摘要:
Methods, apparatus and precursors for producing substantially water-free silica soot, preforms and glass. The methods and apparatus make substantially water-free fused silica preforms or glass by removing water as a reaction product, removing water from the atmosphere, removing water from the transport process, or combinations thereof. In a first embodiment, substantially water-free soot, preforms or glass are achieved by using a hydrogen-free fuel, such as carbon monoxide, in the deposition process. In another embodiment, a soot producing burner has parameters that enable operation on a substantially hydrogen-free fuel. End burners, which minimize water production, are also described. Such water-free methods are useful in depositing fluorine-doped soot because of the low water present and the efficiency in which fluorine is incorporated. In another embodiment, glassy barrier layer methods and apparatus are described for minimizing dopant migration, especially fluorine. Laser and induction methods and apparatus for forming the barrier layer are depicted. A chlorine, fluorine and silica precursor, such as chlorofluorosilane, may be utilized to form fluorinated soot. Other methods and apparatus are directed to combinations of conventional and substantially water-free processes. One embodiment is directed to combustion enhancing additives for addition to the substantially hydrogen-free fuels. The methods and apparatus in accordance with the invention are particularly useful for producing photomask substrates and optical fiber preforms.
摘要:
The invention includes a method of incorporating fluorine into a preform that may be used to produce an optical article. A method that may be used to practice the invention includes a method of making an optical fiber preform. The method includes reacting a fluorine containing precursor in a flame of a combustion burner without forming a soot, thereby forming a fluorine doping atmosphere. A further method that may be practiced to practice the invention includes the step reacting at least a fluorine containing precursor in a flame of a combustion burner, wherein the precursors reacted in the flame are substantially devoid of the element of silicon, thereby forming a fluorine containing atmosphere for the doping of a soot preform. An additional method that may be used to practice the invention includes the step of reacting at least one precursor in the flame of a combustion burner, wherein said precursors comprise at least one fluorine containing compound and the precursors are substantially free of any silicon containing compound, and the additional step of directing a reaction product of said reacting step toward a soot preform.
摘要:
A method of manufacturing an optical waveguide preform includes providing a first process gas atmosphere to a soot preform contained in a vessel. The first atmosphere is held in the vessel for a first reacting time sufficient to at least partially dope or dry the soot preform. The vessel is then at least partially refilled with a second doping or drying atmosphere. The second doping or drying atmosphere is held in the vessel for a second reacting time sufficient to further dope or dry the soot preform.
摘要:
A method of making an optical waveguide preform includes forming a preform including a first portion and a second radial portion, wherein the second portion includes a dopant, and wherein the first portion exhibits a density greater than the second portion. The method further includes stripping at least a portion of the dopant from the second portion. In a preferred embodiment, the stripped dopant has migrated in a previous processing step.
摘要:
A dynamically tunable filter controls the magnitude of couplings between core and cladding modes of a waveguide by surrounding the waveguide with an overcladding having an adjustable refractive index. The coupled modes are attenuated along the core to produce the desired spectral response. The adjustment to the overcladding index is made in a range that is above the refractive index of the underlying cladding to vary amplitudes of attenuated bands of wavelengths without shifting central wavelengths of the bands.
摘要:
The present invention relates to a tunable optical device 10 that includes an optical fiber device 12 having optical properties that vary with temperature and a heater 14. The heater 14 is thermally coupled to the optical fiber device 12. The heater 14 includes a metal layer 18 and two electrical contacts 20, 22 that are electrically connected to the metal layer 18. The electrical contacts 20, 22 are spaced apart from one another along the metal layer 18. The electrical resistance of the portion of the metal layer 18 between the contacts 20, 22 varies with temperature and serves as a resistive heater. The invention also includes a controller 16 that is electrically connected to the heater 14. The controller 16 provides electrical power to the heater 14 and measures the electrical voltage across the heater 14. The controller 16 compares the measured electrical voltage to a pre-selected reference value. The controller then regulates the amount of electrical current supplied to the heater 14. By regulating the amount of electrical current supplied to the heater 14 the temperature of the heater 14 is controlled.
摘要:
Silicon nitride reinforcing fibers provided with a protective surface coating comprising a boron nitride base layer and, optionally, an alumina overcoating, and fiber-reinforced ceramic matrix composite products incorporating the protectively-coated fibers, are disclosed. The composites offer significantly improved high temperature strength in combination with low dielectric constant and low dielectric loss characteristics.
摘要:
This invention relates to the production of laminated structures consisting essentially of a light weight interior member prepared from a glass, glass-ceramic, or ceramic, an exterior member prepared from a glass, glass-ceramic, or ceramic, and a bonding member prepared from a glass, glass-ceramic, or ceramic. The light weight interior member may be composed of a porous body, a corrugated body, or a honeycomb body. In a preferred embodiment, at least one of said members is reinforced through the entrainment of ceramic fibers and/ or whiskers. In the most preferred embodiment, each exterior and interior member is reinforced through the entrainment of ceramic fibers and/or whiskers and the bonding member is reinforced through the entrainment of ceramic whiskers.
摘要:
A UV light-curable composition comprises: (a) a first component, said first component being UV light-polymerizable polymer having a first index of refraction; and (b) a second component, the second component being UV light-polymerizable monomer having a second index of refraction, the second index of refraction being higher than said first index of refraction; wherein the first component polymerizes slower upon exposure to UV radiation than the second component.
摘要:
A method of making an in situ shaped optical element on the terminal end of an optical fiber, and the resultant optical fiber component for manipulating light entering or exiting the terminal end of an optical fiber. The in situ shaped optical element is preferably an inorganic-organic hybrid sol-gel material which is adhered to the terminal end of the optical fiber and shaped in place to define an optical element or surface.