摘要:
Crosslinkable fluorine-containing copolymers comprising copolymerized units of(a) a vinyl ester of a heavily branched carboxylic acid,(b) a vinyl ester of a short-chain carboxylic acid and(c) of a fluoroolefin, the vinyl ester groups of component (b) having been converted into OH groups by solvolysis of the copolymer. The copolymers are suitable for coating purposes of any type, in particular as binders in surface-coating systems for industrial surface-coatings.
摘要:
The invention relates to solutions of fluoropolymers which preferably contain carbonate groups, in solvents of the general formula (I) ##STR1## These solutions are suitable, in particular, for the production of membranes for liquid permeation processes, such as electrolysis.
摘要:
The present invention provides an aqueous fluoropolymer dispersion comprising a melt processible fluoropolymer in an amount of at least 25% by weight based on the weight of the aqueous fluoropolymer dispersion and a fluorinated surfactant having a molecular weight of not more than 1000 g/mol in an amount of not more than 100 ppm, preferably less than 50 ppm, more preferably less than 25 ppm and most preferably less than 10 ppm based on the weight of fluoropolymer solids or being free of said fluorinated surfactant. The aqueous fluoropolymer dispersion has a conductivity of at least 200 μS/cm, preferably at least 500 μS/cm and more preferably at least 1000 μS/cm.
摘要:
Fluorine-containing emulsifiers can be removed from fluoropolymer dispersions by adding to the dispersion a non ionic emulsifier, removing the fluorine-containing emulsifier by contact with an anion exchanger and separating the dispersion from the anion exchanger. The resulting dispersions can be concentrated and used for coating applications.
摘要:
In the suspension polymerization of tetrafluoroethylene a mixture of tetrafluoroethylene and an inert gas is charged under pressure before starting the polymerization, the total pressure being 5 to 50 bar and the concentration of tetrafluoroethylene in this mixture being 30 to 70 mol %. Said concentration is kept within this range by an appropriate feed of tetrafluoroethylene during the polymerization. The granular PTFE powder obtained is distinguished by an improved grain structure and grindability.
摘要:
Solutions of copolymers of the tetrafluoroethylene/ethylene typeCopolymer solutions comprising tetrafluoroethylene, ethylene and, as appropriate, further .alpha.-olefinic monomers in low-molecular-weight polymers of chlorotrifluoroethylene are described. They can be used for coatings, impregnations, cast films and for the production of fibers and filaments by gel spinning.
摘要:
The present invention provides a process of reducing the amount of fluorinated emulsifier in an aqueous fluoropolymer dispersion by contacting the aqueous fluoropolymer dispersion with an anion exchange resin in a non-fixed resin bed, the process comprising: (a) mixing the aqueous fluoropolymer dispersion with an effective amount of a surfactant so as to stabilize the fluoropolymer dispersion while being contacted with the anion exchange resin; (b) contacting the aqueous fluoropolymer dispersion with an anion exchange resin by agitating the aqueous fluoropolymer dispersion with an effective amount of anion exchange resin for a time of less than 4 hours to reduce the amount of fluorinated emulsifier in the aqueous fluoropolymer dispersion to a desired level; and (c) separating the anion exchange resin from the aqueous fluoropolymer dispersion.
摘要:
Polymerizing tetrafluoroethylene with modifying amounts of a perfluoro(alkyl vinyl ether) at temperatures below 60.degree. C. using permanganate or similar initiators by the suspension process and milling the raw polymer to an average particle size of from 10 to 50 .mu.m gives molding powders which are suitable for the preform free-sintering technique.
摘要:
Fluorinated carboxylic acids which do not have the required purity for use as emulsifier in the polymerization of fluorinated monomers can, if necessary after prior de-watering, be treated with oxidants, whereupon the isolation of the pure product is carried out by crystallisation or, preferably, by distillation.