公开(公告)号：US09540766B2

公开(公告)日：2017-01-10

申请号：US13825935

申请日：2011-09-16

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： B32B25/02 ,  D07B1/06 ,  B29B15/08 ,  B60C5/00 ,  B29D30/38

CPC分类号： D07B1/0633 ,  B29B15/08 ,  B29D2030/383 ,  B60C5/00 ,  D07B1/0666 ,  Y10T428/2938 ,  Y10T428/2947 ,  Y10T428/2967 ,  Y10T428/2969

摘要： Composite reinforcer (R-2) that is self-adhesive, by curing, to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example a polyamide, covering said thread, individually each thread or collectively several threads; a second layer (22) of a composition comprising a poly(p-phenylene ether) (“PPE”) and a functionalized diene elastomer bearing functional groups selected from epoxide, carboxyl, acid anhydride and acid ester groups, in particular an epoxidized SBR, covering the first layer (21). Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer.

摘要翻译： 复合增强件（R-2），其通过固化而自粘合到可用作充气轮胎的增强元件的二烯橡胶基质上，包括：一个或多个加强丝（20），例如 碳钢绳; 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如聚酰胺，覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹; 包含聚（对亚苯基醚）（“PPE”）和具有选自环氧化物，羧基，酸酐和酸酯基团的官能团的官能化二烯弹性体，特别是环氧化SBR的组合物的第二层（22） 覆盖第一层（21）。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US20130280511A1

公开(公告)日：2013-10-24

申请号：US13825926

申请日：2011-09-16

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： C08K3/08

CPC分类号： C08K3/08 ,  B29B15/08 ,  B29D30/38 ,  B29D2030/383 ,  Y10T428/294

摘要： Pneumatic tire comprising a composite reinforcer (R-2) that is self-adhesive by curing to a diene rubber matrix, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand an unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative.

摘要翻译： 包括通过固化至二烯橡胶基体而自粘的复合增强件（R-2）的气动轮胎，包括：一个或多个加强丝（20），例如碳钢帘线; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，一方面包括玻璃化转变温度为正的热塑性聚合物，另一方面包含不饱和热塑性塑料弹性体，玻璃化转变 温度为负。

公开(公告)号：US20140051312A1

公开(公告)日：2014-02-20

申请号：US13981677

申请日：2012-01-31

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： B32B27/04 ,  B29D30/06 ,  C09J7/04

CPC分类号： B60C9/0057 ,  B29B15/125 ,  B29D30/0601 ,  B29D30/40 ,  B29K2009/06 ,  B29K2021/003 ,  B29K2071/12 ,  B29L2030/00 ,  B60C9/0042 ,  C08L53/02 ,  C09J7/21 ,  C09J7/30 ,  C09J7/35 ,  C09J153/02 ,  C09J171/12 ,  C09J2425/00 ,  C09J2465/00 ,  D06M15/227 ,  D06M15/233 ,  D06M15/53 ,  Y10T442/2738

摘要： Rubber composite, and in particular tyre, reinforced with a sized textile material, such as a fibre or a film, at least one portion of which is coated with an adhesive layer, capable of adhering directly via curing (crosslinking) to an unsaturated rubber matrix, such as a natural rubber matrix, characterized in that said layer comprises an adhesive composition or thermoplastic adhesive, in the liquid or solid state, which is based on at least one unsaturated thermoplastic styrene (TPS) elastomer and a poly(p-phenylene ether) (PPE).Such an adhesive based on unsaturated TPS and PPE advantageously makes it possible to replace a conventional textile adhesive of RFL type. Use of such an adhesive for the adhesive bonding of a textile material to an unsaturated, in particular diene, rubber. Process for obtaining such a composite.

摘要翻译： 橡胶复合材料，特别是轮胎，用诸如纤维或薄膜的尺寸的纺织材料增强，其至少一部分涂覆有粘合剂层，其能够通过固化（交联）直接粘附到不饱和橡胶基体 ，例如天然橡胶基质，其特征在于所述层包含基于至少一种不饱和热塑性苯乙烯（TPS）弹性体和聚（对亚苯基醚）的液体或固体状态的粘合剂组合物或热塑性粘合剂 ）（PPE）。 基于不饱和TPS和PPE的这种粘合剂有利地可以替代RFL型的常规纺织粘合剂。 使用这种粘合剂将纺织材料粘合到不饱和的，特别是二烯的橡胶上。 获得这种复合材料的方法。

公开(公告)号：US20140045984A1

公开(公告)日：2014-02-13

申请号：US13989017

申请日：2011-11-16

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： C09D109/06 ,  D07B1/06 ,  C09D177/02

CPC分类号： C09D109/06 ,  C09D177/02 ,  D02G3/48 ,  D07B1/0606 ,  D07B1/062 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2039 ,  D07B2205/2046 ,  D07B2205/2082 ,  D07B2207/4068 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T428/2938 ,  Y10T428/294 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/18 ,  D07B2801/16

摘要： Composite reinforcer (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer.

摘要翻译： 通过固化成可以用作充气轮胎的增强元件的二烯橡胶基质而具有自粘性的复合增强件（R-2），包括：一个或多个增强线（20），例如碳 钢丝绳; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，一方面包括玻璃化转变温度为正的热塑性聚合物，另一方面包括官能化的不饱和热塑性塑料弹性体，玻璃 其转变温度为负，所述弹性体含有选自环氧化物，羧基和酸酐或酯基的官能团。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US20140045983A1

公开(公告)日：2014-02-13

申请号：US13981769

申请日：2012-01-31

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： C08K3/08

CPC分类号： B60C9/0042 ,  B29D30/38 ,  B29D2030/383 ,  B60C2009/0021 ,  D02G3/48 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2501/2046 ,  Y10T428/2938 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/16 ,  D07B2801/18

摘要： Composite reinforcer (R-2) capable of adhering directly to a diene rubber matrix, which can be used as a reinforcing element for a pneumatic tyre, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising at least one thermoplastic polymer, the glass transition temperature of which is positive, a poly(p-phenylene ether) (PPE) and a functionalized unsaturated thermoplastic styrene (TPS) elastomer, the glass transition temperature of which is negative, said TPS elastomer bearing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tyre, incorporating such a composite reinforcer.

摘要翻译： 能够直接粘附到可用作充气轮胎的增强元件的二烯橡胶基体上的复合增强件（R-2）包括：一个或多个加强丝（20），例如碳钢绳 ; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，其包含至少一种热塑性聚合物，其玻璃化转变温度为正，聚（对亚苯基醚）（PPE）和官能化不饱和 热塑性苯乙烯（TPS）弹性体，其玻璃化转变温度为负，所述TPS弹性体带有官能团，选自环氧化物，羧基和酸酐或酯基。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US20140044964A1

公开(公告)日：2014-02-13

申请号：US13981762

申请日：2012-01-31

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： C09D177/02

CPC分类号： C09D177/02 ,  B29D30/38 ,  B29D2030/383 ,  B60C9/005 ,  B60C2009/0021 ,  D02G3/48 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2501/2046 ,  Y10T428/2933 ,  Y10T428/2938 ,  D07B2801/16 ,  D07B2801/18

摘要： Composite reinforcer (R-2) capable of adhering directly to a diene rubber matrix, which can be used as a reinforcing element for a pneumatic tyre, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising at least one thermoplastic polymer, the glass transition temperature of which is positive, an unsaturated thermoplastic styrene (TPS) elastomer, the glass transition temperature of which is negative, and a poly(p-phenylene ether) (“PPE”). Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tyre, incorporating such a composite reinforcer.

摘要翻译： 能够直接粘附到可用作充气轮胎的增强元件的二烯橡胶基体上的复合增强件（R-2）包括：一个或多个增强线（20），例如碳钢绳 ; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，包含至少一种热塑性聚合物的热塑性聚合物组合物层，玻璃化转变温度为正的玻璃化转变温度，不饱和热塑性苯乙烯（TPS）弹性体，其玻璃化转变温度 是负的（聚对苯醚）（“PPE”）。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US08790788B2

公开(公告)日：2014-07-29

申请号：US13322235

申请日：2010-05-20

申请人： Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

发明人： Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

IPC分类号： B32B27/00

CPC分类号： D07B1/0666 ,  B29D30/38 ,  D02G3/48 ,  D07B2201/2012 ,  D07B2201/2013 ,  D07B2201/2044 ,  D07B2201/2045 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2046 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T156/10 ,  Y10T428/269 ,  Y10T428/2947 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  D07B2801/18

摘要： Composite reinforcement (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a tire, having one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example 6,6 polyamide, covering the thread or the threads; and a second layer (22) having a functionalized unsaturated thermoplastic styrene elastomer, the glass transition temperature of which is negative, for example an epoxidized SBS elastomer, covering the first layer (21), the elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcement and rubber article or semi-finished product, especially a tire, incorporating such a composite reinforcement.

摘要翻译： 通过固化到二烯橡胶基质上的可自动粘合的复合增强材料（R-2），其可用作轮胎的增强元件，其具有一个或多个增强线（20），例如碳钢绳 ; 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如6,6聚酰胺，覆盖线或线; 和具有官能化的不饱和热塑性苯乙烯弹性体的第二层（22），其玻璃化转变温度为负，例如覆盖第一层（21）的环氧化SBS弹性体，含有选自环氧化物，羧基和 酸酐或酯基。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是掺入这种复合增强件的轮胎。

公开(公告)号：US20120128972A1

公开(公告)日：2012-05-24

申请号：US13322235

申请日：2010-05-20

申请人： Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

发明人： Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

IPC分类号： D07B1/16 ,  B32B37/14 ,  D07B1/06 ,  B32B5/28 ,  D02G3/48

CPC分类号： D07B1/0666 ,  B29D30/38 ,  D02G3/48 ,  D07B2201/2012 ,  D07B2201/2013 ,  D07B2201/2044 ,  D07B2201/2045 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2046 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T156/10 ,  Y10T428/269 ,  Y10T428/2947 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  D07B2801/18

摘要： Composite reinforcement (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example 6,6 polyamide, covering said thread or said threads; and a second layer (22) comprising a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, for example an epoxidized SBS elastomer, covering the first layer (21), said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcement and rubber article or semi-finished product, especially a tire, incorporating such a composite reinforcement.

摘要翻译： 通过固化可以用作轮胎的增强元件的二烯橡胶基体，其是自粘合的复合增强材料（R-2），包括：一个或多个增强线（20），例如碳钢 绳子 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如6,6聚酰胺，覆盖所述螺纹或所述螺纹; 和包含官能化的不饱和热塑性塑料弹性体的第二层（22），其玻璃化转变温度是负的，例如覆盖第一层（21）的环氧化SBS弹性体，所述弹性体含有选自环氧化物，羧基和 酸酐或酯基。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是掺入这种复合增强件的轮胎。

公开(公告)号：US09821606B2

公开(公告)日：2017-11-21

申请号：US13981769

申请日：2012-01-31

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： C08K9/00 ,  B60C9/00 ,  B29D30/38 ,  D02G3/48 ,  D07B1/06

CPC分类号： B60C9/0042 ,  B29D30/38 ,  B29D2030/383 ,  B60C2009/0021 ,  D02G3/48 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2501/2046 ,  Y10T428/2938 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/16 ,  D07B2801/18

摘要： A composite reinforcer that can adhere directly to a diene rubber matrix is usable as a reinforcing element for a pneumatic tire. The composite reinforcer includes at least one reinforcing thread, such as a carbon steel cord. Covering each thread individually or several threads collectively is a layer of a thermoplastic polymer composition. The thermoplastic polymer composition includes at least one thermoplastic polymer have a glass transition temperature that is positive, a poly(p-phenylene ether) (PPE), and a functionalized unsaturated thermoplastic styrene (TPS) elastomer having a glass transition temperature that is negative. The TPS elastomer includes a functional group selected from: an epoxide group, a carboxyl group, an acid anhydride group, and an ester group. A process for manufacturing such a composite reinforcer is presented, as well as a process for producing a rubber article, especially a pneumatic tire, incorporating such a composite reinforcer.

公开(公告)号：US20130273366A1

公开(公告)日：2013-10-17

申请号：US13825935

申请日：2011-09-16

申请人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

发明人： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC分类号： D07B1/06 ,  B60C5/00

CPC分类号： D07B1/0633 ,  B29B15/08 ,  B29D2030/383 ,  B60C5/00 ,  D07B1/0666 ,  Y10T428/2938 ,  Y10T428/2947 ,  Y10T428/2967 ,  Y10T428/2969

摘要： Composite reinforcer (R-2) that is self-adhesive, by curing, to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example a polyamide, covering said thread, individually each thread or collectively several threads; a second layer (22) of a composition comprising a poly(p-phenylene ether) (“PPE”) and a functionalized diene elastomer bearing functional groups selected from epoxide, carboxyl, acid anhydride and acid ester groups, in particular an epoxidized SBR, covering the first layer (21). Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer.

摘要翻译： 复合增强件（R-2），其通过固化而自粘合到可用作充气轮胎的增强元件的二烯橡胶基质上，包括：一个或多个加强丝（20），例如 碳钢绳; 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如聚酰胺，覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹; 包含聚（对亚苯基醚）（“PPE”）和具有选自环氧化物，羧基，酸酐和酸酯基团的官能团的官能化二烯弹性体，特别是环氧化SBR的组合物的第二层（22） 覆盖第一层（21）。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。