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    Catalyst for vinyl compound polymerization and process for producing vinyl polymer
    2.
    发明授权
    Catalyst for vinyl compound polymerization and process for producing vinyl polymer 失效
    用于乙烯基化合物聚合的催化剂和用于生产乙烯基聚合物的方法

    公开(公告)号：US07176266B2

    公开(公告)日：2007-02-13

    申请号：US10889117

    申请日：2004-07-13

    申请人： Haruhito Sato ,  Masami Watanabe ,  Masahiko Kuramoto

    发明人： Haruhito Sato ,  Masami Watanabe ,  Masahiko Kuramoto

    IPC分类号： C08F4/42

    CPC分类号： C07C2/32 ,  C07C2/04 ,  C07C2521/16 ,  C07C2531/14 ,  C07C2531/16 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/7042 ,  C08F4/7006

    摘要： A catalyst for polymerizing vinyl compounds or α-olefins according to the present invention includes (A) a transition metal complex, (B) a clay, clay mineral or ion-exchangeable layered compound, modified with at least one organic compound selected from the group consisting of quaternary ammonium salts, amine compounds, and adducts of amine and Brönsted acid, and (C) at least one aluminoxy compound. The transition metal in (A) is selected from Groups 4 to 10 or Groups 8 to 10 of the Periodic Table for catalysts for vinyl compounds or α-olefins, respectively. The aluminoxy compound is represented by the general Formula wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and z is an integer of 2 or more for catalyst for vinyl compounds and 2 to 4 for catalysts for α-olefins.

    摘要翻译： 根据本发明的用于聚合乙烯基化合物或α-烯烃的催化剂包括（A）过渡金属络合物，（B）粘土，粘土矿物或可离子交换的层状化合物，其被至少一种选自以下的有机化合物 由季铵盐，胺化合物和胺和布朗斯台德酸的加合物组成，和（C）至少一种铝氧化合物。 （A）中的过渡金属分别选自元素周期表第4至10族或第8至10族，用于乙烯基化合物或α-烯烃的催化剂。 铝氧化合物由通式表示，其中多个R基团各自独立地为C 1-10烃基，并且R基团中的至少一个为具有2个或更多个碳原子的烃基; 乙烯基化合物催化剂的z为2以上，α-烯烃用催化剂为2〜4。

    Catalyst for vinyl compound polymerization and process for producing vinyl polymer
    3.
    发明授权
    Catalyst for vinyl compound polymerization and process for producing vinyl polymer 失效
    用于乙烯基化合物聚合的催化剂和用于生产乙烯基聚合物的方法

    公开(公告)号：US06835788B2

    公开(公告)日：2004-12-28

    申请号：US10204262

    申请日：2002-08-20

    申请人： Haruhito Sato ,  Masami Watanabe ,  Masahiko Kuramoto

    发明人： Haruhito Sato ,  Masami Watanabe ,  Masahiko Kuramoto

    IPC分类号： C08F442

    CPC分类号： C07C2/32 ,  C07C2/04 ,  C07C2521/16 ,  C07C2531/14 ,  C07C2531/16 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/7042 ,  C08F4/7006

    摘要： The catalyst for polymerizing vinyl compounds according to the present invention comprises (A) a complex of Group 4 to 10 transition metal of the Periodic Table, (B) a clay, clay mineral or ion-exchangeable layered compound, and (C) at least one aluminoxy compound represented by Formula (1): wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and x is an integer of 2 or more. By using the Group 4 to 10 transition metal complex and the clay, clay mineral or ion-exchangeable layered compound in combination with the specific aluminoxy compound, vinyl polymers are produced at a high efficiency. Also, the catalyst for producing &agr;-olefins according to the present invention comprises (A′) a complex of Group 8 to 10 transition metal of the Periodic Table, (B′) an organic compound-modified clay, clay mineral or ion-exchangeable layered compound, and (C′) at least one aluminoxy compound represented by Formula (2): wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and y is an integer of 2 to 4. Since the organic compound-modified clay, clay mineral or ion-exchangeable layered compound absorbs other catalyst components between layers thereof, the elution of the catalyst components into liquid phase is effectively prevented, thereby facilitating the separation of the catalyst from a reaction product.

    摘要翻译： 根据本发明的用于聚合乙烯基化合物的催化剂包含（A）元素周期表第4至10族过渡金属的络合物，（B）粘土，粘土矿物或可离子交换层状化合物，和（C）至少 一种由式（1）表示的铝氧化合物：其中多个R基团各自独立地为C 1-10烃基，并且至少一个R基团为具有2个或更多个碳原子的烃基; x为2以上的整数。 通过使用4至10族过渡金属络合物和粘土，粘土矿物或可离子交换的层状化合物与特定的铝氧化合物的组合，以高效率生产乙烯基聚合物。 此外，根据本发明的用于制备α-烯烃的催化剂包含（A'）元素周期表第8-10族过渡金属的络合物，（B'）有机化合物改性的粘土，粘土矿物或可离子交换的 层状化合物和（C'）至少一种由式（2）表示的铝氧化合物：其中多个R基团各自独立地为C1-10烃基，并且至少一个R基团为具有2个或更多个的烃基 碳原子 y为2〜4的整数。由于有机化合物改性粘土，粘土矿物或离子交换性层状化合物在其层之间吸收其他催化剂成分，因此有效地防止了催化剂成分向液相的溶出， 催化剂与反应产物的分离。

    Transition metal compound, olefin polymerization catalyst, and method of polymerizing olefin
    4.
    发明授权
    Transition metal compound, olefin polymerization catalyst, and method of polymerizing olefin 失效
    过渡金属化合物，烯烃聚合催化剂和烯烃聚合方法

    公开(公告)号：US06841693B1

    公开(公告)日：2005-01-11

    申请号：US10111419

    申请日：2000-11-10

    申请人： Masami Watanabe ,  Haruhito Sato ,  Masahiko Kuramoto ,  Shinji Tanaka ,  Takao Tamura

    发明人： Masami Watanabe ,  Haruhito Sato ,  Masahiko Kuramoto ,  Shinji Tanaka ,  Takao Tamura

    IPC分类号： C07D213/53 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C08F4/20 ,  C08F4/70 ,  C08F10/00 ,  C08F110/02 ,  C07F15/00 ,  B01J31/00

    CPC分类号： C07D213/53 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C08F4/7042 ,  C08F4/7006

    摘要： A transition metal compound of Groups to 10 of the Periodic Table, represented by the following formula (1): wherein M represents a transition metal of Groups 8 to 10 of the Periodic Table; L, electrically neutral, represents a hetero atom-containing hydrocarbon group represented by the following formula (2) wherein R1 to R5 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having form 1 to 20 carbon atoms, a halogenohydrocarbon group having from 1 to 20 carbon atoms, or a hetero atom-containing group, and optionally these groups are bonded to each other to form a ring; R6 represents a hydrogen atom, a hydrocarbon group having form 1 to 40 carbon atoms, a halogenohydrocarbon group having from 1 to 40 carton atoms, or a hetero atom-containing group; L′ electrically neutral, represents a hetero atom-containing hydrocarbon group represented by the following formula (3) wherein R7 to R11 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having from 1 to 20 carbon atoms, a halogenohydrocarbon group having from 1 to 20 carbon atoms, or a hetero atom-containing group, and optionally these groups are bonded to each other to form a ring; X represents a covalent-bonding or ionic-bonding group, and a plurality of X's are the same or different; Y represents an aromatic group-containing crosslinking group; Z is an integer of 1 or more, indicating the degree of polymerization of the compound; n indicates the atomic valency of M; and each of M, L, and Y are the same or different.

    摘要翻译： 由下式（1）表示的元素周期表中的10至10元的过渡金属化合物：其中M表示周期表第8至10族的过渡金属; L，电中性表示由下式（2）表示的含杂原子的烃基，其中R 1〜R 5各自独立地表示氢原子，卤素原子，1〜20的烃基 碳原子，具有1-20个碳原子的卤代烃基或含杂原子的基团，并且任选地这些基团彼此键合形成环; R 6表示氢原子，碳原子数1〜40的烃基，碳原子数为1〜40的卤代烃基或含杂原子的基团; L'电中性表示含杂原子的 由下式（3）表示的烃基，其中R 7至R 11各自独立地表示氢原子，卤素原子，具有1至20个碳原子的烃基，具有1至20个碳原子的卤代烃基 碳原子或含杂原子的基团，并且任选地，这些基团彼此键合形成环; X表示共价键或离子键合基团，并且多个X相同或不同; Y表示含芳基的交联基团; Z为1以上的整数，表示化合物的聚合度; n表示M的原子价; M，L，Y各自相同或不同。

    Catalyst for olefin polymerization and process for producing olefin polymer with the catalyst
    6.
    发明授权
    Catalyst for olefin polymerization and process for producing olefin polymer with the catalyst 失效
    用于烯烃聚合的催化剂和用催化剂生产烯烃聚合物的方法

    公开(公告)号：US06630551B1

    公开(公告)日：2003-10-07

    申请号：US09600164

    申请日：2000-08-02

    申请人： Fumio Okuda ,  Haruhito Sato ,  Masahiko Kuramoto

    发明人： Fumio Okuda ,  Haruhito Sato ,  Masahiko Kuramoto

    IPC分类号： C08F442

    CPC分类号： C08F10/00 ,  C08F4/7042

    摘要： A catalyst which comprises a compound of a transition metal in Groups 8 to 10 of the Periodic Table having a nitrogenous tridentate ligand, a clay, clay minteral, or lamellar ion-exchanging compound, an organosilane compound, and organoaluminum compound, etc.; and a process for producing a polyolefin with the catalyst. The catalyst is highly active, does not adhere to reactor walls, and can give a polyolefin excellent in powder morphology. Consequently, a polyolefin (especially polyethylene) can be industrially advantageously produced.

    摘要翻译： 包含周期表第8-10族的过渡金属化合物的催化剂，其具有含氮三齿配体，粘土，粘土矿物或层状离子交换化合物，有机硅烷化合物和有机铝化合物等; 以及用该催化剂生产聚烯烃的方法。 该催化剂具有高活性，不附着在反应器壁上，并且可以得到具有优异粉末形态的聚烯烃。 因此，聚烯烃（特别是聚乙烯）可以在工业上有利地生产。

    Catalysts for olefin polymer production
    7.
    发明授权
    Catalysts for olefin polymer production 失效
    用于烯烃聚合物生产的催化剂

    公开(公告)号：US06395846B1

    公开(公告)日：2002-05-28

    申请号：US09509569

    申请日：2000-04-18

    申请人： Haruhito Sato ,  Masahiko Kuramoto

    发明人： Haruhito Sato ,  Masahiko Kuramoto

    IPC分类号： C08F402

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/02 ,  C08F110/06 ,  C08F4/027 ,  C08F4/025 ,  C08F4/65916 ,  C08F4/7042 ,  C08F4/7006

    摘要： The invention relates to high-activity catalysts for olefin polymerization, to efficient methods for producing them, and to efficient methods of using the catalysts for producing high-quality polyolefins. The olefin polymerization with the catalysts does not require a large amount of an organic aluminium compound, and the residual metal in the polyolefins produced is much reduced. The catalysts are characterized by containing a product as prepared by contacting any of clay, a clay mineral and an ion-exchanging layered compound, an organic silane compound, and water with each other, or by containing a silane compound-processed clay.

    摘要翻译： 本发明涉及用于烯烃聚合的高活性催化剂，其有效的制备方法以及使用该催化剂生产高品质聚烯烃的有效方法。 与催化剂的烯烃聚合不需要大量的有机铝化合物，并且所生产的聚烯烃中的残余金属大大降低。 催化剂的特征在于含有通过使任何粘土，粘土矿物和离子交换层状化合物，有机硅烷化合物和水彼此接触或通过含有硅烷化合物处理的粘土而制备的产物。

    Process for purification of styrene polymer
    10.
    发明授权
    Process for purification of styrene polymer 失效
    苯乙烯聚合物的纯化方法

    公开(公告)号：US5321122A

    公开(公告)日：1994-06-14

    申请号：US964560

    申请日：1992-10-21

    申请人： Masahiko Kuramoto ,  Hideo Teshima

    发明人： Masahiko Kuramoto ,  Hideo Teshima

    IPC分类号： C08F6/02 ,  C08F6/08

    CPC分类号： C08F6/02 ,  Y10S526/943

    摘要： There is disclosed a process for purification of a styrene polymer, for purifying a styrene polymer having a high degree of syndiotacticity obtained by using a catalyst comprising (A) aluminoxane and (B) a transition metal compound containing no halogen, deashing the above styrene polymer with an alcoholic alkaline solution and then washing with an alcohol. Also disclosed is a process for purification of a styrene polymer which comprises deashing the above styrene polymer having been produced with a conversion rate of 60% or more after swelling it by adding an aromatic solvent and/or a styrene monomer.According to the process of the present invention, a high purity styrene polymer can be obtained with good efficiency.

    摘要翻译： 公开了一种纯化苯乙烯聚合物的方法，用于纯化通过使用包含（A）铝氧烷和（B）不含卤素的过渡金属化合物的催化剂获得的具有高程度的间同立构规整度的苯乙烯聚合物，将上述苯乙烯聚合物 用酒精碱溶液，然后用酒精洗涤。 还公开了一种用于纯化苯乙烯聚合物的方法，其包括通过加入芳族溶剂和/或苯乙烯单体使其膨胀之后以60％或更高的转化率除去上述苯乙烯聚合物。 根据本发明的方法，可以以高效率获得高纯度苯乙烯聚合物。