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1.发明授权Hydrothermal pretreatment for increasing average pore size in a catalyst support 失效用于增加催化剂载体中平均孔径的水热预处理公开(公告)号：US06958309B2
公开(公告)日：2005-10-25
申请号：US10210353
申请日：2002-08-01
IPC分类号： B01J21/06 , B01J23/40 , B01J23/63 , B01J23/74 , B01J35/00 , B01J35/10 , B01J37/02 , B01J37/10 , C01B3/38 , C01B3/40 , B01J23/00 , B01J23/42 , B01J23/44 , B01J23/56
CPC分类号： B01J23/40 , B01J21/06 , B01J21/066 , B01J23/63 , B01J23/74 , B01J35/002 , B01J35/10 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0205 , B01J37/10 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/1047 , C01B2203/1082 , Y02P20/52
摘要： A pretreatment method for increasing the average pore size of a catalyst support is disclosed which increases the diffusivity and effectiveness factor η. The pretreatment method includes calcining the support in moisturized air at an elevated temperature sufficient to increase the average pore size. In some embodiments, the support may be treated with an acidic/basic solution prior to the calcination step. Alternatively, the calcination step may occur in a gas mixture including water/air/acidic (or basic) gases.
摘要翻译： 公开了一种用于增加催化剂载体的平均孔径的预处理方法，其增加了扩散系数和有效因子η。 预处理方法包括在足以增加平均孔径的高温下煅烧保湿空气中的载体。 在一些实施方案中，可以在煅烧步骤之前用酸性/碱性溶液处理载体。 或者，煅烧步骤可以在包括水/空气/酸性（或碱性）气体的气体混合物中发生。
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公开(公告)号：US06946114B2
公开(公告)日：2005-09-20
申请号：US09946305
申请日：2001-09-05
申请人： Joe D. Allison , Larry D. Swinney , Tianyan Niu , Kevin L. Ricketson , Daxiang Wang , Sriram Ramani , Gloria I. Straguzzi , David M. Minahan , Harold A. Wright , Baili Hu
发明人： Joe D. Allison , Larry D. Swinney , Tianyan Niu , Kevin L. Ricketson , Daxiang Wang , Sriram Ramani , Gloria I. Straguzzi , David M. Minahan , Harold A. Wright , Baili Hu
CPC分类号： C01B3/40 , B01J23/63 , B01J35/04 , B01J37/0205 , C01B3/386 , C01B2203/0261 , C01B2203/1017 , C01B2203/1023 , C01B2203/1041 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , Y02P20/52
摘要： Lanthanide-promoted rhodium-containing supported catalysts that are active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and high efficiency processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises highly dispersed, high surface area rhodium on a granular zirconia support with an intermediate coating of a lanthanide metal and/or oxide thereof and is thermally conditioned during catalyst preparation. In a preferred syngas production process a stream of methane-containing gas and O2 is passed over a thermally conditioned, high surface area Rh/Sm/zirconia granular catalyst in a short contact time reactor to produce a mixture of carbon monoxide and hydrogen.
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3.发明授权公开(公告)号：US07056488B2
公开(公告)日：2006-06-06
申请号：US10299879
申请日：2002-11-19
CPC分类号： C01B3/40 , B01J21/04 , B01J21/06 , B01J21/066 , B01J23/40 , B01J23/58 , B01J23/63 , B01J23/70 , B01J23/755 , B01J23/78 , B01J35/08 , B01J35/10 , B01J35/1009 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0205 , C01B3/386 , C01B2203/0261 , C01B2203/1005 , C01B2203/1011 , C01B2203/1041 , C01B2203/1047 , C01B2203/1241 , Y02P20/52
摘要： Controlled pore structure catalysts are disclosed that are active for catalyzing the partial oxidation of methane to CO and H2 and, advantageously, are capable of initiating the reaction without the need for an additional ignition source. A preferred catalyst comprises rhodium and samarium supported on an alumina or modified alumina support having certain surface area, pore volume, pore size and metal dispersion characteristics that permit light-off of the reaction at temperatures below 500° C. and with little or no use of an ignition agent. A method of partially oxidizing a light hydrocarbon to form synthesis gas, and a method of enhancing low-temperature light-off of the process are also described.
摘要翻译： 公开了用于催化甲烷部分氧化为CO和H 2 H的有效的孔结构催化剂，并且有利地能够启动反应而不需要另外的点火源。 优选的催化剂包括负载在具有一定表面积，孔体积，孔径和金属分散特性的氧化铝或改性氧化铝载体上的铑和钐，其允许在低于500℃的温度和少量或不使用的温度下使反应点燃 的点火剂。 还描述了一种部分氧化轻烃以形成合成气的方法，以及提高该方法的低温点火的方法。
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4.发明授权Cogeneration of organic compounds with synthesis gas by catalytic partial oxidation 失效通过催化部分氧化合成有机化合物与合成气的共生公开(公告)号：US06974843B2
公开(公告)日：2005-12-13
申请号：US10405288
申请日：2003-04-02
IPC分类号： C07C2/84 , C07C29/151 , C07C51/215 , C07C67/39 , C07C27/00 , C01B3/26 , C01B31/18 , C07C1/02
CPC分类号： C07C51/215 , C07C2/84 , C07C29/1518 , C07C67/39 , C07C2523/46 , Y02P20/52 , C07C15/02 , C07C53/00 , C07C31/04
摘要： Disclosed herein are methods and apparatuses for cogenerating organic compounds (e.g., benzene, toluene, xylene, formate, acetate, propionate, butyrate, C1-C4 acids, C1-C4 alcohols, methanol, naphthalene, acenaphthylene, fluorene, phenanthrene, anthracene, fluoranthene, and pyrene) along with synthesis gas in a synthesis gas reactor, preferably a catalytic partial oxidation reactor.
摘要翻译： 本文公开了用于将有机化合物（例如苯，甲苯，二甲苯，甲酸盐，乙酸盐，丙酸盐，丁酸盐，C 1 -C 4酸）共价偶联的方法和装置， 在合成气反应器中与合成气一起，优选催化性部分，优选催化部分 氧化反应器。
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5.发明授权Utilization of micro-channel gas distributor to distribute unreacted feed gas into reactors 有权利用微通道气体分配器将未反应的进料气体分配到反应器中公开(公告)号：US07097787B2
公开(公告)日：2006-08-29
申请号：US10619698
申请日：2003-07-15
申请人： Guy H. Lewis , Chien-Ping Pan , Harold A. Wright , David H. Anderson , David M. Minahan , Vincent H. Melquist , Cemal Ercan , Gloria I. Straguzzi , Stephen R. Landis , Phillipp R. Ellison
发明人： Guy H. Lewis , Chien-Ping Pan , Harold A. Wright , David H. Anderson , David M. Minahan , Vincent H. Melquist , Cemal Ercan , Gloria I. Straguzzi , Stephen R. Landis , Phillipp R. Ellison
CPC分类号： B01J4/001 , B01F3/02 , B01F13/0059 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/00889 , B01J2219/00891 , B01J2219/00984 , C01B3/386 , C01B2203/0261 , C01B2203/12 , C01B2203/1241 , C01B2203/1276 , C01B2203/1282 , Y02P20/52
摘要： A method of partially oxidizing a feed gas comprises providing a reactor containing a catalyst, providing a gas distributor comprising a body having a plurality of channels therethrough and a plurality of outlets from said channels for distributing gas across the catalyst, feeding the feed gas and the oxygen-containing gas into the gas distributor and allowing the feed gas and the oxygen-containing gas to flow through the gas distributor and out through the outlets into contact with the catalyst. The gas distributor preferably comprises a micro-channel gas distributor, which can be assembled by providing a plurality of etched plates defining flow channels, and stacking and fusing the plates. The reactant gases can be mixed within the gas distributor or maintained separately until they have exited the gas distributor.
摘要翻译： 一种部分氧化进料气体的方法包括提供一种含有催化剂的反应器，提供一种气体分配器，其包括具有多个通道的主体和从所述通道的多个出口，用于分配气体穿过催化剂，供给进料气体和 含氧气体进入气体分配器并允许进料气体和含氧气体通过气体分配器流出并通过出口与催化剂接触。 气体分配器优选地包括微通道气体分配器，其可以通过提供限定流动通道的多个蚀刻板并且堆叠和熔合板来组装。 反应物气体可以在气体分配器内混合或分开维护，直到它们离开气体分配器。
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6.发明授权Rare earth aluminates and gallates supported rhodium catalysts for catalytic partial oxidation of hydrocarbons 有权稀土铝酸盐和没食子酸酯负载的铑催化剂用于烃的催化部分氧化公开(公告)号：US07001867B2
公开(公告)日：2006-02-21
申请号：US10152278
申请日：2002-05-21
申请人： Yaming Jin , Tianyan Niu , Harold A. Wright
发明人： Yaming Jin , Tianyan Niu , Harold A. Wright
CPC分类号： C01B3/386 , B01J23/002 , B01J23/63 , B01J23/83 , B01J35/002 , B01J37/0207 , B01J2523/00 , C01B3/40 , C01B2203/0261 , C01B2203/062 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C10G2/32 , Y02P20/52 , Y10S502/525 , B01J2523/31 , B01J2523/3737 , B01J2523/3706
摘要： The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions. In particular, preferred embodiments of the present invention comprise rare earth catalyst supports, catalyst compositions having rare earth supports, and methods of preparing and using the catalysts and supports. Accordingly, the present invention also encompasses an improved method for converting a hydrocarbon containing gas and an oxygen containing gas to a gas mixture comprising hydrogen and carbon monoxide, i.e., syngas, using the rare earth catalyst supports in accordance with the present invention. In addition, the present invention contemplates an improved method for converting hydrocarbon gas to liquid hydrocarbons using the novel syngas catalyst supports and compositions described herein.
摘要翻译： 本发明涉及改进的催化剂组合物，以及制备和使用这些组合物的方法。 特别地，本发明的优选实施方案包括稀土催化剂载体，具有稀土载体的催化剂组合物，以及制备和使用催化剂和载体的方法。 因此，本发明还包括使用根据本发明的稀土催化剂载体将含烃气体和含氧气体转化为包含氢气和一氧化碳（即合成气）的气体混合物的改进方法。 此外，本发明考虑了使用本文所述的新型合成气催化剂载体和组合物将烃气体转化为液体烃的改进方法。
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公开(公告)号：US07230035B2
公开(公告)日：2007-06-12
申请号：US10747718
申请日：2003-12-29
申请人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Tianyan Niu , Harold A. Wright , Shuibo Xie , Mary E. Wolf
发明人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Tianyan Niu , Harold A. Wright , Shuibo Xie , Mary E. Wolf
CPC分类号： B01J37/0207 , B01J23/63 , B01J23/6567 , B01J35/008 , B01J35/023 , B01J37/08 , B01J37/18 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/062 , C01B2203/1011 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1247 , C01B2203/80 , Y02P20/52
摘要： The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions to prepare synthesis gas and ultimately C5+ hydrocarbons. In particular, preferred embodiments of the present invention comprise catalyst systems comprising a core and an outer region disposed on said core, wherein a substantial amount of the catalytic metal is located in the outer region of the catalyst support matrix. In addition, the catalyst systems are able to maintain high conversion and selectivity values with very low catalytically active metal loadings. The catalyst systems are appropriate for improved syngas, oxidative dehydrogenation and other partial oxidation reactions, including improved reaction schemes for the conversion of hydrocarbon gas to C5+ hydrocarbons.
摘要翻译： 本发明涉及改进的催化剂组合物，以及制备和使用这些组合物来制备合成气和最终C 5+烃的方法。 特别地，本发明的优选实施方案包括催化剂体系，其包括芯和设置在所述芯上的外部区域，其中大量的催化金属位于催化剂载体基质的外部区域中。 此外，催化剂体系能够以非常低的催化活性金属负载维持高转化率和选择性值。 催化剂体系适合用于改进合成气，氧化脱氢和其它部分氧化反应，包括用于将烃气转化为C 5+烃的改进的反应方案。
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公开(公告)号：US06992112B2
公开(公告)日：2006-01-31
申请号：US10822528
申请日：2004-04-12
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , C01B3/386 , C01B3/501 , C01B3/56 , C01B13/0251 , C01B2203/0261 , C01B2203/0405 , C01B2203/043 , C01B2203/0465 , C01B2203/062
摘要： The present invention is an improvement in the preparation of liquid hydrocarbons from natural gas/methane, oxygen and/or steam. In particular, the present invention relates to processes for the production of synthesis gas, reducing the oxygen concentration from the synthesis gas, and the production of liquid hydrocarbons using the oxygen reduced synthesis gas as a feedstock. More particularly, the present invention described herein identifies catalyst compositions, apparatus and methods of using such catalysts and apparatus for preparing liquid hydrocarbons via oxygen reduced synthesis gas all in accordance with the present invention.
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公开(公告)号：US06747066B2
公开(公告)日：2004-06-08
申请号：US10219108
申请日：2002-08-15
IPC分类号： C07C2700
CPC分类号： C10G2/32 , C01B3/386 , C01B3/501 , C01B3/56 , C01B13/0251 , C01B2203/0261 , C01B2203/0405 , C01B2203/043 , C01B2203/0465 , C01B2203/062
摘要： The present invention is an improvement in the preparation of liquid hydrocarbons from natural gas/methane, oxygen and/or steam. In particular, the present invention relates to processes for the production of synthesis gas, reducing the oxygen concentration from the synthesis gas, and the production of liquid hydrocarbons using the oxygen reduced synthesis gas as a feedstock. More particularly, the present invention described herein identifies catalyst compositions, apparatus and methods of using such catalysts and apparatus for preparing liquid hydrocarbons via oxygen reduced synthesis gas all in accordance with the present invention.
摘要翻译： 本发明是从天然气/甲烷，氧气和/或蒸汽制备液体烃的改进。 特别地，本发明涉及用于生产合成气的方法，降低来自合成气的氧浓度，以及使用氧还原合成气作为原料生产液体烃。 更具体地，本发明描述了根据本发明的催化剂组合物，使用这种催化剂的装置和方法以及通过氧还原合成气制备液体烃的装置。
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公开(公告)号：US07524786B2
公开(公告)日：2009-04-28
申请号：US11113756
申请日：2005-04-25
申请人： Daxiang Wang , Baili Hu , Yaming Jin , Harold A. Wright
发明人： Daxiang Wang , Baili Hu , Yaming Jin , Harold A. Wright
IPC分类号： B01J38/12
CPC分类号： B01J38/04 , B01J23/464 , B01J23/94 , B01J23/96 , B01J35/002 , B01J38/10 , B01J38/12 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/06 , C01B2203/062 , C01B2203/1047 , C01B2203/1082 , C01B2203/1241 , Y02P20/52 , Y02P20/584
摘要： The present invention relates to a process for the preparation of synthesis gas (i.e., a mixture of carbon monoxide and hydrogen), typically labeled syngas. More particularly, the present invention relates to a regeneration method for a syngas catalyst. Still more particularly, the present invention relates to the regeneration of syngas catalysts using a re-dispersion technique. One embodiment of the re-dispersion technique involves the treatment of a deactivated syngas catalyst with a re-dispersing gas, preferably a carbon monoxide-containing gas such as syngas. If necessary, the catalyst is then exposed to hydrogen for reduction and further re-dispersion.
摘要翻译： 本发明涉及通常标记为合成气的合成气（即，一氧化碳和氢气的混合物）的制备方法。 更具体地说，本发明涉及合成气催化剂的再生方法。 更具体地说，本发明涉及使用再分散技术再生合成气催化剂。 再分散技术的一个实施方案涉及用再分散气体，优选含有一氧化碳的气体如合成气处理失活的合成气催化剂。 如果需要，然后将催化剂暴露于氢气中进行还原和再分散。
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