摘要:
A process for separating a primary gas component from a feed gas mixture comprising the primary gas component and secondary gas components in four or more adsorption beds. The process comprises subjecting each of the four or more adsorption beds to a repetitive cycle. The repetitive cycle comprises, in sequence, a feed step, a pressure decreasing equalization step, a provide purge step, a blowdown step, a purge step, a pressure increasing equalization step, and a repressurization step. During the pressure decreasing equalization step, rinse gas is co-currently introduced simultaneous with the withdrawal of pressure equalization gas. Rinse gas is formed by compressing blowdown gas and/or purge gas effluent from the adsorption bed undergoing the purge step. The process is particularly suited for separating H2 from a reformate stream.
摘要:
A hydrogen production process wherein steam and a hydrocarbon feed is reacted in a prereformer, the prereformed intermediate is further reacted in an oxygen-based reformer, the reformate is shifted and then separated by a pressure swing adsorber to form a H2 product stream and a tail gas, a first portion of the tail gas is recycled to the prereformer and/or the oxygen-based reformer, and a second portion of the tail gas is recycled to the pressure swing adsorber.
摘要:
A process for separating a first gas, for example CO2, from a feed gas mixture comprising the first gas and a second gas, for example H2, in five or more adsorption beds each containing an adsorbent selective for the first gas. The process comprises subjecting each of the adsorption beds to a repetitive cycle comprising, in sequence, (a) a feed step, (b) a rinse step, (c) a pressure decreasing equalization step, (d) a blowdown step, (e) an evacuation step, (f) a pressure increasing equalization step, and (g) a repressurization step. The feed gas mixture may be a reformate from a steam-hydrocarbon reforming process.
摘要:
A process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality of adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressure equalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.
摘要:
Method for the separation of a gas mixture comprising providing a pressure swing adsorption system having a plurality of adsorber vessels, wherein each vessel has an inlet, an outlet, and a bed of particulate adsorbent material disposed therein. The adsorbent material is selective for the adsorption of one or more components from the gas mixture, and each bed of adsorbent material is characterized by a bed depth and by an average particle diameter less than about 1.3 mm. A feed step is carried out during a feed time period wherein the gas mixture is introduced into the adsorber vessel, one or more components are selectively adsorbed from the gas mixture, and a product gas is withdrawn from the adsorber vessel. The bed depth in feet times the dimensionless ratio of the empty bed residence time to the feed time period is less than about 4.
摘要:
Hydrogen sulfide is removed from a hydrogen rich gas stream using adsorbents having a low loss of carbon dioxide adsorption capacity upon sulfur loading including high purity silica gels, titania or highly cross-linked, non-chemically reactive resins. The adsorbents may be used to adsorb both carbon dioxide and hydrogen sulfide, or may be used as a guard bed upstream of a separate carbon dioxide adsorbent.
摘要:
A pressure swing adsorption cycle designed to reduce the variations in ozone concentration, and produce a higher average ozone concentration, in a product gas stream throughout the cycle. The cycle includes a relatively long air sweep stage and provides for the overlapping of the air sweep stage in two adsorber vessels. Effluent from an adsorber vessel in a feed rinse stage is routed to another adsorber vessel that is in an air sweep stage.
摘要:
Method of operating a pressure swing adsorption system having a plurality of parallel adsorber vessels and a plurality of valves and gas manifolds adapted to introduce gas into each adsorber vessel and withdraw gas from each adsorber vessel in a cyclic series of sequential process steps. A leaking valve may be identified by (1) determining a value of an operating parameter that is a function of the mass of gas provided to a receiving adsorber vessel or withdrawn from an adsorber vessel during a selected process step, portion of a process step, or series of process steps; (2) determining the deviation of the value of the operating parameter from a predetermined reference value; and (3) using the magnitude and direction of the deviation to determine whether any valves are leaking.
摘要:
A pressure swing adsorption process which comprises introducing a feed gas mixture into an inlet of an adsorber vessel during a feed period, wherein the feed gas mixture contains a more strongly adsorbable component and a less strongly adsorbable component and the adsorber vessel contains a bed of adsorbent material which selectively adsorbs the more strongly adsorbable component, and withdrawing a product gas enriched in the less strongly adsorbable component from an outlet of the adsorber vessel during at least a portion of the feed period, wherein a dimensionless cycle-compensated mass transfer coefficient defined as K tfeedVads/Vfeed is maintained in the range of about 23 to about 250.
摘要翻译:一种变压吸附方法,其包括在进料期间将进料气体混合物引入吸附容器的入口,其中所述进料气体混合物包含更强吸附组分和较不强吸附组分,并且所述吸附剂容器含有吸附剂床 选择性吸附较强吸附组分的材料,以及在进料周期的至少一部分期间从吸附剂容器的出口排出富含较不强吸附组分的产物气体,其中无量纲循环补偿传质系数定义为 K tfeedVads / Vfeed保持在约23至约250的范围内。
摘要:
A method for the separation of a gas mixture comprises (a) obtaining a feed gas mixture comprising nitrogen and at least one hydrocarbon having two to six carbon atoms; (b) introducing the feed gas mixture at a temperature of about 60° F. to about 105° F. into an adsorbent bed containing adsorbent material which selectively adsorbs the hydrocarbon, and withdrawing from the adsorbent bed an effluent gas enriched in nitrogen; (c) discontinuing the flow of the feed gas mixture into the adsorbent bed and depressurizing the adsorbent bed by withdrawing depressurization gas therefrom; (d) purging the adsorbent bed by introducing a purge gas into the bed and withdrawing therefrom an effluent gas comprising the hydrocarbon, wherein the purge gas contains nitrogen at a concentration higher than that of the nitrogen in the feed gas mixture; (e) pressurizing the adsorbent bed by introducing pressurization gas into the bed; and (f) repeating (b) through (e) in a cyclic manner.