公开(公告)号：US09315443B2

公开(公告)日：2016-04-19

申请号：US14000067

申请日：2011-12-01

申请人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Poetter ,  Anja Schubert ,  Jan Christoph Pfeffer ,  Thomas Tacke ,  Harald Haeger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

发明人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Poetter ,  Anja Schubert ,  Jan Christoph Pfeffer ,  Thomas Tacke ,  Harald Haeger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

IPC分类号： C07C227/00 ,  C07C67/62 ,  B01D11/04 ,  B01J39/04 ,  B01J39/16 ,  C07C227/40 ,  C07C229/08 ,  C02F1/26 ,  C02F1/42 ,  C02F101/34

CPC分类号： C07C67/62 ,  B01D11/0492 ,  B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F2001/425 ,  C02F2101/34 ,  C07C227/40 ,  C07C229/08

摘要： The invention relates to a method for removing an organic compound having one or more positive charges from an aqueous solution. Said method consists of the following steps a) the aqueous solution containing the organic compound, and a hydrophobic organic solution which contains a hydrophobic liquid cation exchanger having one or more negative charges and a negative total charge, are provided, b) the aqueous solution and the organic solution are brought into contact with each other and c) the organic solution is separated from the aqueous solution.

摘要翻译： 本发明涉及从水溶液中除去具有一个或多个正电荷的有机化合物的方法。 所述方法包括以下步骤a）含有有机化合物的水溶液和含有具有一个或多个负电荷和负总电荷的疏水液体阳离子交换剂的疏水性有机溶液，b）水溶液和 使有机溶液彼此接触并且c）将有机溶液与水溶液分离。

公开(公告)号：US20140039210A1

公开(公告)日：2014-02-06

申请号：US14000067

申请日：2011-12-01

申请人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Poetter ,  Anja Schubert ,  Jan Christoph ,  Thomas Tacke ,  Harald Haeger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

发明人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Poetter ,  Anja Schubert ,  Jan Christoph ,  Thomas Tacke ,  Harald Haeger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

IPC分类号： C07C67/62

CPC分类号： C07C67/62 ,  B01D11/0492 ,  B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F2001/425 ,  C02F2101/34 ,  C07C227/40 ,  C07C229/08

摘要： The invention relates to a method for removing an organic compound having one or more positive charges from an aqueous solution. Said method consists of the following steps a) the aqueous solution containing the organic compound, and a hydrophobic organic solution which contains a hydrophobic liquid cation exchanger having one or more negative charges and a negative total charge, are provided, b) the aqueous solution and the organic solution are brought into contact with each other and c) the organic solution is separated from the aqueous solution.

摘要翻译： 本发明涉及从水溶液中除去具有一个或多个正电荷的有机化合物的方法。 所述方法包括以下步骤a）含有有机化合物的水溶液和含有具有一个或多个负电荷和负总电荷的疏水液体阳离子交换剂的疏水性有机溶液，b）水溶液和 使有机溶液彼此接触并且c）将有机溶液与水溶液分离。

公开(公告)号：US20140054224A1

公开(公告)日：2014-02-27

申请号：US14000028

申请日：2011-12-01

申请人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Pötter ,  Anja Schubert ,  Jan Christoph Pfeffer ,  Thomas Tacke ,  Harald Häger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

发明人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Pötter ,  Anja Schubert ,  Jan Christoph Pfeffer ,  Thomas Tacke ,  Harald Häger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

IPC分类号： B01J39/16 ,  B01J39/04

CPC分类号： C07C67/62 ,  B01D11/0492 ,  B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F2001/425 ,  C02F2101/34 ,  C07C227/40 ,  C07C229/08

摘要： The present application relates to a process for removing an organic compound having one or more positive charges from an aqueous solution, comprising the steps a) provision of the aqueous solution comprising the organic compound and of a hydrophobic organic solution which comprises a liquid cation exchanger, where the liquid cation exchanger is hydrophobic, and where the liquid cation exchanger has one or more negative charges and an overall negative charge, b) contacting the aqueous solution and the organic solution, and c) separating off the organic solution from the aqueous solution.

摘要翻译： 本申请涉及从水溶液中除去具有一个或多个正电荷的有机化合物的方法，包括以下步骤：a）提供包含有机化合物的水溶液和包含液体阳离子交换剂的疏水性有机溶液， 其中液体阳离子交换剂是疏水性的，并且其中液体阳离子交换剂具有一个或多个负电荷和总负电荷，b）使该水溶液和有机溶液接触，和c）从该水溶液中分离有机溶液。

公开(公告)号：US10071951B2

公开(公告)日：2018-09-11

申请号：US14000028

申请日：2011-12-01

申请人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Pötter ,  Anja Schubert ,  Jan Christoph Pfeffer ,  Thomas Tacke ,  Harald Häger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

发明人： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Pötter ,  Anja Schubert ,  Jan Christoph Pfeffer ,  Thomas Tacke ,  Harald Häger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

IPC分类号： B01D11/00 ,  B01J39/04 ,  C07C67/62 ,  B01D11/04 ,  B01J39/16 ,  C07C227/40 ,  C07C229/08 ,  C02F1/26 ,  C02F1/42 ,  C02F101/34

CPC分类号： C07C67/62 ,  B01D11/0492 ,  B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F2001/425 ,  C02F2101/34 ,  C07C227/40 ,  C07C229/08

摘要： The present application relates to a process for removing an organic compound having one or more positive charges from an aqueous solution, comprising the steps a) provision of the aqueous solution comprising the organic compound and of a hydrophobic organic solution which comprises a liquid cation exchanger, where the liquid cation exchanger is hydrophobic, and where the liquid cation exchanger has one or more negative charges and an overall negative charge, b) contacting the aqueous solution and the organic solution, and c) separating off the organic solution from the aqueous solution.

公开(公告)号：US09919303B2

公开(公告)日：2018-03-20

申请号：US14419580

申请日：2013-07-24

申请人： Frank Erhardt ,  Lukas Falke ,  Ralf Kelle ,  Harald Haeger ,  Thomas Haas ,  Hans-Georg Hennemann ,  Oliver Thum ,  Martin Roos ,  Markus Poetter

发明人： Frank Erhardt ,  Lukas Falke ,  Ralf Kelle ,  Harald Haeger ,  Thomas Haas ,  Hans-Georg Hennemann ,  Oliver Thum ,  Martin Roos ,  Markus Poetter

IPC分类号： B01J39/04 ,  C07C209/90 ,  B01J39/16 ,  C02F1/42 ,  C02F1/26 ,  C07C227/40 ,  C07C209/84 ,  C02F101/30 ,  C02F101/38 ,  C02F103/36

CPC分类号： B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F1/42 ,  C02F2001/425 ,  C02F2101/30 ,  C02F2101/38 ,  C02F2103/36 ,  C07C209/84 ,  C07C209/90 ,  C07C227/40 ,  C07C2601/14

摘要： The present invention relates to a method for removing an organic compound from an aqueous solution, comprising the steps of providing the aqueous solution which contains the organic compound, and a hydrophobic organic solution, where the latter comprises a liquid hydrophobic cation exchanger, contacting the aqueous solution and the hydrophobic organic solution, and separating off the hydrophobic organic solution from the aqueous solution, wherein the liquid hydrophobic cation exchanger is a saturated alkanoic acid having at least one alkyl substituent, where the organic compound is an organic compound having at least one positive charge and a neutral or positive total charge.

公开(公告)号：US20150209775A1

公开(公告)日：2015-07-30

申请号：US14419580

申请日：2013-07-24

申请人： Frank Erhardt ,  Lukas Falke ,  Ralf Kelle ,  Harald Haeger ,  Thomas Haas ,  Hans-Georg Hennemann ,  Oliver Thum ,  Martin Roos ,  Markus Poetter

发明人： Frank Erhardt ,  Lukas Falke ,  Ralf Kelle ,  Harald Haeger ,  Thomas Haas ,  Hans-Georg Hennemann ,  Oliver Thum ,  Martin Roos ,  Markus Poetter

IPC分类号： B01J39/04 ,  B01J39/16 ,  C07C209/90

CPC分类号： B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F1/42 ,  C02F2001/425 ,  C02F2101/30 ,  C02F2101/38 ,  C02F2103/36 ,  C07C209/84 ,  C07C209/90 ,  C07C227/40 ,  C07C2601/14

摘要： The present invention relates to a method for removing an organic compound from an aqueous solution, comprising the steps of providing the aqueous solution which contains the organic compound, and a hydrophobic organic solution, where the latter comprises a liquid hydrophobic cation exchanger, contacting the aqueous solution and the hydrophobic organic solution, and separating off the hydrophobic organic solution from the aqueous solution, wherein the liquid hydrophobic cation exchanger is a saturated alkanoic acid having at least one alkyl substituent, where the organic compound is an organic compound having at least one positive charge and a neutral or positive total charge.

摘要翻译： 本发明涉及一种从水溶液中除去有机化合物的方法，包括提供含有有机化合物的水溶液和疏水性有机溶液的步骤，其中后者包括液体疏水性阳离子交换剂， 溶液和疏水性有机溶液，并从水溶液中分离疏水性有机溶液，其中液体疏水性阳离子交换剂是具有至少一个烷基取代基的饱和链烷酸，其中有机化合物是具有至少一个阳性的有机化合物 充电和中性或正电荷。

公开(公告)号：US20130052700A1

公开(公告)日：2013-02-28

申请号：US13642412

申请日：2011-03-15

申请人： Markus Poetter ,  Andreas Schmid ,  Bruno Buehler ,  Hans-Georg Hennemann ,  Mattijs Kamiel Julsing ,  Steffen Schaffer ,  Thomas Haas ,  Manfred Schrewe ,  Sjef Cornelissen ,  Martin Roos ,  Harald Haeger

发明人： Markus Poetter ,  Andreas Schmid ,  Bruno Buehler ,  Hans-Georg Hennemann ,  Mattijs Kamiel Julsing ,  Steffen Schaffer ,  Thomas Haas ,  Manfred Schrewe ,  Sjef Cornelissen ,  Martin Roos ,  Harald Haeger

IPC分类号： C12P7/62 ,  C12P7/26 ,  C12P7/24 ,  C12P7/04 ,  C12P13/00 ,  C12P7/64 ,  C12N1/21 ,  C12N1/13 ,  C12P7/40 ,  C12P7/02

CPC分类号： C07K14/21 ,  C12P7/02 ,  C12P7/24 ,  C12P7/42 ,  C12P7/62 ,  C12P7/6436 ,  C12Y114/15003

摘要： The invention provides a biocatalytic process for oxidation of organic compounds with the aid of an alkL gene product, and microorganisms used in this process.

摘要翻译： 本发明提供了借助于alkL基因产物和在该方法中使用的微生物来氧化有机化合物的生物催化方法。

公开(公告)号：US09533933B2

公开(公告)日：2017-01-03

申请号：US14815014

申请日：2015-07-31

申请人： Kevin Micoine ,  Ralf Meier ,  Juergen Herwig ,  Martin Roos ,  Harald Haeger ,  Luca Cameretti ,  Jens Doering

发明人： Kevin Micoine ,  Ralf Meier ,  Juergen Herwig ,  Martin Roos ,  Harald Haeger ,  Luca Cameretti ,  Jens Doering

IPC分类号： C07C45/51 ,  C07C45/58 ,  C07D201/04 ,  B01J23/44 ,  C07C45/82 ,  C07C249/04 ,  C07D225/02 ,  C07D301/12 ,  C08G69/16 ,  C07C29/52 ,  C07C45/00 ,  C07C45/28 ,  C07C49/413

CPC分类号： C07C45/512 ,  B01J23/44 ,  C07C29/52 ,  C07C45/002 ,  C07C45/28 ,  C07C45/58 ,  C07C45/82 ,  C07C49/413 ,  C07C249/04 ,  C07D201/04 ,  C07D225/02 ,  C07D301/12 ,  C08G69/16 ,  C07C35/205

摘要： Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN, wherein CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a.

摘要翻译： 通过环环十二碳烯（CDEN）环氧环十二烷（CDAN环氧化物）制备环十二烷酮（CDON），并将CDAN环氧化物重排为CDON，得到包含所述CDON和CDEN的混合物，其中CDEN与含CDON的混合物分离并送至 在步骤a中对CDAN环氧化物进行环氧化。

公开(公告)号：US20120245375A1

公开(公告)日：2012-09-27

申请号：US13424548

申请日：2012-03-20

申请人： Peter HANNEN ,  Harald Haeger ,  Martin Roos

发明人： Peter HANNEN ,  Harald Haeger ,  Martin Roos

IPC分类号： C07C67/44

CPC分类号： C07C67/333 ,  C07C51/285 ,  C07C51/34 ,  C07C51/373 ,  C07C67/313 ,  C07C69/48 ,  C07C69/716 ,  C07C53/126 ,  C07C59/147 ,  C07C55/02

摘要： A process for preparing an alpha, omega-dicarboxylic acid or an ester thereof, which includes (a) subjecting at least one unsaturated fatty acid or fatty acid derivative to ozonolysis to obtain an ozonolysis reaction mixture; and (b) oxidizing the ozonolysis reaction mixture with an oxidizing agent in the presence of an acid catalyst to obtain an oxidized reaction mixture comprising at least one alpha, omega-dicarboxylic acid or ester; wherein the process is performed using a solvent and the acid catalyst has a pKa of less than or equal to zero, as measured at 25° C.

摘要翻译： 一种制备α，ω-二羧酸或其酯的方法，其包括（a）使至少一种不饱和脂肪酸或脂肪酸衍生物进行臭氧分解以获得臭氧分解反应混合物; 和（b）在酸催化剂存在下用氧化剂氧化臭氧分解反应混合物，得到包含至少一种α，ω-二羧酸或酯的氧化反应混合物; 其中所述方法使用溶剂进行，并且所述酸催化剂的pKa小于或等于零，如在25℃下测量的。

公开(公告)号：US20110015434A1

公开(公告)日：2011-01-20

申请号：US12922807

申请日：2009-04-16

申请人： Peter Hannen ,  Martin Roos ,  Harald Haeger

发明人： Peter Hannen ,  Martin Roos ,  Harald Haeger

IPC分类号： C07C51/36 ,  C07C51/347

CPC分类号： C07C51/353 ,  C07C51/36 ,  C07C51/43 ,  C07C51/44 ,  C07C57/13 ,  C07C55/21

摘要： The invention relates to a method for producing 1,2-dodeca-2,10-diene diacid and 1,12-dodecanoic acid whereby cyclooctene and acrylic acid are reacted with a ruthenium catalyst by way of a metathesis reaction at high substrate concentrations until the reaction takes place in substance, the resulting unsaturated dicarboxylic acid being precipitated and being hydrated in a second reaction step.

摘要翻译： 本发明涉及一种1,2-十二碳-2,10-二烯二酸和1,12-十二烷酸的制备方法，其中环辛烯和丙烯酸通过在高底物浓度下的复分解反应与钌催化剂反应，直到 反应发生在物质中，所得的不饱和二羧酸在第二反应步骤中沉淀并水合。