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    POLYESTER - POLYURETHANE ELASTOMERS FROM RENEWABLE SOURCES
    1.
    发明申请
    POLYESTER - POLYURETHANE ELASTOMERS FROM RENEWABLE SOURCES 审中-公开
    聚酯 - 可再生来源的聚氨酯弹性体

    公开(公告)号：US20150141609A1

    公开(公告)日：2015-05-21

    申请号：US14396232

    申请日：2013-06-25

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Giuseppe Lista ,  Luciano Zanacchi

    IPC: C08G18/32 ,  C08G18/72

    CPC classification number: C08G18/3221 ,  C08G18/10 ,  C08G18/4238 ,  C08G18/664 ,  C08G18/72

    Abstract: Embodiments of the invention encompass polyurethane elastomers which are a reaction product of a reaction mixture that includes a) at least one polyester made using a dicarboxylic acid having a carbon chain of from 9 to 20; b) at least one chain extender; and c) at least one polyisocyanate. At least 20% of the total carbon content of the polyurethane elastomer is from renewable carbon.

    Abstract translation: 本发明的实施方案包括作为反应混合物的反应产物的聚氨酯弹性体，其包括a）使用碳链为9至20的二羧酸制备的至少一种聚酯; b）至少一种扩链剂; 和c）至少一种多异氰酸酯。 聚氨酯弹性体的总碳含量的至少20％来自可再生碳。

    POLYOL FORMULATIONS FOR IMPROVED GREEN STRENGTH OF POLYISOCYANURATE RIGID FOAMS
    2.
    发明申请
    POLYOL FORMULATIONS FOR IMPROVED GREEN STRENGTH OF POLYISOCYANURATE RIGID FOAMS 审中-公开
    用于改善聚异氰酸酯刚性纤维素的强度的多酚配方

    公开(公告)号：US20140186611A1

    公开(公告)日：2014-07-03

    申请号：US14119199

    申请日：2012-05-21

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Michael J. Skowronski ,  Kelly R. Flaherty ,  Jorge Jimenez ,  Woo-Sung Bae ,  Giuseppe Lista

    IPC: C08G63/668 ,  B32B5/20 ,  C08G18/00

    CPC classification number: C08G63/668 ,  B32B5/20 ,  C08G18/00 ,  C08G18/092 ,  C08G18/1816 ,  C08G18/225 ,  C08G18/4018 ,  C08G18/4252 ,  C08G18/48 ,  C08G18/4829 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2105/02 ,  C08J9/146 ,  C08J2375/06 ,  Y10T428/249953

    Abstract: Polyesters and polyol formulations comprising polyesters used in the preparation of polyisocyanurate rigid foams with improved green strength properties are provided. In some embodiments, a polyester which is the reaction product of (a) an aromatic component comprising 80 mole percent or greater of terephthalic acid, (b) at least one polyether polyol having a nominal functionality of 2, a molecular weight of 150 to 1,000 and a polyoxyethylene content of at least 70% by weight of the polyether polyol, (c) at least one glycol different than (b) having a nominal functionality of 2 and a molecular weight from 60 to 250, and (d) at least one polyol having a molecular weight of 60 to 250 and a nominal functionality of at least 3, wherein (a), (b), (c), and (d) are present in the reaction on a percent weight basis of 20 to 60 weight percent of (a), 20 to 50 weight percent of (b), 10 to 30 weight percent of (c), and 5 to 20 weight percent of (d) is provided.

    Abstract translation: 提供了包含用于制备具有改善的生坯强度性能的聚异氰脲酸酯刚性泡沫体的聚酯的聚酯和多元醇配方。 在一些实施方案中，聚酯是（a）包含80摩尔％或更多对苯二甲酸的芳族组分的反应产物，（b）至少一种标称官能度为2的聚醚多元醇，分子量为150至1,000 和聚醚多元醇的至少70重量％的聚氧乙烯含量，（c）至少一种不同于具有标称官能度为2且分子量为60至250的（b）的二元醇，和（d）至少一种 分子量为60〜250，标称官能度为3以上的多元醇，其中（a），（b），（c）和（d）以20〜60重量％的重量％存在于反应中 （a）的百分比，（b）的20〜50重量％，（c）的10〜30重量％和（d）的5〜20重量％。

    Toluene diisocyanate biuret based prepolymers for polyurethane foams
    3.
    发明授权
    Toluene diisocyanate biuret based prepolymers for polyurethane foams 有权

    公开(公告)号：US10730996B2

    公开(公告)日：2020-08-04

    申请号：US15762208

    申请日：2016-06-27

    Applicant: Dow Global Technologies LLC

    Inventor： Giuseppe Lista ,  Alessandra Mosca

    IPC: C08G18/08 ,  C08G18/12 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/72 ,  C08G18/76 ,  C08G18/78 ,  C08J9/00 ,  C08K5/1565 ,  C08G101/00

    Abstract: Polyurethane foams including a polyurethane prepolymer composition, a catalyst, and a propellant are provided. The polyurethane prepolymer composition is produced from a formulation that includes an isocyanate reactive component in an amount of from about 1% to about 70% by weight based on the polyurethane prepolymer composition and an isocyanate component in an amount of from about 1% to about 70% by weight based on the polyurethane prepolymer composition. The isocyanate component includes toluene diisocyanate biuret in an amount of from about 1 to about 100% by weight based on the isocyanate component. The isocyanate reactive component includes one or more polyols. The polyurethane prepolymer composition has a viscosity of less than about 10,000 mPa*s at 50° C. and is substantially free of monofunctional reactive components. The polyurethane prepolymer composition also includes a free isocyanate monomer content of the toluene diisocyanate biuret of less than about 1% by weight.

    Polyurethane mats
    4.
    发明授权
    Polyurethane mats 有权

    公开(公告)号：US10316132B2

    公开(公告)日：2019-06-11

    申请号：US15507608

    申请日：2015-09-02

    Applicant: Dow Italia Divisione Commerciale SRL ,  Dow Global Technologies LLC

    Inventor： Carlo Cocconi ,  Giuseppe Lista ,  Silvia Scussolin

    IPC: C08G18/48 ,  C08G18/76 ,  C08G18/10 ,  B60N3/04 ,  C08G18/66 ,  C08G18/72 ,  C08G18/80

    Abstract: A polyurethane elastomer, e.g., for use in polyurethane mats, includes the reaction product of an isocyanate component that includes at least one isocyanate and an isocyanate-reactive component that includes (a) a first polyol component including from 40 wt % to 90 wt % of at least one polyether polyol having an average hydroxyl functionality that is greater than 2.5 and a number average molecular weight from 300 g/mol to 1,500 g/mol; (b) a second polyol component including from 2 wt % to 20 wt % of at least one ethylene oxide capped polyoxypropylene-polyoxyethylene polyol having an average hydroxyl functionality greater than 1.5 and less than 4.0, a number average molecular weight from 4,000 g/mol to 6,000 g/mol, and from 60% to 85% of a primary hydroxyl group content; and (c) a third polyol component including from 1 wt % to 20 wt % of at least one polyoxypropylene polyol having an average hydroxyl functionality greater than 1.5 and less than 4.0 and a number average molecular weight from 300 g/mol to 1,500 g/mol.

    Aromatic polyesters, polyol blends comprising the same and resultant products therefrom
    5.
    发明授权
    Aromatic polyesters, polyol blends comprising the same and resultant products therefrom 有权
    芳族聚酯，包含其的多元醇共混物和由此产生的产物

    公开(公告)号：US08912245B2

    公开(公告)日：2014-12-16

    申请号：US13930942

    申请日：2013-06-28

    Applicant: Dow Global Technologies LLC

    Inventor： Giuseppe Lista

    IPC: C08G18/00 ,  C08J9/04 ,  C08G18/42 ,  C08G101/00

    CPC classification number: C08J9/04 ,  C08G18/4213 ,  C08G18/4252 ,  C08G2101/0025

    Abstract: The present invention discloses low viscosity aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising at 80 mole percent or greater of terephthalic acid; B) polyethylene glycol having a molecular weight from 150 to 1000; and C) a glycol different from the glycol of B); wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 40 to 75 weight percent of B); and 0 to 40 weight percent of C).

    Abstract translation: 本发明公开了适用于与其它多元醇或其它与聚酯多元醇相容的材料共混以获得聚氨酯和聚异氰尿酸酯产品的低粘度芳族聚酯多元醇。 特别地，本发明公开了包含以下反应的聚酯多元醇：A）包含80摩尔％或更多对苯二甲酸的芳族组分; B）分子量为150〜1000的聚乙二醇; 和C）不同于B）的二醇的二醇; 其中A，B和C以20至60重量％的A）的重量百分比存在于反应中; 40至75重量％的B）; 和0〜40重量％的C）。

    AROMATIC POLYESTERS, POLYOL BLENDS COMPRISING THE SAME AND RESULTANT PRODUCTS THEREFROM
    8.
    发明申请
    AROMATIC POLYESTERS, POLYOL BLENDS COMPRISING THE SAME AND RESULTANT PRODUCTS THEREFROM 有权
    芳香族聚酯，包括其的多元醇混合物及其生物产物

    公开(公告)号：US20130289151A1

    公开(公告)日：2013-10-31

    申请号：US13930942

    申请日：2013-06-28

    Applicant: Dow Global Technologies LLC

    Inventor： Giuseppe Lista

    IPC: C08J9/04

    CPC classification number: C08J9/04 ,  C08G18/4213 ,  C08G18/4252 ,  C08G2101/0025

    Abstract: The present invention discloses low viscosity aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising at 80 mole percent or greater of terephthalic acid; B) polyethylene glycol having a molecular weight from 150 to 1000; and C) a glycol different from the glycol of B); wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 40 to 75 weight percent of B); and 0 to 40 weight percent of C).

    Abstract translation: 本发明公开了适用于与其它多元醇或其它与聚酯多元醇相容的材料共混以获得聚氨酯和聚异氰尿酸酯产品的低粘度芳族聚酯多元醇。 特别地，本发明公开了包含以下反应的聚酯多元醇：A）包含80摩尔％或更多对苯二甲酸的芳族组分; B）分子量为150〜1000的聚乙二醇; 和C）不同于B）的二醇的二醇; 其中A，B和C以20至60重量％的A）的重量百分比存在于反应中; 40至75重量％的B）; 和0〜40重量％的C）。

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