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    Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof
    1.
    发明授权
    Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof 失效
    用铜或锌和铬，钼，钨或钒制备催化剂的方法及其制品

    公开(公告)号：US5134108A

    公开(公告)日：1992-07-28

    申请号：US703923

    申请日：1991-05-22

    申请人： Deepak S. Thakur ,  Eugene Palka ,  Thomas J. Sullivan ,  Eugene Nebesh ,  Brian D. Roberts

    发明人： Deepak S. Thakur ,  Eugene Palka ,  Thomas J. Sullivan ,  Eugene Nebesh ,  Brian D. Roberts

    IPC分类号： B01J23/847 ,  B01J23/85 ,  B01J23/86 ,  B01J23/889 ,  B01J35/10 ,  B01J37/03 ,  C07C29/141 ,  C07C29/145 ,  C07C29/149 ,  C07C51/36

    CPC分类号： C07C51/36 ,  B01J23/847 ,  B01J23/8472 ,  B01J23/85 ,  B01J23/868 ,  B01J23/8892 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/108 ,  B01J37/03 ,  C07C29/141 ,  C07C29/145 ,  C07C29/149

    摘要： This hydrogenation catalyst comprises a major amount of the oxides of a first metal selected from copper or zinc, a second metal selected from chromium, molybdenum, tungsten and vanadium, and optionally, a minor amount of the oxide of a promoter metal selected from the group consisting of manganese, barium, zinc, nickel, cobalt, cadmium, iron and any combination thereof provided that the promotor metal is not zinc if the first metal is zinc. The average particle diameter of the powder is from about 6 to about 20 microns; and the particle surface area is from about 20 to about 70 m.sup.2 /g. The process for preparing this catalyst comprises the steps of(A) simultaneously and adding to a first vessel, (1) a first aqueous solution comprising a copper or zinc salt; (2) a second aqueous solution comprising a soluble base, provided that either the copper solution or the soluble base solution also contains a soluble salt of at least one second metal; or (3) a third aqueous solution comprising a soluble salt of at least one seocnd metal is added simultaneously to the first vessel whereby an aqueous slurry of insoluble solid is formed in the first vessel, provided further that the second metal is chromium, molybdenum, tungsten, or vanadium;(B) advancing at least a portion of the aqueous slurry from the first vessel to a second vessel;(C) recovering the solids from the aqueous slurry in the second vessel; and(D) calcining the recovered solids.

    摘要翻译： 该氢化催化剂包含主要量的选自铜或锌的第一金属的氧化物，选自铬，钼，钨和钒的第二金属，以及任选的少量选自下组的助催化剂金属的氧化物： 由锰，钡，锌，镍，钴，镉，铁及其任何组合构成，只要第一金属为锌，则助催化剂金属不是锌。 粉末的平均粒径为约6至约20微米; 并且颗粒表面积为约20至约70m 2 / g。 制备该催化剂的方法包括以下步骤：（A）同时加入第一容器，（1）包含铜或锌盐的第一水溶液; （2）包含可溶性碱的第二水溶液，条件是铜溶液或可溶性碱溶液也含有至少一种第二金属的可溶性盐; 或（3）将包含至少一种第一金属的可溶性盐的第三水溶液同时加入到第一容器中，由此在第一容器中形成不溶性固体的水性浆液，进一步提供第二金属为铬，钼， 钨或钒; （B）将所述含水浆料的至少一部分从所述第一容器推进到第二容器; （C）从第二容器中的含水浆液中回收固体; 和（D）煅烧回收的固体。

    Hydrogenation catalyst, process for preparing and process of using said catalyst
    5.
    发明授权
    Hydrogenation catalyst, process for preparing and process of using said catalyst 失效
    氢化催化剂，制备和使用所述催化剂的方法

    公开(公告)号：US5155086A

    公开(公告)日：1992-10-13

    申请号：US680100

    申请日：1991-04-02

    申请人： Deepak S. Thakur ,  Brian D. Roberts ,  Thomas J. Sullivan ,  Anita L. Vichek

    发明人： Deepak S. Thakur ,  Brian D. Roberts ,  Thomas J. Sullivan ,  Anita L. Vichek

    IPC分类号： B01J23/80 ,  B01J35/02 ,  B01J35/10 ,  B01J37/03 ,  C07C29/141 ,  C07C29/145 ,  C07C29/149

    CPC分类号： C07C29/149 ,  B01J23/80 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/031 ,  C07C29/141 ,  C07C29/145 ,  B01J35/023

    摘要： In one embodiment, the invention relates to a catalyst in powdered form which comprises a major amount of the oxides of copper and zinc, and a minor amount of aluminum oxide wherein the pore volume of pores of said catalysts having a diameter between about 120 and about 1000 .ANG. is at least about 40% of the total pore volume. In another embodiment, the invention relates to a process for preparing hydrogenation catalysts comprising the oxides of copper, zinc and aluminum which comprises the steps of(A) preparing a first aqueous solution containing at least one water-soluble copper salt and at least one water-soluble zinc salt;(B) preparing a second solution containing at least one water-soluble basic aluminum salt and at least one alkaline precipitating agent;(C) mixing the first and second solutions whereby an insoluble solid is formed;(D) recovering the insoluble solid.The invention also relates to a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters with catalysts of the type described. Catalysts of the invention are useful in both fixed bed and slurry phase hydrogenation reactions.

    摘要翻译： 在一个实施方案中，本发明涉及粉末形式的催化剂，其包含主要量的铜和锌的氧化物和少量氧化铝，其中所述催化剂的孔的孔体积具有约120和约 1000 ANGSTROM是总孔容的至少约40％。 在另一个实施方案中，本发明涉及一种制备包含铜，锌和铝的氧化物的氢化催化剂的方法，其包括以下步骤：（A）制备含有至少一种水溶性铜盐和至少一种水的第一水溶液 可溶锌盐; （B）制备含有至少一种水溶性碱性铝盐和至少一种碱性沉淀剂的第二溶液; （C）混合第一和第二溶液，由此形成不溶性固体; （D）回收不溶性固体。 本发明还涉及用所述类型的催化剂氢化醛，酮，羧酸和羧酸酯的方法。 本发明的催化剂可用于固定床和浆相加氢反应。

    Hydrogenation catalyst and process for preparing same
    6.
    发明授权
    Hydrogenation catalyst and process for preparing same 失效
    氢化催化剂及其制备方法

    公开(公告)号：US5418201A

    公开(公告)日：1995-05-23

    申请号：US077216

    申请日：1993-06-15

    申请人： Brian D. Roberts ,  Deepak S. Thakur ,  Thomas J. Sullivan ,  Robert A. Plundo

    发明人： Brian D. Roberts ,  Deepak S. Thakur ,  Thomas J. Sullivan ,  Robert A. Plundo

    IPC分类号： B01J23/889 ,  B01J37/03 ,  C07C29/141 ,  C07C29/145 ,  C07C29/149 ,  B01J23/84 ,  B01J21/04 ,  B01J23/34

    CPC分类号： B01J37/03 ,  B01J23/8892 ,  C07C29/149

    摘要： In one embodiment, the invention relates to a catalyst in powdered form comprising the oxides of copper, iron, aluminum and manganese wherein the atomic ratio of copper to iron is at least 1:1. In another embodiment, the invention relates to a process for preparing such hydrogenation catalysts which comprises the steps of(A) preparing a first aqueous solution containing at least one water-soluble copper salt, at least one water-soluble iron salt, and at least one water-soluble manganese salt;(B) preparing a second solution containing at least one water-soluble basic aluminum salt and at least one alkaline precipitating agent;(C) mixing the first and second solutions wherein an insoluble solid is formed;(D) recovering the soluble solid; and(E) calcining the recovered solid to form the desired catalyst.The invention also relates to a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters.

    摘要翻译： 在一个实施方案中，本发明涉及包含铜，铁，铝和锰的氧化物的粉末形式的催化剂，其中铜与铁的原子比至少为1:1。 在另一个实施方案中，本发明涉及一种制备这种氢化催化剂的方法，其包括以下步骤：（A）制备含有至少一种水溶性铜盐，至少一种水溶性铁盐和至少一种水溶性铁盐的第一水溶液 一种水溶性锰盐; （B）制备含有至少一种水溶性碱性铝盐和至少一种碱性沉淀剂的第二溶液; （C）混合其中形成不溶性固体的第一和第二溶液; （D）回收可溶性固体; 和（E）煅烧回收的固体以形成所需的催化剂。 本发明还涉及氢化醛，酮，羧酸和羧酸酯的方法。