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公开(公告)号：US11242431B2
公开(公告)日：2022-02-08
申请号：US16463268
申请日：2017-10-25
发明人： Robert Valeri , Haipeng Zheng , Matthew Freeman
摘要： The present invention relates to a heat-curable composition comprising at least one epoxy monomer comprising two or three epoxy groups, which is not a hydrolysis-polymerizable silicon compound, at least one epoxy compound bearing at least one silicon atom having at least one hydrolyzable group directly linked to the silicon atom and at least one epoxy group, and at least one epoxy ring-opening catalyst. The composition comprises at least 50% by weight of compounds having at least one epoxy group, relative to the total weight of polymerizable compounds present in the composition and provides upon pre-curing a tack-free coating that can be removed by treatment with a solution of sodium hydroxide, and upon post-curing a coating that cannot be removed by treatment with a solution of sodium hydroxide.
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2.发明申请METHOD FOR PREPARING ANTISTATIC UV CURABLE HARDCOATINGS ON OPTICAL ARTICLES 审中-公开在光学文章上制备抗静电UV固化硬化的方法公开(公告)号：US20140010971A1
公开(公告)日：2014-01-09
申请号：US13933684
申请日：2013-07-02
发明人： Robert Valeri
CPC分类号： G02B1/14 , G02B1/105 , G02B1/12 , G02B1/16 , G02B27/0006
摘要： The present invention is drawn to a method for manufacturing antistatic UV-cured hard-coatings on optical articles, comprising (a) coating an organic or mineral optical substrate with an essentially anhydrous solution containing from 20% to 90% by weight, relative to the total dry matter of the solution, of at least one non hydrolyzed epoxyalkyltrialkoxysilane and at least 3.2% by weight, relative to the total dry matter of the solution, of at least one photoinitiator selected from the group consisting of triarylsulfonium salts, diaryliodonium salts, and mixtures thereof, (b) curing the resulting coating by irradiation with UV-radiation, said method not comprising any hydrolysis step before the UV curing step.
摘要翻译： 本发明涉及一种在光学制品上制造抗静电UV固化硬涂层的方法，其包括（a）相对于所述光学制品的基本无水溶液涂覆有机或无机光学基材，所述基本上无水的溶液含有20重量％至90重量％ 至少一种非水解环氧烷基三烷氧基硅烷的总干物质和相对于溶液的总干物质至少3.2重量％的至少一种光引发剂，其选自三芳基锍盐，二芳基碘鎓盐和 其混合物，（b）通过UV辐射照射固化所得的涂层，所述方法在UV固化步骤之前不包括任何水解步骤。
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3.发明授权公开(公告)号：US11752713B2
公开(公告)日：2023-09-12
申请号：US17066145
申请日：2020-10-08
发明人： Robert Valeri , John Biteau
IPC分类号： B29D11/00 , B33Y10/00 , G02B1/04 , B29C64/112 , B29C64/135 , B33Y70/00 , B33Y80/00 , B29C37/00 , G02C7/02 , B29K63/00 , B29K69/00 , B29K105/00 , B29L11/00
CPC分类号： B29D11/00442 , B29C37/0025 , B29C64/112 , B29C64/135 , B29D11/00028 , B29D11/0048 , B33Y10/00 , B33Y70/00 , B33Y80/00 , G02B1/041 , G02B1/043 , B29K2063/00 , B29K2069/00 , B29K2105/0014 , B29L2011/0016 , G02C7/022
摘要： The present invention proposes a polymer composition of manufacturing ophthalmic lens by polymerization of polymerizable composition wherein the shrinkage phenomenon is minimized. The polymerizable composition comprised two different categories of monomers which are able during crosslinking to control and limit said chemical shrinkage.
The present invention comprises also ophthalmic lens obtained from said polymer composition using a manufacturing process of casting or additive manufacturing.-
公开(公告)号：US11434401B2
公开(公告)日：2022-09-06
申请号：US16607406
申请日：2018-04-25
发明人： Robert Valeri
IPC分类号： C09J175/14 , B32B7/12 , C08G18/67 , C08G18/81 , C08J5/12 , C09J5/00 , C09J11/06 , G02C7/10 , G02C7/14 , B29C65/00 , B29C65/52 , B29C65/48
摘要： Disclosed are UV curable adhesive compositions and methods to adhere polycarbonate substrates containing UV absorbers to glass for use in ophthalmic lenses.
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公开(公告)号：US20240022849A1
公开(公告)日：2024-01-18
申请号：US18371206
申请日：2023-09-21
发明人： Robert Valeri
IPC分类号： C09D183/06 , C09D4/00 , C09D7/61 , C09D7/40 , C09D7/63 , C09D135/02 , G02B1/14
CPC分类号： C09D183/06 , C09D4/00 , C09D7/61 , C09D7/67 , C09D7/63 , C09D135/02 , G02B1/14
摘要： The UV-curable coating compositions disclosed herein are provided for use as coatings for plastic (organic glass) substrates, and ophthalmic lenses, in particular. The compositions may be applied by a variety of means, including spin coating and inkjet coating. The coating compositions exhibit abrasion resistance comparable to conventional thermally-cured sol-gel coatings.
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公开(公告)号：US20200048472A1
公开(公告)日：2020-02-13
申请号：US16534558
申请日：2019-08-07
发明人： Robert Valeri
摘要： The UV-curable coating compositions disclosed herein are provided for use as coatings for plastic (organic glass) substrates, and ophthalmic lenses, in particular. The compositions may be applied by a variety of means, including spin coating and inkjet coating. The coating compositions exhibit abrasion resistance comparable to conventional thermally-cured sol-gel coatings.
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公开(公告)号：US10459248B2
公开(公告)日：2019-10-29
申请号：US15540197
申请日：2014-12-30
发明人： Robert Valeri
IPC分类号： G02C7/02 , G02B1/14 , B32B27/00 , C09D183/04 , G02B1/11
摘要： An ophthalmic article and methods of manufacturing the ophthalmic article are described herein. The ophthalmic article can include a first coating and a second coating. The first coating can include an abrasion resistant coating that includes flexible materials. The abrasion resistant coating can be radiation cured. The second coating can include a sputter-applied anti-reflective (AR) coating. Such an ophthalmic article can have a Bayer value of at or between 1.25 and 2.6, between 1.25 and 2.0 or 1.25 and 1.75; and a hand steel wool value of 3 or less.
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公开(公告)号：US20180003861A1
公开(公告)日：2018-01-04
申请号：US15540197
申请日：2014-12-30
发明人： Robert Valeri
IPC分类号： G02B1/14 , G02B1/11 , C09D183/04 , G02C7/02 , B32B27/00
摘要： An ophthalmic article and methods of manufacturing the ophthalmic article are described herein. The ophthalmic article can include a first coating and a second coating. The first coating can include an abrasion resistant coating that includes flexible materials. The abrasion resistant coating can be radiation cured. The second coating can include a sputter-applied anti-reflective (AR) coating. Such an ophthalmic article can have a Bayer value of at or between 1.25 and 2.6, between 1.25 and 2.0 or 1.25 and 1.75; and a hand steel wool value of 3 or less.
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公开(公告)号：US20170357032A1
公开(公告)日：2017-12-14
申请号：US15540155
申请日：2014-12-30
发明人： Robert Valeri
摘要： Hard coating compositions and articles coated with said hard coating compositions are described. The coating compositions include at least a first layer as a hard coating to which is adhered a sputtered silicon containing layer, wherein the hard coating is formed with an unhydrolyzed alkoxysilane monomer cured cationically to increase a total amount of hydroxyl functional groups available in the first layer upon curing. The increased hydroxyl functional groups in the hard coating interact with the sputtered silicon containing layer and promote adherence between the hard coating and the sputtered silicon containing layer.
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