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19 条记录 (耗时 0.019 秒)

    Polyhydroxy compounds containing urea groups and either ester or amide groups, process for their preparation, and the use thereof
    1.
    发明授权
    Polyhydroxy compounds containing urea groups and either ester or amide groups, process for their preparation, and the use thereof 失效
    含有脲基和酯或酰胺基的多羟基化合物，其制备方法及其用途

    公开(公告)号：US4704447A

    公开(公告)日：1987-11-03

    申请号：US824042

    申请日：1986-01-30

    申请人： Gerhard Balle ,  Gerhard Grogler ,  Walter Meckel

    发明人： Gerhard Balle ,  Gerhard Grogler ,  Walter Meckel

    IPC分类号： C07C275/16 ,  C07C275/40 ,  C07D223/10 ,  C08G18/38 ,  C08G18/34 ,  C08G18/00 ,  C08G18/32

    CPC分类号： C08G18/3829 ,  C07C275/16 ,  C07C275/40 ,  C07D223/10

    摘要： The compounds of the present invention are obtained by the reaction of carbamoyl lactams (from lactams and polyisocyanates) with polyhydric alcohols or monoamino alcohols in the presence of catalytic quantities of a strong basic catalyst, e.g. an alkali metal alcoholate, at elevated temperatures.The polyols contain urea groups and either ester or amide groups and correspond to formula (I) or (II) ##STR1## The polyols are crystalline, relatively high melting compounds which are used as reactants for the synthesis of polyurethane elastomers, in particular in the form of finely divided components in one-component polyurethane reaction mixtures.

    摘要翻译： 本发明的化合物是通过在催化量的强碱性催化剂，例如甲醇和丙醇的存在下，氨基甲酰基内酰胺（来自内酰胺和多异氰酸酯）与多元醇或单氨基醇的反应得到的。 碱金属醇化物，在升高的温度。 多元醇含有脲基团和酯基或酰胺基团，并且对应于式（I）或（II）。（II）多元醇是结晶的，较高熔点的化合物，其用作反应物 聚氨酯弹性体的合成，特别是在单组分聚氨酯反应混合物中以细碎组分的形式。

    Process for the production of polymer-containing aromatic polyether polyamines
    2.
    发明授权
    Process for the production of polymer-containing aromatic polyether polyamines 失效
    用于生产含聚合物的芳族聚醚多胺的方法

    公开(公告)号：US4506039A

    公开(公告)日：1985-03-19

    申请号：US450813

    申请日：1982-12-20

    申请人： Gerhard Balle ,  Werner Rasshofer ,  Winfried Schoberth

    发明人： Gerhard Balle ,  Werner Rasshofer ,  Winfried Schoberth

    IPC分类号： C08F283/00 ,  C08F283/06 ,  C08G18/00 ,  C08G18/10 ,  C08G18/63 ,  C08G18/14 ,  C08G67/02

    CPC分类号： C08G18/632 ,  C08F283/06 ,  C08G18/10

    摘要： Polymer-containing polyether polyamines containing terminal aromatically-bound amino groups are produced by in situ polymerization of a polyether polyamine with an olefinically unsaturated monomer. The polyether polyamine starting material must have terminal aromatic amino groups, a molecular weight of from 800 to 10,000 and an aromatic amino group content of from 0.3 to 16 wt. %. Suitable olefinically unsaturated monomers include .alpha.,.beta.-unsaturated nitriles, aromatic vinyl compounds, .alpha.,.beta.-unsaturated carboxylic acids and esters thereof, vinyl esters, vinyl halides, vinylidene halides, .alpha.,.beta.-unsaturated carboxylic acid amides and aminoalkyl esters of unsaturated carboxylic acids. Acrylonitrile/styrene mixtures are preferred monomers. The starting materials are employed in quantities such that the product modified polyether polyamine contains from 1 to 60 wt. % polymer or graft-polymer. The product polyamines are particularly useful in the production of polyurethanes.

    摘要翻译： 通过聚醚多胺与烯属不饱和单体的原位聚合制备含末端芳香结合氨基的含聚合物聚醚多胺。 聚醚多胺原料必须具有末端芳族氨基，分子量为800至10,000，芳族氨基含量为0.3至16重量％。 ％。 合适的烯属不饱和单体包括α，β-不饱和腈，芳族乙烯基化合物，α，β-不饱和羧酸及其酯，乙烯基酯，乙烯基卤化物，亚乙烯基卤化物，α，β-不饱和羧酸酰胺和不饱和羧酸的氨基烷基酯 酸。 丙烯腈/苯乙烯混合物是优选的单体。 原料的使用量使得产物改性的聚醚多胺含有1至60wt。 ％聚合物或接枝聚合物。 产物多胺在聚氨酯的生产中特别有用。

    Process for the production of optionally cellular moldings
    5.
    发明授权
    Process for the production of optionally cellular moldings 失效
    用于制备任选的细胞模制品的方法

    公开(公告)号：US4608214A

    公开(公告)日：1986-08-26

    申请号：US685187

    申请日：1984-12-21

    申请人： Gerhard Balle ,  Reiner Paul ,  Werner Rasshofer

    发明人： Gerhard Balle ,  Reiner Paul ,  Werner Rasshofer

    IPC分类号： B41J2/01 ,  C08G18/00 ,  C08G18/40 ,  C08G18/63 ,  C08J9/00 ,  C08K5/098 ,  C08L75/00 ,  C09D11/00 ,  C08J9/34 ,  C08G18/14 ,  C08J9/14

    CPC分类号： C08J9/0023 ,  C08G18/4072 ,  C08G18/63 ,  C08K5/098 ,  C08L75/00 ,  C08J2375/04 ,  Y10S264/83 ,  Y10T428/249989

    摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane and/or polyurethane-urea moldings having an impervious skin by reacting in a closed mold a reaction mixture containing(a) at least one organic polyisocyanate,(b) at least one compound which has a molecular weight of about 400 to 12,000 and at least two isocyanate-reactive groups, and(c) optionally at least one compound which has a molecular weight of from 32 to 399 and at least two isocyanate-reactive groups,wherein before the reaction takes place a surface-improving additive (e) is added containing(e1) a liquid and sedimentation-stable polymer dispersion which is produced by the free radical addition polymerization or copolymerization of one or more olefinically unsaturated monomers in a high molecular weight compound having isocyanate-reactive groups of the type mentioned in (b),and optionally(e2) a metal salt of a monocarboxylic acid having at least 8 carbon atoms in the moleculewherein additive (e) is used in a quantity such that about 0.01 to 3 parts by weight of polymer solids of the polymer dispersion (e1) and up to about 2 parts by weight of metal salt (e2) are incorporated per 100 parts of component (b).

    摘要翻译： 本发明涉及通过在封闭模具中反应含有（a）至少一种有机聚异氰酸酯的反应混合物，（b）在 至少一种分子量为约400至12,000和至少两个异氰酸酯反应性基团的化合物，和（c）任选至少一种分子量为32至399的化合物和至少两种异氰酸酯反应性基团， 其中在反应发生之前，添加表面改性添加剂（e），其含有（e1）液体和沉降稳定的聚合物分散体，其通过高分子量的一种或多种烯属不饱和单体的自由基加成聚合或共聚制备 （b）中提到的具有异氰酸酯反应性基团的重量化合物和任选的（e2）在摩尔中具有至少8个碳原子的一元羧酸的金属盐 其中添加剂（e）的使用量使得每100份聚合物分散体（e1）中加入约0.01至3重量份的聚合物分散体（e1）的聚合物固体和至多约2重量份的金属盐（e2） 组分（b）。

    Process for the production of aminoplast dispersions
    6.
    发明授权
    Process for the production of aminoplast dispersions 失效
    生产氨基塑料分散体的方法

    公开(公告)号：US4301262A

    公开(公告)日：1981-11-17

    申请号：US162843

    申请日：1980-06-25

    申请人： Kuno Wagner ,  Jurgen Ick ,  Gerhard Balle

    发明人： Kuno Wagner ,  Jurgen Ick ,  Gerhard Balle

    IPC分类号： C08G12/00 ,  C08G12/02 ,  C08G18/00 ,  C08G18/54 ,  C08G18/84 ,  C08L75/04 ,  C08F283/00

    CPC分类号： C08G18/84 ,  C08G12/02 ,  C08L75/04

    摘要： The instant invention is directed to a process for the production of dispersions of aminoplast condensates in organic polyhydroxyl compounds by the oligo-condensation or polycondensation of substances capable of aminoplast formation, in said organic polyhydroxyl compounds, the improvement wherein said dispersions are reacted at from about -5.degree. C. to about 180.degree. C. with an amine compound selected from the group consisting of:(a) organic aliphatic or cycloaliphatic mono or polyamines containing at least one primary or secondary amine group, and which are gaseous or liquid at room temperature, and(b) organic alkyl hydrazines containing at least one primary or secondary amine group and which are gaseous or liquid at room temperature.

    摘要翻译： 本发明涉及通过所述有机多羟基化合物中能够形成氨基塑料的物质的低聚缩聚或缩聚生产氨基塑料缩合物在有机多羟基化合物中的分散体的方法，其中所述分散体在约 -5℃至约180℃，其中胺化合物选自：（a）含有至少一个伯或仲胺基团的有机脂族或脂环族单或多胺，并且其在室内为气态或液体 温度和（b）含有至少一个伯或仲胺基团的有机烷基肼，并且在室温下为气态或液体。

    Compounds containing hydroxyl groups and urethano-aryl-sulfonic acid groups
    8.
    发明授权
    Compounds containing hydroxyl groups and urethano-aryl-sulfonic acid groups 失效
    含有羟基和氨基 - 芳基磺酸基团的化合物

    公开(公告)号：US4224418A

    公开(公告)日：1980-09-23

    申请号：US48921

    申请日：1979-06-15

    申请人： Dieter Dieterich ,  Gerhard Balle ,  Hans G. Schmelzer

    发明人： Dieter Dieterich ,  Gerhard Balle ,  Hans G. Schmelzer

    IPC分类号： C07C309/51 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C309/56 ,  C08G18/08 ,  C08G18/46 ,  C08G18/50 ,  C08G18/71 ,  C08G18/77 ,  C08L81/00

    CPC分类号： C08G18/5072 ,  C07C309/56 ,  C08G18/0828 ,  C08G18/4676 ,  C08G18/715 ,  C08G18/775

    摘要： The instant invention is directed to compounds having an average molecular weight of from 300 to 12,000, containing: at least one hydroxyl group and at least one urethano-aryl-sulfonic acid group and a method for their preparation. The process is characterized as a process for the preparation of compounds having a number average molecular weight of from 300 to 12,000 having at least one hydroxyl group and at least one urethano-aryl-sulfonic acid group, comprising: reacting at from 0.degree. to 190.degree. C.(A) compounds having a molecular weight of from 62 to 10,000 having at least two hydroxyl groups; with(B) aromatic isocyanato sulfonic acids, wherein the equivalent ratio of the total quantity of isocyanate groups (including any isocyanate groups present in dimerized form) to sulfonic acid groups is from 0.5:1 to 50:1 and the equivalent ratio of the sum of hydroxyl groups in (A) to NCO groups is from 1.5:1 to 30:1. The invention is also directed to the product by the process.

    摘要翻译： 本发明涉及平均分子量为300至12,000的化合物，其含有至少一个羟基和至少一个氨基 - 芳基磺酸基团及其制备方法。 该方法的特征在于制备具有至少一个羟基和至少一个氨基 - 芳基磺酸基团的数均分子量为300至12,000的化合物的方法，其包括：在0°至190°的反应 （A）具有至少两个羟基的分子量为62至10,000的化合物; 与（B）芳族异氰酸根合磺酸，其中异氰酸酯基团（包括以二聚形式存在的任何异氰酸酯基团）与磺酸基团的总量的当量比为0.5:1至50:1，并且总和的当量比 （A）至NCO基团中的羟基的摩尔比为1.5：1至30：1。 本发明还涉及该方法的产品。

    High-impact polymer alloys
    10.
    发明授权
    High-impact polymer alloys 失效
    高抗冲聚合物合金

    公开(公告)号：US4507444A

    公开(公告)日：1985-03-26

    申请号：US295177

    申请日：1981-08-21

    申请人： Wilhelm Slawyk ,  Gerhard Balle ,  Manfred Munzer ,  Adolf Wohnhas, deceased

    发明人： Wilhelm Slawyk ,  Gerhard Balle ,  Manfred Munzer ,  Adolf Wohnhas, deceased

    IPC分类号： C08F283/00 ,  C08F290/06 ,  C08G18/63 ,  C08G18/67 ,  C08F283/04

    CPC分类号： C08G18/672 ,  C08F283/006 ,  C08F283/008 ,  C08F290/067 ,  C08G18/637 ,  C08G2270/00

    摘要： A process of making radically polymerizable compositions suitable for the production of impact resistant optically clear glass like plastic and forming the glass from such compositions is disclosed. Also taught are the polymerizable compositions and the final glass produced. An isocyanate terminated prepolymer based upon a polyol selected from polyesters, polyester amides, polycarbonates and polyacetals and diisocyanates selected from branched aliphatic isocyanates, cycloaliphatic isocyanates and aliphatic or cycloaliphatic isocyanates graft polymerized with vinyl monomers is chain extended with aliphatic or cyloaliphatic diamines while in solution in vinyl monomers consisting mainly of methacrylic acid esters. The chain extension is carried out with a deficit of amine and preferably to a viscosity at 20% solids in the vinyl monomers of between 200 and 30,000 cP at 20.degree. C. The composition is then radically polymerized to form the high impact glass like plastic alloy.

    摘要翻译： 公开了一种制备适合于生产耐冲击光学透明玻璃如塑料并由这种组合物形成玻璃的自由基聚合性组合物的方法。 还教导了可聚合组合物和所生产的最终玻璃。 基于选自聚酯，聚酯酰胺，聚碳酸酯和聚缩醛的多元醇的异氰酸酯封端的预聚物和选自支链脂族异氰酸酯，脂环族异氰酸酯和与乙烯基单体接枝聚合的脂族或脂环族异氰酸酯的二异氰酸酯在脂肪族或脂环族二胺的同时， 主要由甲基丙烯酸酯组成的乙烯基单体。 链延伸是在胺缺乏的情况下进行的，优选在20℃下在乙烯基单体中的20％固体的粘度为200至30,000cP。然后将组合物自由基聚合以形成高冲击玻璃如塑料合金 。