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公开(公告)号：US5401478A
公开(公告)日：1995-03-28
申请号：US100940
申请日：1993-08-03
IPC分类号： B01D53/86 , B01D53/94 , B01J23/68 , B01J23/888 , B01J23/889 , C01B21/02 , C01B21/20
CPC分类号： C01B21/02 , B01D53/8628 , B01D53/9418 , B01J23/683 , B01J23/687 , B01J23/888 , B01J23/8892 , B01D2251/2062 , B01D2255/20715 , B01D2255/20776
摘要： There is provided a catalytic method for converting nitrogen oxides to nitrogen (i.e., N.sub.2). The catalyst for this method comprises an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this catalyst is zirconia, modified with tungstate. This method may be used for reducing emissions of nitrogen oxides from waste gases, including industrial exhaust gases and automobile exhaust gases. In a particular embodiment, nitrogen oxides in waste gases may be reacted with ammonia before the waste gases are discharged to the atmosphere.
摘要翻译： 提供了将氮氧化物转化为氮气（即N 2）的催化方法。 用于该方法的催化剂包括酸性固体组分，其包含用VIB族金属的氧阴离子改性的IVB族金属氧化物。 该催化剂的实例是用钨酸盐改性的氧化锆。 该方法可用于减少来自废气（包括工业废气和汽车废气）的氮氧化物的排放。 在一个具体实施方案中，废气中的氮氧化物可以在废气排放到大气中之前与氨反应。
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公开(公告)号：US5552128A
公开(公告)日：1996-09-03
申请号：US410156
申请日：1995-03-24
申请人： Clarence D. Chang , Jose G. Santiesteban , David S. Shihabi , Scott A. Stevenson , James C. Vartuli
发明人： Clarence D. Chang , Jose G. Santiesteban , David S. Shihabi , Scott A. Stevenson , James C. Vartuli
IPC分类号： B01D53/86 , B01D53/94 , B01J23/68 , B01J23/888 , B01J23/889 , C01B21/02 , B01D53/56
CPC分类号： B01D53/8628 , B01D53/9413 , B01J23/683 , B01J23/687 , B01J23/888 , B01J23/8892 , C01B21/02
摘要： There is provided a catalytic method for converting nitrogen oxides to nitrogen (i.e., N.sub.2). The catalyst for this method comprises an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal and further comprising at least one metal selected from the group consisting of Group IB, Group IVA, Group VB, Group VIIB, Group VIII, and mixtures thereof. An example of this catalyst is zirconia, modified with tungstate, and iron. This method may be used for reducing emissions of nitrogen oxides from waste gases, including industrial exhaust gases and automobile exhaust gases. In a particular embodiment, nitrogen oxides in waste gases may be reacted with ammonia before the waste gases are discharged to the atmosphere.
摘要翻译： 提供了将氮氧化物转化为氮气（即N 2）的催化方法。 用于该方法的催化剂包括酸性固体组分，其包含用VIB族金属的氧阴离子改性的IVB族金属氧化物，并且还包含选自组IB，组IVA，组VB，组VIIB的至少一种金属， VIII族及其混合物。 该催化剂的实例是用钨酸盐和铁改性的氧化锆。 该方法可用于减少来自废气（包括工业废气和汽车废气）的氮氧化物的排放。 在一个具体实施方案中，废气中的氮氧化物可以在废气排放到大气中之前与氨反应。
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3.发明授权Double bond isomerization of olefin-containing feeds with minimal oligomertization using surface acidity deactivated zeolite catalysts 失效使用表面酸性去活化沸石催化剂的含极少量含有烯烃的进料双重结合异构化
公开(公告)号：US5237120A
公开(公告)日：1993-08-17
申请号：US813717
申请日：1991-12-27
CPC分类号： B01J29/06 , B01J29/7042 , B01J29/7046 , B01J31/0254 , C07C5/2518 , B01J2229/123 , B01J2229/34 , B01J2231/52 , B01J29/40 , B01J29/65
摘要： A method is disclosed for the double bond isomerization of alpha olefin-containing feeds, e.g., conversion of 1-butene-containing hydrocarbon streams to 2-butene-rich product streams, wherein oligomer by-products are minimized. The process uses a catalyst composition comprising a zeolite whose surface has been at least partially deactivated for acid catalyzed reactions by chemisorption of a surface-deactivating agent, e.g., collidine, which possesses an average cross section diameter greater than that of the zeolite pores.
摘要翻译： 公开了用于含α烯烃的进料的双键异构化的方法，例如将含1-丁烯的烃流转化为富含2-丁烯的产物流，其中低聚物副产物最小化。 该方法使用包含沸石的催化剂组合物，所述催化剂组合物的表面已被至少部分失活用于酸催化反应，通过化学吸附具有大于沸石孔的平均截面直径的表面活性剂例如可力丁，可力丁等。
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公开(公告)号：US06224748B1
公开(公告)日：2001-05-01
申请号：US08169107
申请日：1993-12-20
IPC分类号： C10G4702
CPC分类号： C07C5/2724 , B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C01P2002/54 , C07C5/2791 , C10G2400/10 , C07C9/00 , C07C9/16
摘要： A process for hydrocracking heavy, high aromatic content feeds, such as cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal.
摘要翻译： 使用包含氢化/脱氢组分如贵金属的催化剂组合物和包含用氧阴离子改性的IVB族金属氧化物的酸性固体组分加氢裂化重质，高芳族化合物进料如循环油的方法， VIB族金属。
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公开(公告)号：US5608133A
公开(公告)日：1997-03-04
申请号：US551873
申请日：1995-10-23
IPC分类号： B01J23/30 , B01J21/06 , B01J23/24 , C07B61/00 , C07C2/02 , C07C2/14 , C07C11/02 , C10G50/00 , C10G50/02 , C10G69/12 , C10L1/16 , C10L10/08 , C10M107/02
CPC分类号： B01J21/066 , B01J21/06 , B01J23/24 , C07C2/14 , C10G50/00 , C10G50/02 , C10G69/126 , C07C2521/06 , C07C2527/00
摘要： There is provided a catalytic oligomerization process. The process involves the use of a catalyst comprising an acidic solid. The acidic solid may comprise a Group IVB metal oxide, such as zirconia, modified with an oxyanion of a Group VIB metal, such as tungsten. The oligomers produced by this process may be hydrogenated to produce thermally stable lubricants and lubricant additives, gasoline and diesel.
摘要翻译： 提供催化低聚方法。 该方法包括使用包含酸性固体的催化剂。 酸性固体可以包含用VIB族金属如钨的氧阴离子改性的IVB族金属氧化物，例如氧化锆。 通过该方法生产的低聚物可以被氢化以产生热稳定的润滑剂和润滑剂添加剂，汽油和柴油。
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公开(公告)号：US5543036A
公开(公告)日：1996-08-06
申请号：US167108
申请日：1993-12-16
IPC分类号： B01J21/06 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , C01G25/02 , C07C5/27 , C10G67/04 , C10G17/00 , C10G17/095 , C10G45/04
CPC分类号： B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C07C5/2724 , C07C5/2791 , C01P2002/54 , C10G2400/10
摘要： A process for hydrotreating a hydrocarbon feedstock, such as light cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. The hydrotreating process removes contaminants, such as sulfur and/or nitrogen, from the feedstock.
摘要翻译： 使用包含氢化/脱氢组分的催化剂组合物和包含用VIB族金属的氧阴离子改性的IVB族金属氧化物的酸性固体组分对烃原料如轻质循环油进行加氢处理的方法。 加氢处理工艺从原料中除去污染物，如硫和/或氮。
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公开(公告)号：US6114551A
公开(公告)日：2000-09-05
申请号：US412773
申请日：1999-10-04
IPC分类号： B01J29/89 , C01B39/06 , C07D301/19 , C07D303/04 , C07D305/00
CPC分类号： C07D301/19 , B01J29/89 , B01J2229/16 , B01J2229/183 , B01J2229/32 , B01J29/7038
摘要： A method of synthesizing an olefin epoxidation catalyst comprises the step of treating a porous crystalline aluminosilicate material having an X-ray diffraction pattern including d-spacing maxima at 12.4.+-.0.25, 6.9.+-.0.15, 3.57.+-.0.07 and 3.42.+-.0.07 Angstrom, such as MCM-22, with a dealuminating agent under conditions effective to remove framework aluminium from the material and produce a dealuminated product. The dealuminated product is then treated with a titanium-containing material under conditions effective to insert titanium into the dealuminated product and produce a titanium-containing, dealuminated catalyst composition.The resultant catalyst is useful in the epoxidation of olefins, such as propylene and cyclohexene, with hydrogen peroxide and organic hydroperoxides.
摘要翻译： 合成烯烃环氧化催化剂的方法包括以下步骤：处理多晶结晶硅铝酸盐材料，该多晶结晶硅铝酸盐材料具有包含d间距最大值的X射线衍射图，为12.4 +/- 0.25,6.9 +/- 0.15,3.57 +/- 0.07和3.42 +/- 0.07埃，例如MCM-22，在有效从材料中除去骨架铝并产生脱铝产品的条件下用脱铝剂。 然后在有效地将钛插入脱铝产品中并且生产含钛脱铝催化剂组合物的条件下，用含钛材料处理脱铝产品。 得到的催化剂可用于烯烃如丙烯和环己烯与过氧化氢和有机氢过氧化物的环氧化。
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公开(公告)号：US6080904A
公开(公告)日：2000-06-27
申请号：US728395
申请日：1996-10-09
CPC分类号： C07C5/2724 , C07C5/2791 , C07C2523/14 , C07C2523/42
摘要： There is provided an isomerization process using a catalyst comprising a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this catalyst is zirconia, modified with tungstate and platinum. This catalyst is used to isomerize, for example, C.sub.4 to C.sub.8 paraffins. The feed to this paraffin isomerization reaction may, optionally, include cyclic hydrocarbons, such as benzene or cyclohexane, which may undergo ring opening reactions during the course of the isomerization reaction.
摘要翻译： 提供使用包含氢化/脱氢组分如贵金属的催化剂和包含用VIB族金属的氧阴离子改性的IVB族金属氧化物的酸性固体组分的异构化方法。 该催化剂的实例是用钨酸盐和铂改性的氧化锆。 该催化剂用于异构化例如C 4至C 8链烷烃。 这种链烷烃异构化反应的进料可以任选地包括在异构化反应过程中可能经历开环反应的环烃，例如苯或环己烷。
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公开(公告)号：US6008399A
公开(公告)日：1999-12-28
申请号：US266623
申请日：1999-03-11
IPC分类号： C07C68/00
CPC分类号： C07C68/00
摘要： A process for preparing organic carbonates, such as dimethyl carbonate, without the use of phosgene and with a high yield and selectivity to the desired carbonate, by reacting a formaldehyde-acetal with a source of oxygen, in the presence of a catalyst.
摘要翻译： 在催化剂存在下，通过使甲醛缩醛与氧源反应，制备有机碳酸酯如碳酸二甲酯的方法，而不使用光气，并且对所需碳酸酯具有高产率和选择性。
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公开(公告)号：US5780382A
公开(公告)日：1998-07-14
申请号：US509717
申请日：1995-07-31
IPC分类号： B01J21/06 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/38 , B01J23/42 , B01J23/652 , B01J32/00 , B01J37/02 , B01J37/08 , C01G25/02 , C01G41/00 , C07C5/27 , C07C9/12 , C07C9/16 , C10G67/04 , B01J23/16 , B01J23/22
CPC分类号： C07C5/2724 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C01G41/00 , C07C5/2791 , C01P2002/54 , C10G2400/10
摘要： There is provided a method for preparing an acidic solid comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this acidic solid is zirconia, modified with tungstate. This modified solid oxide may be used as a catalyst, for example, to isomerize C.sub.4 to C.sub.8 paraffins. The method for preparing this acidic solid involves contacting a hydrated oxide of a Group IVB metal under hydrothermal conditions, such as reflux conditions, prior to contact of the hydrated oxide with an aqueous solution comprising a source of an oxyanion of a Group VIB metal.
摘要翻译： 提供了一种制备酸性固体的方法，该酸性固体包含用VIB族金属的氧阴离子改性的ⅣB族金属氧化物。 这种酸性固体的一个例子是用钨酸盐改性的氧化锆。 该改性的固体氧化物可以用作催化剂，例如使C4至C8链烷烃异构化。 制备该酸性固体的方法包括在水合氧化物与包含VIB族金属的氧阴离子源的水溶液接触之前，在水热条件如回流条件下使IVB族金属的水合氧化物接触。
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