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    Cosmetic composition for protection against ultraviolet radiation and its use for this purpose
    1.
    发明授权
    Cosmetic composition for protection against ultraviolet radiation and its use for this purpose 失效
    用于防止紫外线辐射的化妆品组合物及其用于此目的

    公开(公告)号：US4726942A

    公开(公告)日：1988-02-23

    申请号：US575754

    申请日：1984-02-01

    申请人： Gerard Lang ,  Alain Malaval ,  Madeleine Leduc

    发明人： Gerard Lang ,  Alain Malaval ,  Madeleine Leduc

    IPC分类号： A61K8/37 ,  A61K8/42 ,  A61K9/10 ,  A61K9/12 ,  A61Q17/04 ,  C06B23/00 ,  C06B25/24 ,  C06B25/34 ,  A61K7/42 ,  A61K7/44

    CPC分类号： A61Q17/04 ,  A61K8/37 ,  A61K8/42 ,  C06B23/007 ,  C06B25/24 ,  C06B25/34 ,  Y10S424/05 ,  Y10S514/937 ,  Y10S514/944

    摘要： A cosmetic composition for protection against ultraviolet radiation and its use for this purpose.The present invention relates to a cosmetic composition containing, as an agent for protecting against the UV rays at least one compound of the formula ##STR1## where Ar denotes an m- or p-phenylene or biphenylene radical capable of being substituted by one or more halogen atoms, one or more C.sub.1 -C.sub.6 lower alkyl or lower alkoxy groups,R denotes a hydrogen atom, an ester group --COOR.sub.1, an amide group --CONR.sub.1 R.sub.2 or a nitrile group;R' denotes an ester group --COOR.sub.1 or amide group --CONR.sub.1 R.sub.2 ; in addition when R denotes a hydrogen atom, R' can be an acid group --COOH or its salts,R.sub.1 being capable of being a linear, branched or cyclic, saturated or unsaturated carbon chain containing up to 18 carbon atoms, unsubstituted or substituted by one or more hydroxyl, alkoxy, amino or quaternary ammonium groups,R.sub.2 being capable of being a hydrogen atom or a C.sub.1 -C.sub.6 lower alkyl group, in a cosmetically acceptable medium.

    摘要翻译： 用于防止紫外线辐射的化妆品组合物及其用于此目的。 本发明涉及一种化妆品组合物，其含有作为防止UV射线的至少一种下式化合物的作用剂，其中Ar表示可被一个或多个取代基取代的间 - 或对亚苯基或亚联苯基 卤素原子，一个或多个C 1 -C 6低级烷基或低级烷氧基，R表示氢原子，酯基-COOR 1，酰胺基-CONR1R2或腈基; R'表示酯基-COOR1或酰胺基-CONR1R2; 另外当R表示氢原子时，R'可以是酸基-COOH或其盐，R1可以是含有至多18个碳原子的直链，支链或环状，饱和或不饱和的碳链，未被取代或被 一种或多种羟基，烷氧基，氨基或季铵基团，R 2可以是化学上可接受的介质中的氢原子或C 1 -C 6低级烷基。

    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays
    3.
    发明授权
    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays 失效
    3-亚苄基 - 樟脑，其制备方法及其在防紫外线中的应用

    公开(公告)号：US4654434A

    公开(公告)日：1987-03-31

    申请号：US825932

    申请日：1986-02-04

    申请人： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    发明人： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    IPC分类号： A61K8/35 ,  A61K8/46 ,  A61Q17/04 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86 ,  C07C309/25 ,  C07C69/76 ,  C07C143/52

    CPC分类号： A61K8/466 ,  A61K8/35 ,  A61Q17/04 ,  C07C255/00 ,  C07C309/00 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86

    摘要： The invention relates to new 3-benzylidene-camphor derivatives of the formula: ##STR1## in which R.sub.1 denotes H or SO.sub.3.sup..crclbar. M.sup..sym., with M=H, an alkali metal or N.sup..sym. (R.sub.3).sub.4, with R.sub.3 =H or C.sub.1 -C.sub.4 alkyl or hydroxyalkyl; R.sub.2 denotes C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and n=0-4; and Z denotes ##STR2## in which R.sub.4 has the same meaning as R.sub.1 and can be identical or different, or alternatively ##STR3## in which R.sub.5 denotes H, optionally substituted aryl, C.sub.1 -C.sub.4 alkyl, --CN, --C00R7 or ##STR4## and R.sub.6 denotes --COOR.sub.8 or ##STR5## in which R.sub.7 and R.sub.8, which are identical or different, denote alkyl, alkenyl, cycloalkyl or aralkyl and R.sub.9 and R.sub.10, which are identical or different, denote H, alkyl, alkenyl or cycloalkyl; if R.sub.5 =H, alkyl or aryl, R.sub.6 can represent --COO.sup..crclbar. M.sup..sym. ; the methylidene-camphor radical, on the one hand, and the radical Z, on the other hand, are in the meta or para position. These derivatives act as sun filters.

    摘要翻译： 本发明涉及下式的新的3-亚苄基 - 樟脑衍生物：其中R 1表示H或SO 3（ - ）M（+），其中M = H，碱金属或N（+）（ R3）4，其中R3 = H或C1-C4烷基或羟烷基; R2表示C1-C4烷基或C1-C4烷氧基，n = 0-4; 并且Z表示其中R 4具有与R 1相同的含义并且可以相同或不同，或者其中R 5表示H，任选取代的芳基，C 1 -C 4烷基，-CN，-COOR 7或

    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays
    4.
    发明授权
    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays 失效
    3-亚苄基 - 樟脑，其制备方法及其用于防止紫外线的用途

    公开(公告)号：US4663088A

    公开(公告)日：1987-05-05

    申请号：US825933

    申请日：1986-02-04

    申请人： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    发明人： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    IPC分类号： A61K8/35 ,  A61K8/46 ,  A61Q17/04 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86 ,  C07C309/03 ,  C07C309/25 ,  C07C143/52

    CPC分类号： A61K8/35 ,  A61K8/466 ,  A61Q17/04 ,  C07C255/00 ,  C07C309/00 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86

    摘要： The invention relates to new 3-benzylidene-camphor derivatives of the formula: ##STR1## in which R.sub.1 denotes H or SO.sub.3.sup..crclbar. M.sup..sym., with M=H, an alkali metal or N.sup..sym. (R.sub.3).sub.4, with R.sub.3 =H or C.sub.1 -C.sub.4 alkyl or hydroxyalkyl; R.sub.2 denotes C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and n=0-4; and Z denotes ##STR2## in which R.sub.4 has the same meaning as R.sub.1 and can be identical or different, or alternatively ##STR3## in which R.sub.5 denotes H, optionally substituted aryl, C.sub.1 -C.sub.4 alkyl, --CN, --COOR7 or ##STR4## and R.sub.6 denotes --COOR.sub.8 or ##STR5## in which R.sub.7 and R.sub.8, which are identical or different, denote alkyl, alkenyl, cycloalkyl or aralkyl and R.sub.9 and R.sub.10, which are identical or different, denote H, alkyl, alkenyl or cycloalkyl; if R.sub.5 =H, alkyl or aryl, R.sub.6 can represent --COO.sup..crclbar. M.sup..sym. ; the methylidene-camphor radical, on the one hand, and the radical Z, on the other hand, are in the meta or para position. These derivatives act as sun filters.

    摘要翻译： 本发明涉及下式的新的3-亚苄基 - 樟脑衍生物：其中R 1表示H或SO 3（ - ）M（+），其中M = H，碱金属或N（+）（ R3）4，其中R3 = H或C1-C4烷基或羟烷基; R2表示C1-C4烷基或C1-C4烷氧基，n = 0-4; 并且Z表示其中R 4具有与R 1相同的含义并且可以相同或不同，或者其中R 5表示H，任选取代的芳基，C 1 -C 4烷基，-CN，-COOR 7或

    Compositions for coloring the skin based on indole derivatives
    7.
    发明授权
    Compositions for coloring the skin based on indole derivatives 失效
    基于吲哚衍生物着色皮肤的组合物

    公开(公告)号：US4956174A

    公开(公告)日：1990-09-11

    申请号：US21931

    申请日：1987-03-05

    申请人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    发明人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/46 ,  A61K8/49 ,  A61K8/58 ,  A61K8/86 ,  A61K8/92 ,  A61Q1/02 ,  A61Q19/04

    CPC分类号： A61Q19/04 ,  A61K8/492

    摘要： Cosmetic composition designed to impart to the skin a coloring which is substantially similar to the pigmentation resulting from natural tanning, characterized in that it contains, in a cosmetically acceptable medium suitable for topical application, at least one compound of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom, a lower alkyl group or a residue --SiR.sub.9 R.sub.10 R.sub.11, R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ; R.sub.4 and R.sub.5 which may be identical or different, denote a hydrogen atom, a linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group R.sub.6 OSO.sub.2 --, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or an aralkyl group, or alternatively R.sub.4 and R.sub.5, with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group when at least one of the groups, R.sub.1, R.sub.2 or R.sub.3 is other than hydrogen or alternatively a thiocarbonyl group, a residue >P(O)OR.sub.6, a group >CR.sub.7 R.sub.8 or a methylene group, R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, R.sub.8 denoting a lower alkoxy group or a mono- or dialkylamino group and R.sub.9, R.sub.10 or R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 being other than hydrogen; and the corresponding salts with alkali metals, alkaline earth metals, ammonium or amines.

    摘要翻译： 化妆品组合物被设计成赋予皮肤一种基本上类似于由天然鞣制引起的色素沉着的着色，其特征在于其在适合局部应用的化妆品可接受的介质中包含至少一种下式的化合物： I），其中R 1表示氢原子，低级烷基或残基-SiR 9 R 10 R 11，R 2和R 3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或 一组-COOSiR9R10R11; 可以相同或不同的R 4和R 5表示氢原子，直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， 基团R6OSO2-，基团-SiR9R10R11，基团-P（O）（OR6）2或芳烷基，或者R4和R5与它们所连接的氧原子形成任选含有羰基的环， R 1，R 2或R 3中的至少一个不是氢或硫代羰基，残基> P（O）OR 6，基团> CR 7 R 8或亚甲基，R 6表示氢原子或低级烷基 ，R7表示氢原子或低级烷基，R8表示低级烷氧基或单或二烷基氨基，R9，R10或R11可以相同或不同，表示直链或支链的低级烷基，至少一个 的取代基R 1，R 2，R 3，R 4和R 5不是氢; 和与碱金属，碱土金属，铵或胺的相应的盐。

    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds
    10.
    发明授权
    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds 失效
    基于吲哚衍生物的角质纤维染色组合物和新化合物

    公开(公告)号：US4822375A

    公开(公告)日：1989-04-18

    申请号：US21932

    申请日：1987-03-05

    申请人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    发明人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/41 ,  A61K8/49 ,  A61K8/92 ,  A61Q5/10 ,  C07D209/08 ,  C07D209/12 ,  C07D209/42 ,  C07D491/04 ,  C07D491/056 ,  C07F7/18 ,  C07F9/572 ,  C09B53/00 ,  C09B53/02 ,  C09B57/00 ,  C09B69/00 ,  D06P3/08 ,  A61K7/13 ,  C07D209/30 ,  C07F9/12

    CPC分类号： C07D491/04 ,  A61K8/492 ,  A61Q5/10 ,  C07D209/08 ,  C07F7/1856 ,  C07F9/5728 ,  C09B69/007 ,  C09B69/008

    摘要： Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds.Dyeing composition for keratinous fibres, and especially human hair, characterized in that it contains, in a cosmetically acceptable medium suitable for dyeing these fibres, at least one dye corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a lower alkyl group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group -COOSiR.sub.9 - R.sub.10 R.sub.11 ; and R.sub.5, which may be identical or different, denote at least one linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, the other group R.sub.4 or R.sub.5 being able to be a hydrogen atom, R.sub.4 and R.sub.5 are not simultaneously acetyl, or alternatively R.sub.4 and R.sub.5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a thiocarbonyl group, a group>P(O)OR.sub.6 or>CR.sub.7 R.sub.8 ;R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, and R.sub.8 denotes a lower alkoxy group or a mono- or dialkylamino group, R.sub.9, R.sub.10 and R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, and the cosmetically acceptable salts of alkali metals, alkaline earth metal metals, ammonia or amines.

    摘要翻译： 基于吲哚衍生物的角质纤维染色组合物和新化合物。 用于角质纤维，特别是人类头发的染色组合物，其特征在于，其在适合于染色这些纤维的化妆品可接受的培养基中含有至少一种对应于下式的染料：其中R 1表示氢原子 或低级烷基或-SiR 9 R 10 R 11基团; R2和R3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或基团-COOSiR9-R10R11; 和R 5可以相同或不同，表示至少一个直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， SiR 9 R 10 R 11，基团-P（O）（OR 6）2或基团R 6 OSO 2 - ，另一基团R 4或R 5可以是氢原子，R 4和R 5不同时为乙酰基，或者R4和R5连同 形成任选地含有羰基，硫代羰基，基团> P（O）OR 6或> CR 7 R 8的环的氧原子。 R6表示氢原子或低级烷基，R7表示氢原子或低级烷基，R8表示低级烷氧基或一或二烷基氨基，R9，R10和R11可相同或不同， 表示直链或支链的低级烷基，以及碱金属，碱土金属金属，氨或胺的美容上可接受的盐。