摘要:
A process for the addition of Si-bonded hydrogen to an aliphatic multiple bond in the presence of a platinum catalyst selected from the group consisting of______________________________________ I XPtY, II ##STR1## III APt(Y')X"and ______________________________________ mixtures thereof, in which A is a halogen, X is a substituted or unsubstituted hydrocarbon radical having from 1 to 3 aliphatic double bonds which is bonded to the platinum atom via a PtC-sigma bond and a Pt-olefin-Pi-bond, X' is a hydrocarbon radical which is substituted with an alkoxy or acyloxy group and has from 1 to 3 double bonds and is bonded to the platinum atom via a PtC-sigma bond and a Pt-olefin-Pi-bond, X" is a substituted or unsubstituted hydrocarbon having an aliphatic double bond which is bonded to the platinum atom via a Pt-olefin-Pi-bond, Y is a chelate-like bonded beta-diketonate ligand or arylcarboxylate ligand, Y' is a beta-diketonate ligand and Z is a double link bridge ligand.
摘要:
This invention relates to organosiloxanes which have SiC-bonded ester groups and contain at least one unit of the general formula: ##EQU1## is which R represents the same or different monovalent hydrocarbon radicals having from 1 to 12 carbons atoms, which are free of aliphatic unsaturation and which may contain one ether oxygen atom; R' represents hydrogen or a methyl group (CH.sub.3) and a is O, 1 or 2. These organosiloxanes can be prepared by hydrolyzing or co-hydrolyzing silanes of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a X.sub.3-a'where R, R' and a are the same as above and X represents the same or different hydrolyzable atoms or groups. Also, they may be prepared by the addition of a diester of allyl succinic acid and/or methallyl succinic acid to an organosiloxane containing Si-bonded hydrogen. These new organosiloxanes may be used as lubricants for inorganic and organic fibers, metal surfaces and as hydraulic fluids.
摘要:
This invention relates to organosiloxanes which have SiC-bonded ester groups and contain at least one unit of the general formula: ##EQU1## in which R represents the same or different monovalent hydrocarbon radicals having from 1 to 12 carbon atoms, which are free of aliphatic unsaturation and which may contain one ether oxygen atom; R' represents hydrogen or a methyl group (CH.sub.3) and a is 0, 1 or 2. These organosiloxanes can be prepared by hydrolyzing or co-hydrolyzing silanes of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a X.sub.3-a,where R, R' and a are the same as above and X represents the same or different hydrolyzable atoms or groups. Also, they may be prepared by the addition of a diester of allyl succinic acid and/or methallyl succinic acid to an organosiloxane containing Si-bonded hydrogen. These new organosiloxanes may be used as lubricants for inorganic and organic fibers, metal surfaces and as hydraulic fluids.
摘要:
This invention relates to organosiloxanes which have SiC-bonded ester groups and contain at least one unit of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a O.sub.3-a/2in which R represents the same or different monovalent hydrocarbon radicals having from 1 to 12 carbon atoms, which are free of aliphatic unsaturation and which may contain one ether oxygen atom; R' represents hydrogen or a methyl group (CH.sub.3) and a is 0, 1 or 2. These organosiloxanes can be prepared by hydrolyzing or co-hydrolyzing silanes of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a X.sub.3-a,where R, R' and a are the same as above and X represents the same or different hydrolyzable atoms or groups. Also, they may be prepared by the addition of a diester of allyl succinic acid and/or methallyl succinic acid to an organosiloxane containing Si-bonded hydrogen. These new organosiloxanes may be used as lubricants for inorganic and organic fibers, metal surfaces and as hydraulic fluids.
摘要翻译:本发明涉及具有SiC键合的酯基并且含有至少一个通式为:ROOCCH 2 CH(COOR)CH 2 CHR'CH 2 Si(CH 3)a O 3-a / 2的单元的有机硅氧烷,其中R表示相同或不同的具有 1至12个碳原子,其不含脂族不饱和基团并且可以含有一个醚氧原子; R'表示氢或甲基(CH 3),a是0,1或2.这些有机硅氧烷可以通过水解或共水解通式如下的硅烷来制备:ROOCCH2CH(COOR)CH2CHR'CH2Si(CH3)aX3-a 其中R,R'和a与上述相同,X表示相同或不同的可水解原子或基团。 此外,它们可以通过将烯丙基琥珀酸和/或甲代烯丙基琥珀酸的二酯加入到含有Si键合氢的有机硅氧烷中来制备。 这些新的有机硅氧烷可用作无机和有机纤维,金属表面和液压油的润滑剂。
摘要:
An improved method for preparing modified organopolysiloxanes which comprises graft polymerizing monomers containing aliphatic unsaturation onto organopolysiloxanes in the presence of a free radical and an inert liquid having a boiling point up to about 100.degree. C. at 760 mm Hg (abs.) and which is a nonsolvent for the organopolysiloxanes and the graft polymers at the applicable polymerization temperatures.
摘要:
The invention relates to a data carrier having memory locations to which data is written, wherein the memory locations have a number of first memory locations with erroneous data and at least one second memory location for the arrangement of analytical substances on the data carrier, wherein, when the analytical substances react with a medium that is to be investigated, the reaction product may cause a change to the data item which is written to the at least one second memory location, and the number of first memory locations is designed such that, on the one hand, when there is no reaction between the analytical substances and a medium which is to be investigated, a first data record can be determined when reading the data carrier and using a conventional error correction method, and, on the other hand, when the reaction product has caused a change to the data item which is written to the at least one second memory location, a second data record can be determined when reading the data carrier and using the conventional error correction method, with the second data record not being the same as the first data record.
摘要:
The invention relates to a method for detecting and/or quantifying analytes from a sample on an analysis carrier that has been formatted using a digital data code. Detection fields comprising the sensor elements required for the respective detection process, together with additional data structures in a defined digital format, are provided on the analysis carrier and combined to form sequcnces of formatted structures that can be interpreted as code words. To detect and quantify an analyte in a sample, the latter is applied to the analysis carrier and the formation of signal-generating elements is initiated at locations of molecular interaction. The localisation of signal-generating elements in the respective detection fields causes a formatted structure at this location to be replaced by another. This leads to the conversion of one code word into another within the predetermined quantity of valid code words. Both code words can be sequentially read and interpreted in the predetermined format. The statement concerning a successful or unsuccessful reaction is based on a comparison of the respective code words prior to and after detection. Detection takes place using a reading device, which is preferably constructed from components of the consumer goods industry.
摘要:
An improved process for preparing methylchlorosilanes which comprises reacting tetramethylsilane and hydrogen chloride in the gaseous state with a solid Friedel-Crafts catalyst.
摘要:
2,4,4-Trichlorobutadienyl-1-phosphate and 1-phosphonates are novel compounds, and are effective against organisms such as insects, acarides, and nematodes, and are suitable for application to plants.