2CH = CH2。 优选地，粘合剂包括甲基丙烯酸甲酯，丙烯酸2-乙基己酯的丙烯酸丁酯和选自丙烯酸或甲基丙烯酸的羧酸的单元。

公开(公告)号：US6084024A

公开(公告)日：2000-07-04

申请号：US748216

申请日：1996-11-12

申请人： Chung-Ling Mao ,  Kenneth Merle Kem

发明人： Chung-Ling Mao ,  Kenneth Merle Kem

IPC分类号： C08F218/10 ,  C08F220/12 ,  C09J131/02 ,  C09J133/06 ,  C08L31/00

CPC分类号： C08F220/18 ,  C08F218/10 ,  C08F220/12 ,  C09J133/06 ,  C09J133/062 ,  C08F220/06 ,  C08F220/14 ,  C09J2201/606 ,  Y10T156/10

摘要： The present invention is directed to improved aqueous based pressure sensitive adhesive emulsion polymers. Conventional emulsion based pressure sensitive adhesives are comprised of a copolymer comprised of polymerized units of acrylic esters and ethylenically unsaturated monomers, the copolymer having a T.sub.g of from -15 to -70.degree. C. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in the incorporation of a vinyl C.sub.8-13 ester of a neo-acid into the copolymer present in the pressure sensitive adhesives. Such vinyl ester is formed from a mixture of propylene oligomers and such vinyl ester is represented by the chemical formula C.sub.8-13 H.sub.17-27 CO.sub.2 CH.dbd.CH.sub.2.

摘要翻译： 本发明涉及改进的基于水性的压敏粘合剂乳液聚合物。 常规的基于乳液的压敏粘合剂由包含丙烯酸酯和烯属不饱和单体的聚合单元的共聚物组成，该共聚物的Tg为-15至-70℃。水性乳液聚合压敏粘合剂的改进 存在于将新酸的乙烯基C8-13酯引入存在于压敏粘合剂中的共聚物中。 这种乙烯基酯由丙烯低聚物的混合物形成，这种乙烯基酯由化学式C8-13H17-27CO2CH = CH2表示。

公开(公告)号：US5519084A

公开(公告)日：1996-05-21

申请号：US173251

申请日：1993-12-23

申请人： Helen Pak-Harvey ,  Chung-Ling Mao

发明人： Helen Pak-Harvey ,  Chung-Ling Mao

IPC分类号： C04B24/18 ,  C04B24/24 ,  C04B24/26 ,  C04B24/38 ,  C04B40/00 ,  C08J3/12 ,  C08L29/04 ,  C09D133/06

CPC分类号： C08J3/122 ,  C04B24/2641 ,  C04B40/0042 ,  C09D133/064 ,  C08J2333/06 ,  C08L29/04

摘要： A method for preparing an acrylic polymer powder which is redispersible in water by atomizing an aqueous polymer dispersion containing a dispersing aid, the improvement which comprises employing an acrylic polymer containing 1-15 wt % olefinically unsaturated carboxylic acid comonomer and an effective amount of a dispersing aid consisting essentially of polyvinyl alcohol.

摘要翻译： 一种制备丙烯酸聚合物粉末的方法，其通过雾化含有分散助剂的聚合物水分散体水分再分散在水中，其改进包括使用含有1-15重量％烯属不饱和羧酸共聚单体的丙烯酸聚合物和有效量的分散体 助剂基本上由聚乙烯醇组成。

公开(公告)号：US4225645A

公开(公告)日：1980-09-30

申请号：US956703

申请日：1978-11-01

申请人： Chung-Ling Mao ,  Walter Nudenberg

发明人： Chung-Ling Mao ,  Walter Nudenberg

IPC分类号： C08K5/02 ,  C08K5/3492 ,  C08K13/02 ,  C08L75/04 ,  D06M11/47 ,  D06M15/564 ,  D06M17/10 ,  C08K5/34

CPC分类号： D06M17/10 ,  C08K13/02 ,  C08K5/02 ,  C08K5/34922 ,  C08L75/04 ,  D06M11/47 ,  D06M15/564 ,  Y10T442/2049 ,  Y10T442/2656 ,  Y10T442/2861

摘要： This invention relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.

摘要翻译： 本发明涉及由弹性体聚氨酯预聚物获得的阻燃交联弹性体组合物; 含有氯和/或溴的有机阻燃添加剂; 锑的化合物; 和六烷氧基甲基三聚氰胺。 这些新的组合物是自熄的以及不滴水的。

公开(公告)号：US4049636A

公开(公告)日：1977-09-20

申请号：US661212

申请日：1976-02-25

申请人： Chung-Ling Mao ,  Francis X. O'Shea

发明人： Chung-Ling Mao ,  Francis X. O'Shea

IPC分类号： C08G18/00 ,  C08G18/12 ,  C08G18/40 ,  C08G18/63 ,  C08G18/65 ,  C08G18/04

CPC分类号： C08G18/6564 ,  C08G18/12 ,  C08G18/4072 ,  C08G18/632 ,  Y10S528/906

摘要： Flexible automobile exterior body parts are molded from a polyurethane elastomer prepared from a reaction mixture comprising:A. a poly(oxypropylene)-poly(oxyethylene) glycol of molecular weight of from about 1500 to about 4000 containing 15 to 50% by weight oxyethylene groups;B. a "graft" polyol of molecular weight from about 2500 to about 4500, prepared by the in situ polymerization of one or more ethylenically unsaturated monomers in a poly(oxypropylene) and/or poly(oxypropylene)-poly(oxyethylene) glycol containing less than 15% by weight oxyethylene groups;C. methylenebis(4-phenylisocyanate);D. 1,4-butanediol.The invention also relates to this polyurethane elastomer.

摘要翻译： 柔性汽车外部身体部件由由反应混合物制备的聚氨酯弹性体成型，包括：

公开(公告)号：US4041105A

公开(公告)日：1977-08-09

申请号：US661595

申请日：1976-02-26

申请人： Francis X. O'Shea ,  Chung-Ling Mao

发明人： Francis X. O'Shea ,  Chung-Ling Mao

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/63 ,  C08G18/65

CPC分类号： C08G18/6564 ,  C08G18/10 ,  C08G18/632 ,  C08G2120/00

摘要： Flexible automobile exterior body parts are molded from a polyurethane elastomer prepared from a reaction mixture comprising:A. a "graft" polyol prepared by the in situ polymerization of one or more ethylenically unsaturated monomers in a poly(oxypropylene)-poly(oxyethylene) glycol of molecular weight from about 1750 to about 4000 and containing from 15 to 50% oxyethylene groups by weight,B. methylenebis(4-phenylisocyanate),C. 1,4-butanediol.

摘要翻译： 柔性汽车外部身体部件由由反应混合物制备的聚氨酯弹性体模制成，包括：

公开(公告)号：US4698384A

公开(公告)日：1987-10-06

申请号：US831015

申请日：1986-02-19

申请人： Chung-Ling Mao

发明人： Chung-Ling Mao

IPC分类号： C08F2/16 ,  C08F218/08

CPC分类号： C08F218/08

摘要： A copolymer emulsion for bonding nonwoven products comprising an aqueous medium having colloidally dispersed therein a copolymer consisting essentially of vinyl acetate, 5-35 wt % ethylene and 2 to 10 wt % of an amide functional crosslinking comonomer which is N-methylolacrylamide or a compound of the formula R--NH--(CH.sub.2).sub.n --CH(OR').sub.2 where R is (meth)acryloyl, R' is a C.sub.1 -C.sub.4 alkyl group and n is 3 or 4, the copolymer emulsion prepared in the presence of 0.1 to 1 wt % polyvinyl pyrrolidone, based on vinyl acetate in the copolymer. Such emulsion binder copolymers demonstrate improved solvent resistance.

摘要翻译： 一种用于粘合非织造产品的共聚物乳液，其包含胶体分散在其中的水性介质，所述共聚物乳液基本上由乙酸乙烯酯，5-35重量％乙烯和2-10重量％的作为N-羟甲基丙烯酰胺的酰胺官能交联共聚单体组成的共聚物或 式R-NH-（CH2）n-CH（OR'）2其中R是（甲基）丙烯酰基，R'是C1-C4烷基，n是3或4，在0.1的存在下制备的共聚物乳液 至1重量％的聚乙烯吡咯烷酮，基于共聚物中的乙酸乙烯酯。 这种乳液粘合剂共聚物显示出改善的耐溶剂性。

公开(公告)号：US4147678A

公开(公告)日：1979-04-03

申请号：US796585

申请日：1977-05-13

申请人： Chung-Ling Mao ,  Walter Nudenberg

发明人： Chung-Ling Mao ,  Walter Nudenberg

IPC分类号： C08G18/00 ,  C08K5/02 ,  C08K5/34 ,  C08K13/02 ,  C08L75/00 ,  C08L75/04 ,  C08K3/38

CPC分类号： C08L75/04 ,  C08K13/02 ,  C08K5/02 ,  Y10S521/906

摘要： This inventon relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.

摘要翻译： 本发明涉及由弹性体聚氨酯预聚物获得的阻燃交联弹性体组合物; 含有氯和/或溴的有机阻燃添加剂; 锑的化合物; 和六烷氧基甲基三聚氰胺。 这些新的组合物是自熄的以及不滴水的。

公开(公告)号：US4108868A

公开(公告)日：1978-08-22

申请号：US552497

申请日：1975-02-24

申请人： Chung-Ling Mao

发明人： Chung-Ling Mao

IPC分类号： C07D333/48 ,  C07D333/66 ,  C08G18/10 ,  C08G18/38 ,  C08K5/05

CPC分类号： C07D333/48 ,  C07D333/66 ,  C08G18/10 ,  C08G18/3874

摘要： Chain extended polyurethanes are prepared, using certain 3-(hydroxyhydrocarbylsecondaryamino)thiophene 1,1-dioxides, some of which are new chemicals. E.g., 3-(2-hydroxypropylamino)tetrahydrothiophene 1,1-dioxide is especially useful as a chain extender for high resiliency, flexible polyurethane foams.

摘要翻译： 使用某些3-（羟基烃基二仲氨基）噻吩1,1-二氧化物制备扩链聚氨酯，其中一些是新的化学物质。 例如，3-（2-羟基丙基氨基）四氢噻吩1,1-二氧化物特别可用作高弹性的增链剂，柔性聚氨酯泡沫。