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1.发明授权Process for selective production of propylene from hydrocarbon fractions with four carbon atoms 有权从具有四个碳原子的烃馏分中选择性生产丙烯的方法公开(公告)号：US06743958B2
公开(公告)日：2004-06-01
申请号：US09846690
申请日：2001-05-02
IPC分类号： C07C604
CPC分类号： C07C11/06 , C07C6/04 , C07C11/09 , C07C2521/06 , C07C2523/36
摘要： For the selective production of propylene from an olefinic C4 fraction, a process is implemented that successively comprises: 1) the selective hydrogenation of butadiene with isomerization of butene-1 into butene-2; 2) the separation by distillation of a mixture that is rich in isobutene and butene-1 at the top and a fraction that is rich in butene-2 at the bottom; 3) the skeletal isomerization of isobutene into n-butenes on the top fraction, with recycling in stage 1; and 4) the metathesis of the butene-2-rich fraction with ethylene.
摘要翻译： 对于从烯烃C4馏分中选择性生产丙烯的方法，其顺序包括：1）丁烯与丁烯-2的异构化的选择性氢化; 2）通过蒸馏分离富集的混合物 在顶部的异丁烯和丁烯-1，底部富含丁烯-2的馏分; 3）在第一阶段循环的异丁烯在顶级馏分上的正丁烯异构化成正丁烯; 和4）富含丁烯的富烯馏分与乙烯的复分解。
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2.发明授权Process for selective production of propylene from hydrocarbon fractions with four carbon atoms 有权从具有四个碳原子的烃馏分中选择性生产丙烯的方法公开(公告)号：US06916448B2
公开(公告)日：2005-07-12
申请号：US10682980
申请日：2003-10-14
CPC分类号： C07C11/06 , C07C6/04 , C07C11/09 , C07C2521/06 , C07C2523/36
摘要： For the selective production of propylene from an olefinic C4 fraction, a process is implemented that successively comprises: 1) the selective hydrogenation of butadiene with isomerization of butene-1 into butene-2; 2) the separation by distillation of a mixture that is rich in isobutene and butene-1 at the top and a fraction that is rich in butene-2 at the bottom; 3) the skeletal isomerization of isobutene into n-butenes on the top fraction, with recycling in stage 1; and 4) the metathesis of the butene-2-rich fraction with ethylene. The advantage of this process is to produce in a very selective way polymerization-quality propylene from all of the olefinic compounds of a C4 fraction, including isobutene.
摘要翻译： 对于从烯烃C 4 H 4馏分选择性生产丙烯，实施了连续包括：1）丁烯与丁烯-2的异构化的选择性氢化; 2）通过蒸馏分离富含异丁烯和顶部丁烯-1的混合物和底部富含丁烯-2的馏分; 3）将异丁烯骨架异构化为顶级馏分中的正丁烯，并在第1阶段循环使用; 和4）富含丁烯的富烯馏分与乙烯的复分解。 该方法的优点是以非常有选择的方式生产聚合优质的丙烯从C 4 S 4馏分的所有烯烃化合物，包括异丁烯。
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3.发明授权Composition of catalyst and solvent and catalysis processes using this composition 有权使用该组合物的催化剂和溶剂的组成和催化方法公开(公告)号：US07256152B2
公开(公告)日：2007-08-14
申请号：US10232837
申请日：2002-09-03
申请人： Helene Olivier-Bourbigou , Dominique Commereuc , Olivia Martin , Lionel Magna , Emmanuel Pellier
发明人： Helene Olivier-Bourbigou , Dominique Commereuc , Olivia Martin , Lionel Magna , Emmanuel Pellier
IPC分类号： B01J31/00 , B01J31/02 , B01J31/14 , B01J35/12 , C07B61/00 , C07C2/00 , C07C2/08 , C07C2/26 , C07C2/62 , C07C5/22 , C07C5/25 , C07C9/21 , C07C11/02 , C07C11/10 , C07C15/02
CPC分类号： B01J31/0281 , B01J31/0225 , B01J31/0288 , B01J31/0289 , B01J2231/20 , B01J2231/323 , B01J2231/52 , C07C2/26 , C07C2/58 , C07C2531/025
摘要： A composition defined: either as comprising at least one Broensted acid, designated HB, dissolved in a liquid medium with an ionic nature of general formula Q+A−, in which Q+ represents an organic cation and A− represents an anion that is different from B, or as resulting from dissolving at least one Broensted acid, designated HB, in a non-aqueous liquid medium with an ionic nature of general formula Q+A−, in which Q+ represents an organic cation and A− represents an anion that is identical to the anion B, can be used as a catalyst and solvent in acid catalysis processes, in particular in the alkylation of aromatic hydrocarbons, the oligomerization of olefins, the dimerization of isobutene, the alkylation of olefins by isoparaffins, the isomerization of n-paraffins into isoparaffins, the isomerization of n-olefins into iso-olefins, the isomerization of the double bond of an olefin and the purification of an olefin mixture that contains branched alpha olefins as impurities.
摘要翻译： 一种组合物，其定义为：包含至少一种Broensted酸，称为HB，溶解在具有通式Q + A-的离子性质的液体介质中，其中Q +表示有机阳离子，A-表示不同于 B或由至少一种名为HB的Broensted酸溶解在具有通式Q + A-的离子性质的非水性液体介质中，其中Q +表示有机阳离子，A-表示阴离子， 与阴离子B相同，可用作酸催化方法中的催化剂和溶剂，特别是芳烃的烷基化，烯烃的低聚，异丁烯的二聚，异链烷烃的烯烃的烷基化， 链烷烃变成异链烷烃，正烯烃异构化成异烯烃，烯烃双键异构化和含有支链α-烯烃作为杂质的烯烃混合物的纯化。
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4.发明授权Catalytic composition and a process for oligomerizing ethylene, in particular to 1-hexene 有权催化组合物和使乙烯低聚的方法，特别是1-己烯公开(公告)号：US06828269B2
公开(公告)日：2004-12-07
申请号：US09745441
申请日：2000-12-26
IPC分类号： C08F200
CPC分类号： B01J31/2234 , B01J31/0214 , B01J31/143 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2/30 , C07C2531/02 , C07C2531/14 , C08F10/00 , Y02P20/52 , C08F4/69
摘要： A catalytic composition is obtained by mixing at least one chromium compound with at least one aryloxy compound of an element M selected from the group formed by magnesium, calcium, strontium and barium, with general formula M(RO)2-nXn, where RO is an aryloxy radical containing 6 to 80 carbon atoms, X is a halogen or a hydrocarbyl radical containing 1 to 30 carbon atoms and n is a whole number that can take values of 0 to 2, and with at least one aluminum compound selected from hydrocarbylaluminum compounds (tris(hydrocarbyl)-aluminum, chlorinated or brominated hydrocarbylaluminum compounds) and aluminoxanes. The catalytic composition can be used in an ethylene oligomerization process, in particular to produce 1-hexene.
摘要翻译： 通过将至少一种铬化合物与选自由镁，钙，锶和钡形成的基团的至少一种芳氧基化合物与通式M（RO）2-nXn混合，得到催化组合物，其中RO为 含有6〜80个碳原子的芳氧基，X是卤素或含有1至30个碳原子的烃基，n是可以取0至2的整数，并且与至少一种选自烃基铝化合物的铝化合物 （三（烃基）铝，氯化或溴化烃基铝化合物）和铝氧烷。 催化组合物可用于乙烯低聚方法，特别是生产1-己烯。
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5.发明授权Process for the codimerization of fatty substance dienes and olefins that are catalyzed by nickel complexes 有权由镍络合物催化的脂肪二烯和烯烃的同分异构化方法公开(公告)号：US06452029B1
公开(公告)日：2002-09-17
申请号：US09362217
申请日：1999-07-28
IPC分类号： C09F706
CPC分类号： C10M105/34 , C07C67/303 , C07C67/347 , C07C69/24 , C07C69/587
摘要： A nickel catalytic system that makes it possible to obtain branched compounds from fatty substances by reacting simple olefins on polyunsaturated esters, which may or may not be conjugated, is described. The compounds that are obtained may be hydrogenated and used as lubricant bases or may be transformed according to known procedures into compounds of acid, alcohol, amine or amide type, used in varied applications.
摘要翻译： 描述了一种镍催化体系，其可以通过在多不饱和酯上反应简单的烯烃从脂肪物质获得支链化合物，其可以或可以不共轭。 获得的化合物可以被氢化并用作润滑剂基质，或者可以根据已知的方法转化成用于各种应用的酸，醇，胺或酰胺型的化合物。
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6.发明授权Process and unit for carrying out a reaction on an organic feed, such as dimerisation or metathesis, in the presence of a polar phase containing a catalyst 失效在含有催化剂的极性相存在下，在有机原料上进行反应的方法和单元，例如二聚或复分解公开(公告)号：US06284937B1
公开(公告)日：2001-09-04
申请号：US09084353
申请日：1998-05-27
IPC分类号： C07C226
CPC分类号： C07C6/04 , B01J19/245 , B01J2219/00103 , B01J2219/00159 , B01J2219/00186 , C07B61/00 , C07C2527/125 , C07C2531/14
摘要： A process for carrying out a reaction on an organic feed, for example dimerization, co-dimerization, oligomerization or metathesis of olefins, as described in which the catalyst is a catalytic metal compound dissolved in a non-aqueous ionic medium which is not or is only slightly miscible with hydrocarbons. The reaction is carried out in a system comprising at least two treatment loops each comprising at least one reaction zone and at least one zone for separating the organic and polar phases between which the polar medium containing the catalytic metal compound, and the organic phase circulate. Fresh polar phase is injected into the second loop and used polar phase is eliminated from the first loop. The hydrocarbon to be transformed is injected into the first loop and the products are withdrawn from the second loop. The invention also concerns a unit for carrying out the process.
摘要翻译： 对有机原料进行反应的方法，例如烯烃的二聚，共二聚，低聚或复分解，其中催化剂是溶解在非水性离子介质中的催化金属化合物，其不是或不是 只与碳氢化合物轻微混溶。 该反应在包括至少两个处理回路的系统中进行，每个处理回路各自包含至少一个反应区和至少一个用于分离有机相和极性相的区域，在该区域之间含有催化金属化合物的极性介质和有机相循环。 新鲜极性相注入到第二回路中，并且使用极性相从第一回路中消除。 将待转化的烃注入第一回路中，并从第二回路中取出产物。 本发明还涉及用于执行该过程的单元。
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7.发明授权
公开(公告)号：US5898092A
公开(公告)日：1999-04-27
申请号：US862698
申请日：1997-05-23
申请人： Dominique Commereuc
发明人： Dominique Commereuc
CPC分类号： C07C6/04 , B01J23/36 , B01J2231/543 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/14 , C07C2523/20 , C07C2523/26 , C07C2523/36 , C07C2529/04 , C07C2531/14 , C07C2531/26 , C07C2531/32 , C07C2531/34 , C07C2531/36
摘要： A supported catalyst with rhenium and also containing aluminium introduced by a compound of the formula (OR).sub.qAlR'.sub.r with R being a hydrocarbyl residue with from 1 to 40 carbon atoms, R' being an alkyl residue with from 1 to 20 carbon atoms, and with q and r equal to 1 or 2 with q+r=3. A process for the preparation of a catalyst comprising impregnating a compound of rhenium on a porous support formed by refractory oxides and/or alumino-silicates of an acid, neutral or basic nature, roasting at a temperature of form 200 to 950.degree. C. and impregnating with said aluminium compound. The catalyst is used for the metathesis of olefins.
摘要翻译： 具有铼并且还含有由式（OR）qAlR'r化合物引入的负载催化剂，R是具有1至40个碳原子的烃基残基，R'是具有1至20个碳原子的烷基， q和r等于1或2，q + r = 3。 一种制备催化剂的方法，包括将铼化合物浸渍在由难溶氧化物和/或酸性，中性或碱性的耐热氧化铝和/或铝硅酸盐形成的多孔载体上，在200至950℃的温度下焙烧， 用所述铝化合物浸渍。 催化剂用于烯烃的复分解。
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8.发明授权Process and plant for the conversion of olefinic C.sub.4 cuts to polyisobutene and to propylene 失效用于将烯烃C4馏分转化为聚异丁烯和丙烯的方法和装置
公开(公告)号：US5877365A
公开(公告)日：1999-03-02
申请号：US644159
申请日：1996-05-10
IPC分类号： B01J8/08 , C07B61/00 , C07C6/04 , C07C7/163 , C07C11/06 , C08F2/00 , C08F4/12 , C08F4/14 , C08F8/00 , C08F10/10 , C08F110/10 , C07C2/02 , C07C6/02
CPC分类号： C08F110/10 , B01J8/08 , C07C11/06 , C07C6/04 , C07C7/163 , C07C2521/04 , C07C2523/20 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/755
摘要： The present invention concerns a process for the conversion of an olefinic C.sub.4 cut to polyisobutene and to propylene by metathesis. The process comprises three successive steps: (1) selective hydrogenation of diolefins with simultaneous isomerisation of 1-butene to 2-butenes, (2) polymerisation of the isobutene, including optional prior extraction of the isobutene, (3) metathesis of 2-butene with ethylene. Part or all of the C.sub.4 cut may originate from the metathesis of an olefinic C.sub.5 cut with ethylene after hydroisomerisation of the C.sub.5 cut. Application to C.sub.4 and C.sub.5 steam cracking cuts.
摘要翻译： 本发明涉及通过复分解将烯烃C4馏分转化为聚异丁烯和丙烯的方法。 该方法包括三个连续步骤：（1）将1-丁烯同时异构化为2-丁烯的二烯烃的选择性氢化，（2）异丁烯的聚合，包括任选先前提取的异丁烯，（3）2-丁烯的复分解 与乙烯。 C4馏分的部分或全部可以源自C5馏分加氢异构化后的烯烃C5馏分的复分解。 应用于C4和C5蒸汽裂解切割。
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9.发明授权Catalytic compositions based on compounds of rhenium and aluminium, preparation thereof and use thereof for the metathesis of olefins 失效基于铼和铝化合物的催化组合物，其制备方法和用于烯烃复分解的用途
公开(公告)号：US5747409A
公开(公告)日：1998-05-05
申请号：US554439
申请日：1995-11-06
申请人： Dominique Commereuc
发明人： Dominique Commereuc
IPC分类号： B01J31/32 , B01J23/36 , B01J31/14 , B01J31/16 , B01J31/22 , C07B61/00 , C07C6/04 , C07C11/02 , B01J31/00 , C07C6/02
CPC分类号： B01J23/36 , B01J31/1616 , B01J31/2226 , B01J2231/543 , B01J2531/0216 , B01J2531/31 , B01J2531/74
摘要： The present invention concerns new catalytic compositions containing at least one compound of rhenium and aluminium corresponding to the general formula: O.sub.3 Re--O--�Al(OR)(L).sub.x --O!.sub.n --ReO.sub.3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns the preparation of such compositions and the use thereof for the metathesis of olefins in a homogeneous phase.
摘要翻译： 本发明涉及包含至少一种铼和铝化合物的新催化组合物，其对应于通式为：O 3 Re-O- [Al（OR）（L）x O] n -R Re 3，其中R为烃基残基，例如烷基 含有1至40个碳原子的环烷基，烯基，芳基和芳基或环烷基，该残基可以被烷氧基或卤素取代，L是合成溶剂，x等于0或1，n是 本发明还涉及这种组合物的制备及其在均相中烯烃复分解的用途。
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10.发明授权Supported catalysts containing rhenium and aluminium, preparation thereof and use thereof for the metathesis of olefins 失效含有铼和铝的载体催化剂，其制备方法和用于烯烃复分解的用途
公开(公告)号：US5747408A
公开(公告)日：1998-05-05
申请号：US554351
申请日：1995-11-06
申请人： Dominique Commereuc
发明人： Dominique Commereuc
IPC分类号： B01J31/32 , B01J23/36 , B01J31/14 , B01J31/16 , B01J31/22 , C07B61/00 , C07C6/04 , C07C6/06 , C07C11/02 , B01J31/00 , C07C6/00
CPC分类号： C07C6/06 , B01J23/36 , B01J31/1616 , B01J31/2208 , C07C6/04 , B01J2231/543 , B01J2531/0216 , B01J2531/31 , B01J2531/74 , C07C2531/14
摘要： The present invention concerns new catalysts based on compounds containing both rhenium and aluminum, which are deposited on an organic or inorganic support. The compounds of rhenium and aluminum correspond to the general formula: O.sub.3 Re--O--�Al(OR)(L).sub.x --O!.sub.n --ReO.sub.3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl, and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns the preparation of such catalysts and the use thereof for the metathesis of olefins.
摘要翻译： 本发明涉及基于含有铼和铝的化合物的新催化剂，其沉积在有机或无机载体上。 铼和铝的化合物对应于以下通式：O 3 Re-O- [Al（OR）（L）x O] n -R Re 3，其中R是烃基残基，例如烷基，环烷基，烯基，芳基和芳基或 被取代的含有1至40个碳原子的环烷基，该残基可以被烷氧基或卤素取代，L是合成溶剂，x等于0或1，n是1至10的整数。 本发明还涉及这种催化剂的制备及其用于烯烃复分解的用途。
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