公开(公告)号：US5685973A

公开(公告)日：1997-11-11

申请号：US653094

申请日：1996-05-24

Applicant: Stacey I. Zones ,  Andrew Rainis

Inventor： Stacey I. Zones ,  Andrew Rainis

IPC: B01J29/04 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C5/22 ,  C07C5/27 ,  C07C5/41 ,  C07C6/12 ,  C10G3/00 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  C10G50/00

CPC classification number: C10G50/00 ,  B01J29/04 ,  C01B39/082 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C5/226 ,  C07C5/2724 ,  C07C5/41 ,  C07C5/415 ,  C07C6/126 ,  C10G11/05 ,  C10G3/44 ,  C10G3/45 ,  C10G3/49 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  C07C2529/064 ,  C10G2300/1037 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2400/02 ,  C10G2400/30 ,  Y02P30/20

Abstract: The present invention relates to new crystalline zeolite SSZ-42 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using an organic templating agent selected from the group consisting of N-benzyl-1,4-diazabicyclo�2.2.2!octane cations and N-benzyl-1-azabicyclo�2.2.2!octane cations.

Abstract translation: 本发明涉及通过使用选自N-苄基-1,4-二氮杂双环[2.2.2]二氧杂环己烷的有机模板剂制备结晶分子筛，特别是大孔沸石的方法制备的新的结晶沸石SSZ-42， 辛烷阳离子和N-苄基-1-氮杂双环[2.2.2]辛烷阳离子。

公开(公告)号：US5371312A

公开(公告)日：1994-12-06

申请号：US42430

申请日：1993-04-05

Applicant: Rudolph M. Lago ,  David O. Marler ,  Sharon B. McCullen ,  David H. Olson

Inventor： Rudolph M. Lago ,  David O. Marler ,  Sharon B. McCullen ,  David H. Olson

IPC: B01J29/40 ,  B01J31/02 ,  B01J31/12 ,  C07C1/20 ,  C07C2/12 ,  C07C2/66 ,  C07C5/27 ,  C07C5/41 ,  C07C6/12 ,  C10G45/64 ,  C07C5/52

CPC classification number: C10G45/64 ,  B01J29/40 ,  B01J31/123 ,  C07C1/20 ,  C07C2/12 ,  C07C2/66 ,  C07C5/2708 ,  C07C5/41 ,  C07C6/123 ,  C07C6/126 ,  B01J2229/12 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/06 ,  C07C2529/064 ,  Y02P20/52

Abstract: A process for shape selective hydrocarbon conversion involves contacting a hydrocarbon feedstream under conversion conditions with a catalytic molecular sieve which has been modified by treatment with an amino silane polymer while molecular sieve acid sites are protected. When the process is toluene disproportionation, a toluene feedstream may also contain a second silicon source which is a high pxylene selectivating agent. The invention also includes the modification method and the shape selective catalyst which results from the modification.

Abstract translation: 用于形状选择性烃转化的方法包括在转化条件下使烃进料流与催化分子筛接触，催化分子筛在分子筛酸性位点受到保护时已用氨基硅烷聚合物进行改性。 当该方法是甲苯歧化反应时，甲苯进料流还可以含有第二硅源，其是高的吡咯啉选择性试剂。 本发明还包括由改性产生的改性方法和形状选择性催化剂。

公开(公告)号：US20140296602A1

公开(公告)日：2014-10-02

申请号：US14277532

申请日：2014-05-14

Applicant: UOP LLC

Inventor： Neelesh J. Rane ,  Paula Bogdan ,  Veronica G. Deak ,  Patrick Whitchurch ,  Karl Z. Steigleder ,  Marlyn A. Hamborg ,  Wharton Sinkler ,  Steven A. Bradley

IPC: C07C5/27

CPC classification number: B01J29/7469 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/186 ,  B01J2229/42 ,  C07C5/2775 ,  C07C2521/04 ,  C07C2529/064 ,  C07C2529/70 ,  C07C2529/74 ,  Y02P20/52 ,  C07C15/08

Abstract: An extruded C8 alkylaromatic isomerization catalyst is described. The catalyst has an average pore diameter in a range of about 110 Å to about 155 Å measured by BJH adsorption method and a pore volume less than about 0.62 cc/g measured by N2 porosimetry. A process for isomerizing a non-equilibrium C8 aromatic feed to provide an isomerized product is also described.

公开(公告)号：US4008291A

公开(公告)日：1977-02-15

申请号：US587470

申请日：1975-06-16

Applicant: Robert F. Zabransky ,  Robert F. Anderson

Inventor： Robert F. Zabransky ,  Robert F. Anderson

IPC: B01J8/04 ,  B01J29/90 ,  C07C2/66 ,  C07C3/52

CPC classification number: B01J29/90 ,  B01J8/0453 ,  C07C2/66 ,  C07C2529/064 ,  Y02P20/582 ,  Y02P20/584 ,  Y10S585/906

Abstract: A continuous catalytic alkylation reaction and catalyst reactivation process is carried out using a simulated moving catalyst bed to effect simultaneously in different zones of a multi-zone, fixed catalyst bed, an alkylation reaction and a reactivation of catalyst. The catalyst of the present invention is a crystalline aluminosilicate zeolite composited with a Group VIII metal hydrogenation agent, and the reactivation medium utilized includes alkylatable hydrocarbon and hydrogen.

Abstract translation: 使用模拟移动催化剂床，在多区域，固定催化剂床，烷基化反应和催化剂的再活化的不同区域中同时进行连续催化烷基化反应和催化剂再活化过程。 本发明的催化剂是与VIII族金属氢化剂复合的结晶硅铝酸盐沸石，所用的再活化介质包括可烷基烃和氢。

公开(公告)号：US3851004A

公开(公告)日：1974-11-26

申请号：US40117873

申请日：1973-09-27

Applicant: UNION CARBIDE CORP

Inventor： YANG C

IPC: B01J23/00 ,  B01J29/10 ,  B01J29/90 ,  B01J38/58 ,  C07B31/00 ,  C07B37/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/58 ,  C07C2/66 ,  C07C9/16 ,  C07C15/00 ,  C07C67/00 ,  C07C3/52

CPC classification number: C07C2/58 ,  B01J29/10 ,  B01J29/90 ,  B01J38/58 ,  C07C2/66 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2529/064 ,  Y02P20/584 ,  Y10S585/906 ,  C07C15/02

Abstract: 1. IN AN ALKYLATION PROCESS IN WHICH AN ALKYLATABLE ORGANIC COMPOUND IS CONTACTED AND REACTED WITH AN ALKYLATION AGENT IN A CATALYTIC CONVERSION ZONE CONTAINING A CATALYST COMPOSITION COMPRISING AT LEAST ONE HYDROGENATION AGENT OF THE GROUP OF NICKEL, PLATINUM, PALLADIUM, RUTHENIUM AND RHODIUM AND THREE-DIMENSIONAL CRYSTALLINE ZEOLITIC MOLECULAR SIEVE HAVING A PORE DIAMETER LARGE ENOUGH TO ADSORB ORTHO-DIETHYLBENZENE, AN ALKALI METAL CONTENT OF LESS THAN 3.5 WEIGHT PERCENT ON A SOLIDS BASIS, AN SIO2/AL2O/3 MOLAR RATIO OF AT LEAST 7.0. SAID CONTACT AND REACTION BEING CONTINUED UNTIL THE ALKYLATION ACTIVITY OF THE CATALYST HAS DECREASED, THE IMPROVEMENT WHICH COMPRISES PERIDICALLY CONTACTING A DHYDROGENATING THE CATALYST COMPOSITION AT A TEMPERATURE OF FROM 80*F. TO 572*F. WITH A LIQUID SOLUTION OF HYDROGEN IN A SATURATED HYDROCARBON HAVING FROM 4 TO 12 CARBON ATOMS, SAID SOLUTION CONTAINING AT LEAST 0.1 MOLE PERCENT DISSOLVED HYDROGEN, UNTIL THE ALKYLATION ACTIVITY OF THE CATALYST IS IMPROVED.

公开(公告)号：US3578723A

公开(公告)日：1971-05-11

申请号：US3578723D

申请日：1968-04-18

Applicant: MOBIL OIL CORP

Inventor： BOWES EMMERSON ,  WISE JOHN J

IPC: B01J29/50 ,  B01J29/70 ,  C07C5/27 ,  C07C6/12 ,  C01B33/28 ,  C07C3/58 ,  C07C5/22

CPC classification number: C07C6/12 ,  B01J29/50 ,  B01J29/7011 ,  C07C5/2708 ,  C07C5/2737 ,  C07C2529/064 ,  C07C15/00

Abstract: A NEW AND UNUSUAL FAMILY OF CRYSTALLINE ZEOLITES IDENTIFIED AS ZEOLITE ZSM-4 ARE USED AS CATALYSTS FOR THE ISOMERIZATION AND DISPROPORTIONATION OF AROMATIC HYDROCARBONS.

公开(公告)号：US3496246A

公开(公告)日：1970-02-17

申请号：US3496246D

申请日：1969-03-14

Applicant: MOBIL OIL CORP

Inventor： CHEN NAI YUEN

IPC: B01J20/18 ,  B01J29/064 ,  C07C5/03 ,  C07C11/00 ,  C07C11/06 ,  C07C5/04 ,  C07C5/14

CPC classification number: C01B33/2892 ,  B01J20/186 ,  B01J29/064 ,  C07C5/03 ,  C07C2529/064 ,  Y10S585/906 ,  C07C9/06

公开(公告)号：US09481617B2

公开(公告)日：2016-11-01

申请号：US14264441

申请日：2014-04-29

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Scott A. Stevenson ,  Alla K. Khanmamedova ,  Dustin B. Farmer ,  Scott F. Mitchell ,  Jim Vartuli

IPC: C07C2/12 ,  C07C5/32 ,  C07C1/20 ,  C07C5/41 ,  B01J29/04 ,  B01J29/83 ,  B01J29/85 ,  C07C2/24 ,  C07C2/66 ,  C07C2/76 ,  C07C6/12 ,  C10G35/095 ,  B01J29/84 ,  C07C2/42 ,  C07C5/31 ,  C07C5/367 ,  C10G35/09 ,  C10G35/085

CPC classification number: C07C1/20 ,  B01J29/047 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/186 ,  C07C2/12 ,  C07C2/24 ,  C07C2/42 ,  C07C2/66 ,  C07C2/76 ,  C07C5/31 ,  C07C5/367 ,  C07C5/412 ,  C07C5/417 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/064 ,  C07C2529/44 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/83 ,  C07C2529/85 ,  C10G35/085 ,  C10G35/09 ,  C10G35/095 ,  Y02P20/52 ,  C07C15/02

Abstract: In an embodiment a catalyst comprises a medium or large pore zeolite having germanium incorporated into the zeolite framework. The zeolite can have a pore structure that is one dimensional, two dimensional or three dimensional. A metal selected from Group 10 can be deposited on the zeolite. In an embodiment, a process for synthesizing the zeolite comprises preparing a medium pore zeolite containing germanium in the framework of the zeolite and calcining the zeolite. In an embodiment, the catalyst can be used in a process for the conversion of hydrocarbons comprising contacting a hydrocarbon stream containing alkanes, olefins, or mixtures thereof having 2 to 12 carbon atoms per molecule with the catalyst and recovering the product.

Abstract translation: 在一个实施方案中，催化剂包含掺入沸石骨架中的锗的中孔或大孔沸石。 沸石可以具有一维，二维或三维的孔结构。 选自组10的金属可以沉积在沸石上。 在一个实施方案中，合成沸石的方法包括在沸石的骨架中制备含有锗的中孔沸石并煅烧沸石。 在一个实施方案中，催化剂可用于烃的转化方法，包括使含有每分子具有2至12个碳原子的烷烃，烯烃或其混合物的烃流与催化剂接触并回收产物。

公开(公告)号：US09266100B2

公开(公告)日：2016-02-23

申请号：US13697640

申请日：2011-05-17

Applicant: Suman Kumar Jana

Inventor： Suman Kumar Jana

IPC: B01J29/06 ,  B01J29/48 ,  B01J29/064 ,  B01J29/46 ,  B01J29/068 ,  B01J29/44 ,  B01J29/072 ,  B01J29/42 ,  B01J29/076 ,  C07C2/76 ,  B01J37/08

CPC classification number: B01J29/48 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J37/0236 ,  B01J37/08 ,  B01J2229/16 ,  B01J2229/40 ,  B01J2229/42 ,  C07C2/76 ,  C07C2523/28 ,  C07C2529/064 ,  C07C2529/068 ,  C07C2529/072 ,  C07C2529/076 ,  C07C2529/40 ,  C07C2529/42 ,  C07C2529/46 ,  C07C2529/48 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/04

Abstract: The present invention relates to a method for producing a zeolite catalyst useful for aromatization of a lower alkane, a zeolite catalyst useful for aromatization of a lower alkane obtainable by said method and a process for aromatization of a lower alkane using the zeolite catalyst of the present invention.

Abstract translation: 本发明涉及一种生产用于低级烷烃芳构化的沸石催化剂的方法，可用于通过所述方法获得的低级烷烃芳构化的沸石催化剂和使用本发明的沸石催化剂使低级烷烃芳构化的方法 发明。

公开(公告)号：US07358411B2

公开(公告)日：2008-04-15

申请号：US10872703

申请日：2004-06-21

Applicant: Brendan Dermot Murray ,  Garo Garbis Vaporciyan

Inventor： Brendan Dermot Murray ,  Garo Garbis Vaporciyan

IPC: C07C4/26

CPC classification number: C07C4/24 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/40 ,  C07C2523/44 ,  C07C2523/72 ,  C07C2523/74 ,  C07C2529/064 ,  C07C2529/22 ,  Y02P20/127 ,  C07C15/085

Abstract: The invention relates to a hydrocracking process involving the steps of reacting a diphenyl alkane having a formulation of R1R2C(Ph)-(C)n(H)m-C(Ph)R3R4 with hydrogen using a catalyst containing a metal selected from the group consisting of Group IB and Group VIII metal compounds, preferably on an acidic support, to produce alkylbenzene(s) having a structure of R1R2C(Ph)R5 and R6(Ph)CR3R4; wherein the total number of carbon atoms for R5 and R6 is equal to n; wherein R1, R2, R3, R4 each is a H or a hydrocarbon group having 1-10 carbon atoms.

Abstract translation: 本发明涉及一种加氢裂化方法，其涉及使用含有选自以下的金属的催化剂使具有R1R2C（Ph） - （C）n（H）mC（Ph）R3R4的配方的二苯基烷烃与氢气反应 IB族和VIII族金属化合物，优选在酸性载体上，以产生具有R 1 R 2 C（Ph）R 5和R 6（Ph）CR 3 R 4结构的烷基苯; 其中R5和R6的碳原子总数等于n; 其中R1，R2，R3，R4各自为H或具有1-10个碳原子的烃基。