Nickel metal hydride battery design
    1.
    发明申请
    Nickel metal hydride battery design 有权
    镍氢电池设计

    公开(公告)号:US20050238959A1

    公开(公告)日:2005-10-27

    申请号:US10887434

    申请日:2004-07-08

    摘要: The present invention relates to rechargeable nickel metal hydride batteries and methods for making the same. More particularly, the present invention relates to rechargeable nickel metal hydride batteries having a precharge in the negative electrode sufficient for oxidation prevention in the negative electrode. The present invention discloses a nickel metal hydride battery, wherein the precharge of the negative electrode may be supplied by a variety of sources. The positive active material of the positive electrode may have positive active particles, such as nickel hydroxide, having a precursor coating that incorporates cobalt material capable of forming a conductive network. Sources other than cobalt-containing materials in the positive electrode include hydrogen gas provided directly to the negative active material, nickel aluminum mixed with the negative active material, the etching of the negative active material with an alkaline solution and borohydride chemically charging the negative active material. Preferably, a majority of the precharge of the negative electrode is supplied by sources other than cobalt-containing materials in the positive electrode.

    摘要翻译: 本发明涉及可再充电镍氢电池及其制造方法。 更具体地说,本发明涉及在负极中具有足以在负极中进行氧化防止的预充电的可充电镍金属氢化物电池。 本发明公开了一种镍金属氢化物电池,其中负极的预充电可以由各种源提供。 正极的正极活性材料可以具有正的活性颗粒,例如氢氧化镍,其具有引入可形成导电网络的钴材料的前体涂层。 来自正极中的含钴材料以外的源包括直接设置在负极活性物质上的氢气,与负极活性物质混合的镍铝,用碱性溶液腐蚀负极活性物质和化学充电负极活性物质的硼氢化物 。 优选地,负极的大部分预充电由正极中的含钴材料以外的源供给。

    Process for making nickel hydroxide
    3.
    发明申请
    Process for making nickel hydroxide 有权
    制造氢氧化镍的方法

    公开(公告)号:US20050123469A1

    公开(公告)日:2005-06-09

    申请号:US10727413

    申请日:2003-12-04

    IPC分类号: C01G53/04 C01B17/96 C01G51/02

    摘要: A preferred embodiment of the present invention provides a process for making nickel sulfate by converting nickel metal into nickel sulfate, which may be converted to nickel hydroxide. Nickel metal is dissolved in sulfuric acid and oxygen containing gas is introduced to produce a nickel sulfate solution having nickel sulfate and water as illustrated in the following chemical equation. Ni+H2SO4+½O2→NiSO4+H2O The nickel sulfate is filtered and sulfuric acid is continually added to maintain stoichiometry within a reactor until the nickel metal is dissolved. The sulfuric acid, oxygen containing gas and nickel metal may be heated to facilitate the desired reaction. Then, the nickel sulfate may be utilized to produce nickel hydroxide.

    摘要翻译: 本发明的优选实施方案提供了一种通过将镍金属转化成硫酸镍制备硫酸镍的方法,其可以转化为氢氧化镍。 将镍金属溶解在硫酸中,并引入含氧气体以产生具有硫酸镍和水的硫酸镍溶液,如以下化学方程所示。 <?in-line-formula description =“In-line Formulas”end =“lead”?> Ni + H 2 SO 2 4 + 1/2 O 2 < 硫酸镍(H 2 O 3)2 H 2 O 2&lt;&lt;直线公式描述=“内联式”末端=“尾”→硫酸镍 过滤并持续加入硫酸以在反应器内保持化学计量,直到镍金属溶解。 可以加热硫酸,含氧气体和镍金属以促进所需的反应。 然后,可以使用硫酸镍制造氢氧化镍。

    Mg-Ni hydrogen storage composite having high storage capacity and excellent room temperature kinetics
    10.
    发明申请
    Mg-Ni hydrogen storage composite having high storage capacity and excellent room temperature kinetics 审中-公开
    具有高储存容量和优异的室温动力学的Mg-Ni储氢复合材料

    公开(公告)号:US20060266441A1

    公开(公告)日:2006-11-30

    申请号:US11497449

    申请日:2006-08-02

    IPC分类号: C22C45/04

    摘要: A hydrogen storage alloy having an atomically engineered microstructure that both physically and chemically absorbs hydrogen. The atomically engineered microstructure has a predominant volume of a first microstructure which provides for chemically absorbed hydrogen and a volume of a second microstructure which provides for physically absorbed hydrogen. The volume of the second microstructure may be at least 5 volume % of atomically engineered microstructure. The atomically engineered microstructure may include porous micro-tubes in which the porosity of the micro-tubes physically absorbs hydrogen. The micro-tubes may be at least 5 volume % of the atomically engineered microstructure. The micro-tubes may provide proton conduction channels within the bulk of the hydrogen storage alloy and the proton conduction channels may be at least 5 volume % of the atomically engineered microstructure.

    摘要翻译: 具有物理和化学吸收氢的原子工程微结构的储氢合金。 原子工程化的微结构具有主要体积的第一微结构,其提供化学吸收的氢和提供物理吸收的氢的第二微结构体积。 第二微结构的体积可以是原子工程化微结构的至少5体积%。 原子工程化的微结构可以包括其中微管的孔隙物理吸收氢的多孔微管。 微管可以是原子工程微结构的至少5体积%。 微管可以在储氢合金的体积内提供质子传导通道,并且质子传导通道可以是原子工程微结构的至少5体积%。