Catalytic cracking of coke producing hydrocarbons
    1.
    发明授权
    Catalytic cracking of coke producing hydrocarbons 失效
    焦炭生产碳氢化合物的催化裂化

    公开(公告)号:US5271826A

    公开(公告)日:1993-12-21

    申请号:US502008

    申请日:1990-03-30

    IPC分类号: C10G11/00 C10G11/18

    CPC分类号: C10G11/18

    摘要: A process for thermally and catalytically upgrading a heavy feed in a single riser reactor FCC unit is disclosed. A heavy feed is added to a blast zone in the base of the riser, and sufficient hot regenerated FCC catalyst is added to induce both thermal and catalytic cracking of the heavy feed. A reactive quench material, which cools the material discharged from the blast zone is added to a quench zone downstream of the blast zone, to reduce temperature at least in part by undergoing endothermic reactions in the riser. Quench liquids can be distillable FCC feeds such as gas oil, slack wax, or alcohols or ethers. The quench material is added in an amount equal to 100 to 1000 wt % of the non-distillable material in the heavy feed. A preferred catalyst, with a high zeolite content, is used which retains activity in the quench despite initial contact with the heavy feed, which tends to overwhelm conventional FCC catalysts.

    摘要翻译: 公开了一种用于热和催化升级单个提升管反应器FCC单元中重质进料的方法。 将重的原料加入到提升管底部的鼓风区中,并加入足够的热再生FCC催化剂以诱导重质进料的热和催化裂化。 将从鼓风区排出的材料冷却的反应性淬火材料加入到鼓风区下游的骤冷区,至少部分通过在提升管中经受吸热反应来降低温度。 淬火液体可以是可蒸馏的FCC进料,例如瓦斯油,松散蜡或醇或醚。 淬火材料的添加量等于重料中不可蒸馏材料的100-1000wt%。 使用具有高沸石含量的优选的催化剂,其保持淬灭中的活性,尽管与重质进料初始接触,这倾向于压倒常规的FCC催化剂。

    Thermocouple probe and method for measuring fluid flow rates
    3.
    发明授权
    Thermocouple probe and method for measuring fluid flow rates 失效
    热电偶探头和流体流量测量方法

    公开(公告)号:US4750357A

    公开(公告)日:1988-06-14

    申请号:US839240

    申请日:1986-03-13

    IPC分类号: B01J8/00 G01F1/68 G01F1/74

    CPC分类号: B01J8/001 G01F1/68 G01F1/74

    摘要: A method for measuring local fluid flow rates in a vessel, e.g., a packed bed two-phase flow catalytic reactor, is disclosed which comprises:(a) arranging a plurality of heated thermocouple probes in the vessel at predetermined locations in the path of the fluid flow therethrough;(b) obtaining a first set of temperature readings with the probe heaters off to provide the local reactor temperature;(c) obtaining a second set of temperature readings with the probe heaters on to provide the skin temperature of the heater well;(d) using the difference between readings (b) and (c) to calculate the fluid flow rates.

    摘要翻译: 公开了一种用于测量容器(例如填充床两相流动催化反应器)中的局部流体流速的方法,其包括:(a)在容器中的预定位置处将多个加热的热电偶探针布置在容器的路径中的预定位置处 流体流过其中; (b)用探针加热器取出第一组温度读数以提供局部反应器温度; (c)用探针加热器获得第二组温度读数以提供加热器的皮肤温度; (d)使用读数(b)和(c)之间的差来计算流体流速。

    Method of adding zsm-5 containing catalyst to fluid bed catalytic
cracking units
    5.
    发明授权
    Method of adding zsm-5 containing catalyst to fluid bed catalytic cracking units 失效
    将含有zsm-5的催化剂加入到流化床催化裂化装置中的方法

    公开(公告)号:US4994173A

    公开(公告)日:1991-02-19

    申请号:US470025

    申请日:1990-01-25

    摘要: Modified ZSM-5 type zeolite catalyst is prepared by controlled aging in a moving bed catalytic cracking unit. The modified catalyst exhibits significant olefin isomerization activity and reduced paraffin cracking activity. Hydrocarbons are cracked to products boiling in the motor fuel range, e.g., gasoline, by using the modified catalyst mixture comprising a ZSM-5 type zeolite and a conventional cracking catalyst. The ZSM-5 type zeolite is treated with partial pressure steam under conditions which increase the gasoline octane number of the product fuel without decreasing gasoline plus distillate yield. A process for changing a catalytic cracking unit's inventory from a conventional catalyst to a modified ZSM-5 type containing catalyst is also disclosed.

    摘要翻译: 改性ZSM-5型沸石催化剂是通过在移动床催化裂化装置中控制老化来制备的。 改性催化剂表现出显着的烯烃异构化活性和降低的链烷烃裂解活性。 通过使用包含ZSM-5型沸石和常规裂化催化剂的改性催化剂混合物,将碳氢化合物裂解成在发动机燃料范围内沸腾的产物,例如汽油。 在增加产品燃料的汽油辛烷值但不降低汽油加馏出物产率的条件下,用分压蒸汽处理ZSM-5型沸石。 还公开了将催化裂化装置的库存从常规催化剂改变为含改性ZSM-5的催化剂的方法。

    Quenched catalytic cracking process
    6.
    发明授权
    Quenched catalytic cracking process 失效
    淬火催化裂化工艺

    公开(公告)号:US4978440A

    公开(公告)日:1990-12-18

    申请号:US463831

    申请日:1990-01-08

    IPC分类号: C10G11/18

    CPC分类号: C10G11/18

    摘要: A fluidized catalytic riser cracking process is disclosed wherein a quench stream, preferably water or steam, is injected downstream of the riser reactor outlet to decrease the residence time and temperature of a majority of the hydrocarbons in a reactor vessel accepting a riser reactor effluent.

    摘要翻译: 公开了一种流化催化提升管裂解方法,其中将骤冷料流,优选水或蒸汽注入提升管反应器出口的下游,以减少反应器容器中大部分烃的停留时间和温度,从而接受提升管反应器流出物。

    Process for removing metals from crude
    7.
    发明授权
    Process for removing metals from crude 失效
    从原油中除去金属的方法

    公开(公告)号:US4645589A

    公开(公告)日:1987-02-24

    申请号:US789218

    申请日:1985-10-18

    摘要: A process for removing metal from a metal-containing hydrocarbon oil such as a heavy crude is disclosed which comprises:(a) contacting a hydrocarbon oil phase containing at least one metal selected from the group consisting of vanadium and nickel with an aqueous phase of dissolved phosphorous compound capable of forming a compound or a complex with said metal, said aqueous phase containing a substantial quantity of water relative to the amount of liquid hydrocarbon contacted therewith, said contacting resulting in the removal of a substantial quantity of the metal from the hydrocarbon oil phase to the aqueous phase; and,(b) separating the metal-containing aqueous phase from the demetalated hydrocarbon oil phase prior to subjecting the latter to downstream catalytic processing.

    摘要翻译: 公开了一种从含金属的烃油如重质原油中除去金属的方法,其包括:(a)使含有至少一种选自钒和镍的金属的烃油相与溶解的 能够与所述金属形成化合物或络合物的磷化合物,所述水相相对于与其接触的液体烃的量含有大量的水,所述接触导致从烃油中除去大量的金属 相到水相; 和(b)在将金属含水相与脱金属烃油相进行下游催化处理之前分离。

    FCC unit combined with a circulating fluid bed combustor
    9.
    发明授权
    FCC unit combined with a circulating fluid bed combustor 失效
    FCC单元与循环流化床燃烧器结合

    公开(公告)号:US4784748A

    公开(公告)日:1988-11-15

    申请号:US113318

    申请日:1987-10-28

    IPC分类号: C10G11/18

    CPC分类号: C10G11/18

    摘要: The invention combines two unit operations i.e. fluid catalytic cracking (FCC) and circulating fluid bed (CFB) boiler technologies. The circulating solid inventory of the CFB boiler is introduced to the bottom of a conventional FCC unit to supply the endothermic heat of reaction. A once-through FCC catalyst is introduced under high-temperature, short residence time conditions whereby improved yields are achieved through the reduction of coke made in the FCC unit.

    摘要翻译: 本发明组合了两种单元操作,即流化催化裂化(FCC)和循环流化床(CFB)锅炉技术。 CFB锅炉的循环固体库存被引入常规FCC装置的底部以提供反应的吸热。 在高温,短停留时间条件下引入一次直接FCC催化剂,从而通过减少在FCC装置中制造的焦炭来实现提高的产率。

    Multistage conversion of lower olefins with interreactor quenching
    10.
    发明授权
    Multistage conversion of lower olefins with interreactor quenching 失效
    低级烯烃与反应器淬火的多级转化

    公开(公告)号:US4740645A

    公开(公告)日:1988-04-26

    申请号:US903915

    申请日:1986-09-05

    摘要: A continuous multi-stage catalytic process for converting ethene-rich lower olefinic feedstock to heavier liquid hydrocarbon product, comprising the steps ofcontacting ethene-rich feedstock at elevated temperature and moderate pressure in a primary stage reaction zone with a first catalyst comprising shape selective medium pore zeolite to convert at least a portion of the lower olefinic components to intermediate olefinic hydrocarbons;cooling primary stage reaction effluent by introducing a stream of cold water sufficient to reduce the primary stage effluent to second stage reaction temperature; andcontacting unreacted ethene and at least a portion of the intermediate olefinic hydrocarbons from the primary stage with nickel-containing shape selective medium pore zeolite oligomerization component at elevated temperature to provide a heavier hydrocarbon effluent stream comprising gasoline and/or distillate range hydrocarbons.

    摘要翻译: 一种用于将含富烯烃的较低级烯烃原料转化为较重液体烃产物的连续多级催化方法,包括以下步骤:在初级阶段反应区中将升温和中等压力的富含烯烃的原料与包含形状选择介质 孔沸石将至少一部分低级烯烃组分转化成中间体烯烃; 通过引入足以将初级阶段流出物降至第二阶段反应温度的冷水流来冷却初级反应流出物; 并在升高的温度下使未反应的乙烯和至少一部分来自初级阶段的中间体烯烃与含镍形状选择性中孔沸石低聚组分接触,以提供包含汽油和/或馏出物范围烃的较重烃流出物流。