公开(公告)号：US20080051457A1

公开(公告)日：2008-02-28

申请号：US11660695

申请日：2005-08-22

申请人： Hayami Nakao ,  Yoshihiro Matsuzaki ,  Shinsuke Fujioka ,  Masayuki Morimoto ,  Masanori Tohnishi ,  Rudiger Fischer ,  Christian Funke ,  Olga Malsam ,  Christian Arnold ,  Erich Sanwald ,  Waltraud Hempel ,  Udo Reckmann

发明人： Hayami Nakao ,  Yoshihiro Matsuzaki ,  Shinsuke Fujioka ,  Masayuki Morimoto ,  Masanori Tohnishi ,  Rudiger Fischer ,  Christian Funke ,  Olga Malsam ,  Christian Arnold ,  Erich Sanwald ,  Waltraud Hempel ,  Udo Reckmann

IPC分类号： A01N37/44 ,  A01P7/04 ,  C07C233/64

CPC分类号： C07C317/28 ,  A01N37/30 ,  A01N41/10 ,  A01N43/40 ,  A01N43/54 ,  C07C217/90 ,  C07C271/28 ,  C07D213/64 ,  C07D213/70 ,  C07D213/75 ,  C07D239/42

摘要： The present invention relates to an optically active phthalamide derivative represented by the following formula (I): (wherein each of R1 and R2 represents H, optionally substituted C1-C6 alkyl, or C1-C6 alkoxycarbonyl; R3 represents C1-C6 alkyl; A represents H, C1-C6 alkyl, C3-C6 alkenyl, C3-C6 alkynyl, optionally substituted phenoxy C1-C6 alkyl, or the like; p represents 0, 1, 2, 3, or 4; q represents 0, 1, or 2; X represents halogen, CN, NH2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 alkylthio, or the like; m represents 0, 1, 2, 3, or 4; Y represents halogen, CN, NH2, C1-C6 alkyl, optionally substituted phenyl, or the like; n represents 1, 2, 3, 4, or 5; and each of Z1 and Z2 represents C—Y or N; and further X and Y may form a condensed ring together with carbon atoms adjacent thereto on a phenyl ring), a salt thereof, an agrohorticultural insecticide comprising the above derivative as an active ingredient, and a method of use thereof. The optically active phthalamide derivative of the present invention has superior control activity as an agrohorticultural insecticide, and has excellent effects even when the insecticide is used in admixture with other insecticides.

摘要翻译： 本发明涉及由下式（I）表示的光学活性邻苯二甲酰胺衍生物：其中R 1和R 2各自表示H，任选取代的C 1 -C 6 烷基或C 1 -C 6烷氧基羰基; R 3表示C 1 -C 6烷基; A表示H，C 1 -C 6烷基，C 3 -C 6烯基，C 3 -C 6炔基，任选取代的苯氧基C 1 -C 6烷基， 等等; p表示0,1,2,3或4; q表示0,1或2; X表示卤素，CN，NH 2，C 1 -C 6烷基，C 2 -C 6 烯基，C 1 -C 6烷硫基等; m表示0,1,2,3或4; Y表示卤素，CN，NH 2，C 1 -C 6烷基，任选取代的苯基或 类似物; n表示1,2,3,4或5; Z 1和Z 2各自表示CY或N;并且另外X和Y可以形成 与苯环上邻接的碳原子一起形成的稠合环），其盐，包含上述衍生物作为有效成分的农业园艺杀虫剂，以及am 使用方法。 本发明的光学活性酞酰胺衍生物作为农业用杀虫剂具有优异的控制活性，即使将杀虫剂与其他杀虫剂混合使用也具有优异的效果。

公开(公告)号：US20090118375A1

公开(公告)日：2009-05-07

申请号：US11661091

申请日：2005-08-20

申请人： Rudiger Fischer ,  Christian Funke ,  Olga Malsam ,  Peter Losel ,  Ulrich Gorgens ,  Christian Arnold ,  Masanori Tohnischi ,  Minoru Yamaguchi ,  Hiroto Harayama ,  Shinsuke Fujioka

发明人： Rudiger Fischer ,  Christian Funke ,  Olga Malsam ,  Peter Losel ,  Ulrich Gorgens ,  Christian Arnold ,  Masanori Tohnischi ,  Minoru Yamaguchi ,  Hiroto Harayama ,  Shinsuke Fujioka

IPC分类号： A01N37/18 ,  C07C321/20 ,  A01P7/00 ,  C07C209/74 ,  C07C211/52

CPC分类号： C07C211/52 ,  A01N37/30 ,  A01N41/10 ,  C07C317/28 ,  C07C323/42

摘要： Novel optically active phthalamides of the formula (I) in which A, q, R1, R2, E1, E2, X, m, Y, n and Z are as defined in the description, processes for preparing these compounds and their use for controlling pests.

摘要翻译： 其中A，q，R 1，R 2，E 1，E 2，X，m，Y，n和Z如说明书中所定义的式（I）的新型光学活性邻苯二甲酰胺，用于制备这些化合物及其用于控制 害虫

公开(公告)号：US07161032B2

公开(公告)日：2007-01-09

申请号：US10525504

申请日：2003-08-26

申请人： Minoru Yamaguchi ,  Hayami Nakao ,  Makoto Goto ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

发明人： Minoru Yamaguchi ,  Hayami Nakao ,  Makoto Goto ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

IPC分类号： C07C303/00 ,  A01N25/26 ,  A01N25/34 ,  C05G3/00

CPC分类号： C07D213/75 ,  A01N41/06 ,  A01N43/40 ,  A01N47/02 ,  C07C311/32 ,  C07C311/48 ,  C07C317/28 ,  C07C323/49 ,  C07D279/12

摘要： Sulfonamide derivatives represented by general formula (I) or salts thereof; insecticides for agricultural and horticultural use containing the same as the active ingredient; and usage thereof: [wherein A is optionally substituted (C1–C6)alkylene, (C3–C6)alkenylene or the like; R1 is H, optionally substituted (C1–C6)alkyl, (C3–C6)alkenyl, (C3–C6)cycloalkyl or the like; R2, R3 and R4 are each H, (C1–C6)alkyl, (C3–C6)alkenyl or the like, or R2 and A or R2 and R1 may form a 3- to 8-membered ring which may be interrupted by one to three atoms selected from among O, S and N; Q is C or N; X and Y are each halogen, CN, NO2, (C1–C6)alkyl, (C2–C6)alkenyl or the like; m is 0 to 2; n is 0 to 3; and two adjacent Xs or Ys on the aromatic ring may be united to form a fused ring]. The compounds exhibit excellent insecticidal activity against insect pests resistant to existing pesticides even when applied in dosages lower than those of similar pesticides.

摘要翻译： 由通式（I）表示的磺酰胺衍生物或其盐; 含有与活性成分相同的农业和园艺用杀虫剂; 及其用途：[其中A是任选取代的（C 1 -C 6 -C 6）亚烷基，（C 3 -C 6 - 亚烷基等; R 1是H，任选取代的（C 1 -C 6 -C 6）烷基，（C 3 -C 6 - （C 3 -C 6 -C 6）环烷基等;（C 3 -C 6）烷基，（C 3 -C 6 -C 6）环烷基等; R 2，R 3和R 4各自为H，（C 1 -C 6）烷基， （C 1 -C 6）烷基，（C 3 -C 6 -C 6）链烯基等，或R 2和A或R 2 R 1和R 2可以形成3至8元环，其可以被选自O，S和N中的一至三个原子间隔; Q是C或N; X和Y各自为卤素，CN，NO 2，（C 1 -C 6）烷基，（C 1 -C 6）烷基， 链烯基或类似物; m为0〜2; n为0〜3; 并且芳环上的两个相邻的X或Y可以结合形成稠环]。 该化合物对于现有农药抗性的昆虫害虫具有优异的杀虫活性，即使施用量低于类似农药的剂量。

公开(公告)号：US20060167315A1

公开(公告)日：2006-07-27

申请号：US10525504

申请日：2003-08-26

申请人： Minoru Yamaguchi ,  Hayami Nakao ,  Makoto Goto ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

发明人： Minoru Yamaguchi ,  Hayami Nakao ,  Makoto Goto ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

IPC分类号： C07D213/72 ,  C07C311/30

CPC分类号： C07D213/75 ,  A01N41/06 ,  A01N43/40 ,  A01N47/02 ,  C07C311/32 ,  C07C311/48 ,  C07C317/28 ,  C07C323/49 ,  C07D279/12

摘要： Sulfonamide derivatives represented by general formula (I) or salts thereof; insecticides for agricultural and horticultural use containing the same as the active ingredient; and usage thereof: [wherein A is optionally substituted (C1-C6)alkylene, (C3-C6)alkenylene or the like; R1 is H, optionally substituted (C1-C6)alkyl, (C3-C6)alkenyl, (C3-C6)cycloalkyl or the like; R2, R3 and R4 are each H, (C1-C6)alkyl, (C3-C6)alkenyl or the like, or R2 and A or R2 and R1 may form a 3- to 8-membered ring which may be interrupted by one to three atoms selected from among Of S and N; Q is C or N; X and Y are each halogen, CN, NO2, (C1-C6)alkyl, (C2-C6)alkenyl or the like; m is 0 to 2; n is 0 to 3; and two adjacent Xs or Ys on the aromatic ring may be united to form a fused ring]. The compounds exhibit excellent insecticidal activity against insect pests resistant to existing pesticides even when applied in dosages lower than those of similar pesticides.

摘要翻译： 由通式（I）表示的磺酰胺衍生物或其盐; 含有与活性成分相同的农业和园艺用杀虫剂; 及其用途：[其中A是任选取代的（C 1 -C 6 -C 6）亚烷基，（C 3 -C 6 - 亚烷基等; R 1是H，任选取代的（C 1 -C 6 -C 6）烷基，（C 3 -C 6 - （C 3 -C 6 -C 6）环烷基等;（C 3 -C 6）烷基，（C 3 -C 6 -C 6）环烷基等; R 2，R 3和R 4各自为H，（C 1 -C 6）烷基， （C 1 -C 6）烷基，（C 3 -C 6 -C 6）链烯基等，或R 2和A或R 2 R 1和R 2可以形成3至8元环，其可以被选自S和N中的一至三个原子间隔; Q是C或N; X和Y各自为卤素，CN，NO 2，（C 1 -C 6）烷基，（C 1 -C 6）烷基， 链烯基或类似物; m为0〜2; n为0〜3; 并且芳环上的两个相邻的X或Y可以结合形成稠环]。 该化合物对于现有农药抗性的昆虫害虫具有优异的杀虫活性，即使施用量低于类似农药的剂量。

公开(公告)号：US07696129B2

公开(公告)日：2010-04-13

申请号：US10477990

申请日：2002-05-16

申请人： Makoto Goto ,  Minoru Yamaguchi ,  Hiroto Harayama ,  Hayami Nakao ,  Takashi Furuya ,  Masanori Tohnishi ,  Masayuki Morimoto ,  Shinsuke Fujioka

发明人： Makoto Goto ,  Minoru Yamaguchi ,  Hiroto Harayama ,  Hayami Nakao ,  Takashi Furuya ,  Masanori Tohnishi ,  Masayuki Morimoto ,  Shinsuke Fujioka

IPC分类号： A61N43/76 ,  A01N43/76 ,  C07C15/00 ,  C07D263/02

CPC分类号： C07D213/73 ,  A01N37/30 ,  A01N41/10 ,  A01N43/40 ,  A01N43/76 ,  C07C211/52 ,  C07C217/16 ,  C07C217/84 ,  C07C233/66 ,  C07C233/69 ,  C07C233/78 ,  C07C233/85 ,  C07C251/40 ,  C07C271/12 ,  C07C271/14 ,  C07C317/28 ,  C07C323/36 ,  C07C323/42 ,  C07D213/75 ,  C07D213/82 ,  C07D263/10

摘要： The present invention provides a substituted anilide derivative of formula (I): {wherein Z is a group of formula (II) or (III) (in these formulas, A is C1-C6 alkylene, C2-C6 alkenylene, etc., R1 is H, halogen, —C(R5)═NOR6, (substituted) phenyl, (substituted) heterocyclic ring, -A1-R7, etc.; R2 is H, C1-C4 alkyl, etc.), R3 is H, C1-C4 alkyl, etc.; R4 is H, F, fluoro C1-C6 alkyl; Rf is F, fluoro C1-C6 alkyl; 1 is 0 to 2; Y is halogen, (substituted) phenyl, (substituted) phenoxy, etc.; and m is 0 to 3}, an intermediate thereof, an agrohorticultural agent, and a method for the use thereof. The compound of the present invention exhibits, at a low dosage, high uptake and translocation from the root and an excellent insecticidal effect especially when applied to soil.

摘要翻译： 本发明提供式（I）的取代的酰苯胺衍生物：其中Z是式（II）或（III）的基团（在这些式中，A是C 1 -C 6亚烷基，C 2 -C 6亚烯基等，R 1 是H，卤素，-C（R5）= NOR6，（取代的）苯基，（取代的）杂环，-A1-R7等; R2是H，C1-C4烷基等），R3是H，C1 -C4烷基等; R4是H，F，氟C1-C6烷基; Rf是F，氟C 1 -C 6烷基; 1为0〜2; Y是卤素，（取代的）苯基，（取代的）苯氧基等; m为0〜3}，其中间体，农业栽培剂及其使用方法。 本发明的化合物在低剂量下表现出高的摄取和从根部移位，并且特别是当施用于土壤时具有优异的杀虫作用。

公开(公告)号：US07151195B2

公开(公告)日：2006-12-19

申请号：US10512917

申请日：2003-05-01

申请人： Yoshihiro Matsuzaki ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

发明人： Yoshihiro Matsuzaki ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

IPC分类号： C07C233/00 ,  C07C235/00 ,  C07C237/00 ,  C07C239/00

CPC分类号： C07C381/00 ,  A01N41/12 ,  C07F9/091 ,  C07F9/1651 ,  C07F9/2458

摘要： The present invention relates to a phthalamide derivative represented by the general formula (I): wherein R1, R2, R3, X, Y, m, and n are as defined in the disclosure, which can be used as the active ingredient in an agricultural or horticultural insecticide that exhibits an excellent insecticidal effect even when used in a small active-ingredient amount.

公开(公告)号：US20060166830A1

公开(公告)日：2006-07-27

申请号：US10512917

申请日：2003-05-01

申请人： Yoshihiro Matsuzaki ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

发明人： Yoshihiro Matsuzaki ,  Masayuki Morimoto ,  Shinsuke Fujioka ,  Masanori Tohnishi

IPC分类号： A01N37/18

CPC分类号： C07C381/00 ,  A01N41/12 ,  C07F9/091 ,  C07F9/1651 ,  C07F9/2458

摘要： The present invention relates to a phthalamide derivative represented by the general formula (I): wherein R1, R2, R3, X, Y, m, and n are as defined in the disclosure, which can be used as the active ingredient in an agricultural or horticultural insecticide that exhibits an excellent insecticidal effect even when used in a small active-ingredient amount.

摘要翻译： 本发明涉及由通式（I）表示的邻苯二甲酰胺衍生物：其中R 1，R 2，R 3，X， Y，m和n如本公开中所定义，其可以用作农业或园艺杀虫剂中的活性成分，即使以小的活性成分量使用也显示出优异的杀虫作用。

公开(公告)号：US07256192B2

公开(公告)日：2007-08-14

申请号：US10168334

申请日：2000-12-22

申请人： Masanori Tohnishi ,  Eiji Kohno ,  Hayami Nakao ,  Tateki Nishida ,  Takashi Furuya ,  Toshiaki Shimizu ,  Akira Seo ,  Kazuyuki Sakata ,  Shinsuke Fujioka

发明人： Masanori Tohnishi ,  Eiji Kohno ,  Hayami Nakao ,  Tateki Nishida ,  Takashi Furuya ,  Toshiaki Shimizu ,  Akira Seo ,  Kazuyuki Sakata ,  Shinsuke Fujioka

IPC分类号： A01N43/58 ,  A61K31/50

CPC分类号： C07D295/205 ,  A01N37/30 ,  A01N41/06 ,  A01N43/16 ,  A01N43/28 ,  A01N43/40 ,  A01N47/12 ,  A01N47/28 ,  A01N57/14 ,  C07C233/66 ,  C07C233/69 ,  C07C233/75 ,  C07C233/78 ,  C07C239/16 ,  C07C271/12 ,  C07C271/20 ,  C07C271/28 ,  C07C275/14 ,  C07C307/06 ,  C07C311/05 ,  C07C311/18 ,  C07C323/12 ,  C07C323/43 ,  C07C335/08 ,  C07C2601/02 ,  C07F9/2458

摘要： The present invention relates to an aromatic diamide derivative represented by the general formula (I): [A1 is optionally substituted (C1-C8)alkylene group, (C3-C8)alkenylene group or the like, B is —O— or —N(R4)— (wherein R4 is H, (C1-C6)alkyl, halo(C1-C6)alkyl or the like), R1 is H, (C1-C6)alkyl, optionally substituted phenyl, optionally substituted heterocyclic group, or the like, R2 and R3 are each H, (C3-C6)cycloalkyl or —A2—R8 (A2 is —C(═O)—, —C(═S)— or —C(═NR9)—, R8 and R9 are each H, (C1-C6)alkyl or the like), Q1 to Q5 are each carbon or nitrogen, X and Y are each halogen, cyano, nitro, (C3-C6)cycloalkyl, optionally substituted phenyl, optionally substituted heterocyclic group, or the like, n is 0 to 4, m is 1 to 5, and Z1 and Z2 are each O or S] or a salt thereof, an agricultural and horticultural chemical, and a usage of the chemical. The agricultural and horticultural chemicals of the present invention exhibit remarkable controlling effects against various insect pests such as agricultural, forest and horticultural insect pests, and stored grain insect pests, etc., which injure paddy rice, fruit trees, vegetables, other crop plants, flowers and ornamental plants, and the like.

公开(公告)号：US06559341B2

公开(公告)日：2003-05-06

申请号：US10035132

申请日：2002-01-04

申请人： Masanori Tohnishi ,  Hayami Nakao ,  Eiji Kohno ,  Tateki Nishida ,  Takashi Furuya ,  Toshiaki Shimizu ,  Akira Seo ,  Kazuyuki Sakata ,  Shinsuke Fujioka ,  Hideo Kanno

发明人： Masanori Tohnishi ,  Hayami Nakao ,  Eiji Kohno ,  Tateki Nishida ,  Takashi Furuya ,  Toshiaki Shimizu ,  Akira Seo ,  Kazuyuki Sakata ,  Shinsuke Fujioka ,  Hideo Kanno

IPC分类号： C07C2146

CPC分类号： C07D213/40 ,  C07C211/52 ,  C07C233/65 ,  C07C233/66 ,  C07C233/75 ,  C07C233/81 ,  C07C233/91 ,  C07C233/92 ,  C07C235/64 ,  C07C235/84 ,  C07C237/22 ,  C07C251/48 ,  C07C255/57 ,  C07C261/04 ,  C07C271/20 ,  C07C271/64 ,  C07D213/70 ,  C07D263/32 ,  C07D277/30 ,  C07D295/192 ,  C07D307/52 ,  C07D333/20 ,  C07F9/18 ,  C07F9/4021

摘要： The present invention provides a phthalic acid diamide derivative represented by the general formula (I) (wherein R1, R2 and R3 are each H, C3-C6 cycloalkyl group, group of the formula —A1—Ql or the like; X may be the same or different and are each halogen atom, nitro group, phenyl group, group of the formula —A2—R7 or the like; n is 1 to 4; Y may be same or different and are each halogen atom, cyano group, phenyl group, group of the formula —A2—R7 or the like; m is 1 to 5; Z1 and Z2 are each O or S), fluorine-containing aniline compound represented by the general formula (ST-I) as starting material for said phthalic acid diamide derivative (wherein Ra is halogen atom, C1-C6 alkyl group or the like and Rb, Rc and Rd is H or C2-C6 perfluoroalkyl group), and an agricultural and horticultural insecticide containing said phthaldiamide derivative, as well as to provide a method for use of said insecticide. The agricultural and horticultural insecticides of the present invention show excellent activities for controlling injurious insects.

摘要翻译： 本发明提供由通式（I）表示的邻苯二甲酸二酰胺衍生物（其中R1，R2和R3分别为H，C3-C6环烷基，式-A1-Q1等基团等; X可以是 相同或不同，各自为卤原子，硝基，苯基，式-A2-R7等基团; n为1至4; Y可以相同或不同，各自为卤素原子，氰基，苯基 式-A2-R7等基团; m为1〜5; Z 1和Z 2各自为O或S），由通式（ST-I）表示的含氟苯胺化合物作为所述邻苯二甲酸 酸式二酰胺衍生物（其中Ra为卤素原子，C1-C6烷基等，Rb，Rc和Rd为H或C2-C6全氟烷基），以及含有所述邻苯二甲酰胺衍生物的农业和园艺杀虫剂， 一种使用所述杀虫剂的方法。 本发明的农业和园艺杀虫剂显示出控制有害昆虫的优良活性。

公开(公告)号：US06864289B1

公开(公告)日：2005-03-08

申请号：US10088543

申请日：2000-09-22

申请人： Masanori Tohnishi ,  Hayami Nakao ,  Eiji Kohno ,  Tateki Nishida ,  Takashi Furuya ,  Toshiaki Shimizu ,  Akira Seo ,  Kazuyuki Sakata ,  Shinsuke Fujioka ,  Hideo Kanno

发明人： Masanori Tohnishi ,  Hayami Nakao ,  Eiji Kohno ,  Tateki Nishida ,  Takashi Furuya ,  Toshiaki Shimizu ,  Akira Seo ,  Kazuyuki Sakata ,  Shinsuke Fujioka ,  Hideo Kanno

IPC分类号： A01N37/22 ,  A01N37/30 ,  A01N37/46 ,  A01N41/10 ,  A01N43/40 ,  C07C233/83 ,  C07C233/85 ,  C07C237/22 ,  C07C251/38 ,  C07C251/40 ,  C07C317/28 ,  C07C317/50 ,  C07C323/12 ,  C07C323/41 ,  C07D213/75 ,  C07D213/81 ,  C07D213/82 ,  C07D239/28 ,  A01N37/50

CPC分类号： C07D213/75 ,  A01N37/22 ,  A01N37/30 ,  A01N37/46 ,  A01N41/10 ,  A01N43/40 ,  C07C233/83 ,  C07C233/85 ,  C07C237/22 ,  C07C251/38 ,  C07C251/40 ,  C07C317/28 ,  C07C317/50 ,  C07C323/12 ,  C07C323/41 ,  C07D213/81 ,  C07D213/82 ,  C07D239/28

摘要： Aromatic diamide derivative represented by the general formula (I) or a salt thereof and agricultural/herticultural composition containing the same as the active ingredient, wherein A1 represents alkylene, alkenylene or alkynylene; B represents, CO— or —C(═N—OR4)— (wherein R4 represents H, etc.); R1 to R3 represent each H, etc.; Q1 to Q5 represent each N or carbon; Y represents halogeno, etc.; m is from 0 to 5; and Z1 and Z2 represent each O or S.

摘要翻译： 由通式（I）表示的芳族二酰胺衍生物或其盐和含有与活性成分相同的农业/农业组合物，其中A 1表示亚烷基，亚烯基或亚炔基; B表示CO-或-C（= N-OR 4） - （其中R 4表示H等）; R 1至R 3代表每个H等; Q 1至Q 5代表每个N或碳; Y代表卤素等; m为0〜5; Z 1和Z 2代表O或S.