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    Measuring sensor for determining the oxygen content of gas mixtures
    1.
    发明授权
    Measuring sensor for determining the oxygen content of gas mixtures 失效
    用于测定气体混合物氧含量的测量传感器

    公开(公告)号：US5702580A

    公开(公告)日：1997-12-30

    申请号：US617873

    申请日：1996-03-21

    申请人： Hermann Dietz ,  Werner Gruenwald ,  Claudio De La Prieta ,  Gert Lindemann ,  Ulrich Eisele ,  Carmen Schmiedel

    发明人： Hermann Dietz ,  Werner Gruenwald ,  Claudio De La Prieta ,  Gert Lindemann ,  Ulrich Eisele ,  Carmen Schmiedel

    IPC分类号： G01N27/41 ,  G01N27/417 ,  G01N27/419 ,  G01N27/407

    CPC分类号： G01N27/417

    摘要： A measuring sensor for determining oxygen content in a gas mixture including exhaust gases of internal combustion engines, includes a base substrate which is comprised of a base material and which is electrically insulating; and an electrochemical measuring probe and an electrochemical reference probe arranged separate from each other on the base substrate. The measuring probe includes at least one internal electrode; at least one solid electrolyte island; and at least one external electrode. The measuring probe additionally includes a diffusion barrier. Further base material layers composed of the base material are provided so as to embed at least the diffusion barrier, the at least one internal electrodes for the measuring probe and the internal electrode for the reference probe. A diffusion hole is defined between the measuring probe and the reference probe which extends from the base substrate through the diffusion barrier and respective base material layers, and out to the gas mixture to be measured. Thermal stress and the accompanying tendency to cracking is reduced by providing the solid electrolyte as islands. Separate disposition of the measuring probe and the reference probe, i.e., without a common electrode, permits construction as individual layers using, for example, screen printing.

    摘要翻译： PCT No.PCT / DE95 / 01305 Sec。 371日期1996年3月21日 102（e）日期1996年3月21日PCT提交1995年9月22日PCT公布。 公开号WO96 / 11394 日期1996年04月18日用于测定包括内燃机废气的气体混合物中的氧含量的测量传感器包括由基材构成并且是电绝缘的基底， 以及在基底基板上彼此分离设置的电化学测量探针和电化学参考探针。 测量探头包括至少一个内部电极; 至少一个固体电解质岛; 和至少一个外部电极。 测量探头还包括扩散阻挡层。 提供由基材构成的其他基材层，以便至少嵌入扩散阻挡层，至少一个用于测量探针的内部电极和用于参考探针的内部电极。 在测量探针和参考探针之间限定了扩散孔，该探针从基底基底通过扩散阻挡层和相应的基底层层延伸出来，并且进入待测量的气体混合物。 通过提供固体电解质作为岛来减少热应力和伴随的开裂倾向。 测量探针和参考探针的单独布置，即没有公共电极，可以使用例如丝网印刷将结构设计为单独的层。

    Ceramic layer systems, particularly for gas sensors
    3.
    发明授权
    Ceramic layer systems, particularly for gas sensors 失效

    公开(公告)号：US5998012A

    公开(公告)日：1999-12-07

    申请号：US716376

    申请日：1996-09-19

    申请人： Karl-Hermann Friese ,  Lothar Weber ,  Werner Gruenwald ,  Gert Lindemann ,  Harald Neumann ,  Ulrich Eisele

    发明人： Karl-Hermann Friese ,  Lothar Weber ,  Werner Gruenwald ,  Gert Lindemann ,  Harald Neumann ,  Ulrich Eisele

    IPC分类号： G01N27/409 ,  B32B18/00 ,  C04B35/00 ,  C04B41/50 ,  C04B41/87 ,  G01N27/407 ,  B23B17/00

    CPC分类号： C04B41/009 ,  B32B18/00 ,  C04B41/5042 ,  C04B41/87 ,  G01N27/4073 ,  G01N27/4075 ,  C04B2237/34 ,  C04B2237/341 ,  C04B2237/343 ,  C04B2237/348 ,  Y10T428/252 ,  Y10T428/256 ,  Y10T428/257

    摘要： A ceramic layer system including at least two layers having respective ion conductivities which are substantially different includes a substrate layer composed of a ceramic material and having substantially no ion conductivity; and at least one conducting layer positioned adjacent to the substrate layer, containing coated ceramic particles composed of ceramic particles composed of a ceramic material having no substantial ion conductivity which are coated with a material having a substantial ion conductivity so that each conducting layer of the at least one conducting layer has a continuous phase after sintering composed of the material which has a substantial ion conductivity and so that the at least one conducting layer has an ion conductivity effective to conduct ions. A method of producing a gas sensor for detecting small quantities of at least one gas in gas mixtures includes providing a substrate layer composed of ceramic particles composed of a material having substantially no ion conductivity; applying a layer composed of coated ceramic particles onto the substrate layer, the coated ceramic particles being composed of ceramic particles composed of a material that has no substantial ion conductivity coated with a material which has a substantial ion conductivity at the operating temperature of the gas sensor; applying at least one functional layer onto the layer composed of coated ceramic particles to provide a green body; preheating the green body to remove binding agents, plastifying agents, and any additional organic constituents; and sintering the green body after preheating by heating to a temperature effective to sinter the green body so that the layer comprised of coated ceramic particles has a continuous phase comprised of the material which has a substantial ion conductivity.

    Measuring sensor for determining the oxygen content of gas mixtures
    4.
    发明授权
    Measuring sensor for determining the oxygen content of gas mixtures 失效
    用于测定气体混合物氧含量的测量传感器

    公开(公告)号：US5474665A

    公开(公告)日：1995-12-12

    申请号：US306572

    申请日：1994-09-15

    申请人： Karl-Hermann Friese ,  Hermann Dietz ,  Hermann Fischer ,  Manfred Koeder ,  Werner Gruenwald ,  Ulrich Eisele

    发明人： Karl-Hermann Friese ,  Hermann Dietz ,  Hermann Fischer ,  Manfred Koeder ,  Werner Gruenwald ,  Ulrich Eisele

    IPC分类号： F02B1/04 ,  F02D41/14 ,  G01N27/409 ,  G01N27/419 ,  G01N27/407

    CPC分类号： G01N27/419 ,  F02B1/04

    摘要： The invention relates to a measuring sensor having pump reference for measuring the oxygen content of gas mixtures, particularly exhaust gases of internal combustion engines. The sensor includes a measuring cell (A) and a reference cell (B) each having a pair of electrodes, with one of each respective pairs of electrodes being common to the two cells, and having a fixed electrolyte. Reference cell (B) has defined therein an internal oxygen reference zone which is hermetically sealed from the gas mixture and which is connected to the atmosphere by way of a pressure-equalization line. The measuring cell (A) and the reference cell (B) can be heated by heating apparatus to a temperature at which the fixed electrolyte has an ionic conductivity which is sufficiently high. The heating apparatus and a porous insulation are advantageously disposed in the vicinity of the electrode of the reference cell which is not in common with the measuring cell and which is porous so that the porous insulation, together with the porous electrode, form the internal oxygen reference zone and, together with the porous electrode and its porous conductor track, form the pressure-equalization line.

    摘要翻译： 本发明涉及一种具有用于测量气体混合物，特别是内燃机废气的氧含量的泵参考的测量传感器。 传感器包括测量单元（A）和参考单元（B），每个参考单元具有一对电极，每对电极中的每一对电极与两个单元共用，并具有固定的电解液。 参考电池（B）在其中限定了内部氧参考区，其内部氧参考区与气体混合物气密密封，并通过压力平衡线连接到大气。 测量单元（A）和参考单元（B）可以通过加热装置加热至固定电解质具有足够高的离子电导率的温度。 加热装置和多孔绝缘体有利地设置在参比单元的电极附近，其与测量池不相同，并且是多孔的，使得多孔绝缘体与多孔电极一起形成内部氧参考 并且与多孔电极及其多孔导体轨道一起形成压力平衡线。

    Method for producing ceramic green bodies
    6.
    发明授权
    Method for producing ceramic green bodies 失效
    生产陶瓷生坯的方法

    公开(公告)号：US06780349B1

    公开(公告)日：2004-08-24

    申请号：US09979899

    申请日：2002-06-11

    申请人： Gert Lindemann ,  Imke Koengeter ,  Doris Peters ,  Ingrid Wuehrl ,  Ulrich Eisele

    发明人： Gert Lindemann ,  Imke Koengeter ,  Doris Peters ,  Ingrid Wuehrl ,  Ulrich Eisele

    IPC分类号： B28B320

    CPC分类号： C04B35/62218 ,  C04B35/486 ,  C04B35/6342

    摘要： A method of producing ceramic greenware, in particular a ceramic green film, having a ceramic powder component as the main ingredient and at least one organic solvent-free component as a secondary ingredient. To do so, the ceramic powder component is processed with the organic components initially to yield a highly viscous, solvent-free starting material which is then shaped by an extruder to form the greenware or green film.

    摘要翻译： 以陶瓷粉末成分为主要成分和至少一种无机无溶剂成分作为次要成分的陶瓷绿色陶瓷，特别是陶瓷绿色膜的制造方法。 为了这样做，陶瓷粉末组分最初用有机组分进行处理以产生高粘度，无溶剂的起始材料，然后通过挤出机成型以形成绿色软件或绿色膜。

    Sensor element, in particular a temperature sensor
    7.
    发明授权
    Sensor element, in particular a temperature sensor 失效
    传感器元件，特别是温度传感器

    公开(公告)号：US06636142B2

    公开(公告)日：2003-10-21

    申请号：US09980472

    申请日：2001-11-30

    申请人： Heinz Geier ,  Gert Lindemann ,  Friederike Lindner ,  Thomas Brinz ,  Ulrich Eisele

    发明人： Heinz Geier ,  Gert Lindemann ,  Friederike Lindner ,  Thomas Brinz ,  Ulrich Eisele

    IPC分类号： H01C104

    CPC分类号： G01K7/183

    摘要： A sensor element, especially a temperature sensor (5) is proposed, having a sensitive area (11), whose electrical resistance changes under the influence of a temperature to which the sensitive area (11) is exposed. In this case, sensitive area (11) has a glass ceramic fusion (15) of a starting material containing at least one component which is furnished at least substantially with a surface metallization. The proposed temperature sensor (5) is especially suitable for use at temperatures in excess of 1000° C., at which it shows resistance characteristics like that of a platinum resistor.

    摘要翻译： 提出了一种传感器元件，特别是温度传感器，其具有敏感区域，其敏感区域在敏感区域暴露的温度的影响下变化。 在这种情况下，敏感区域具有包含至少基本上具有表面金属化的至少一种成分的起始材料的玻璃陶瓷熔合。 所提出的温度传感器特别适合在超过1000℃的温度下使用，在此温度传感器显示出如铂电阻器的电阻特性。

    Process for the production of composite systems having at least two inorganic ceramic layers
    8.
    发明授权
    Process for the production of composite systems having at least two inorganic ceramic layers 失效
    用于生产具有至少两个无机陶瓷层的复合体系的方法

    公开(公告)号：US5628848A

    公开(公告)日：1997-05-13

    申请号：US367141

    申请日：1995-01-09

    申请人： Karl-Hermann Friese ,  Werner Gruenwald ,  Ulrich Eisele

    发明人： Karl-Hermann Friese ,  Werner Gruenwald ,  Ulrich Eisele

    IPC分类号： B32B18/00 ,  C04B37/00 ,  G01N27/407 ,  B32B31/26

    CPC分类号： B32B18/00 ,  C04B37/001 ,  G01N27/4073 ,  C04B2237/343 ,  C04B2237/348 ,  C04B2237/36 ,  C04B2237/586 ,  C04B2237/76

    摘要： The invention relates to composite systems having at least two layers which comprise different inorganic, ceramic phases and are produced by cosintering of different, finely divided inorganic materials arranged in layers. The composite systems are characterized in that at least two adjacent layers comprise a dense phase largely free of macropores. The layers are durably bonded to one another by sintering together of particles of the different materials at the phase boundary or boundaries. The composite systems and the processes for the production thereof are used, for example, in the manufacture of gas sensors.

    摘要翻译： PCT No.PCT / DE94 / 00520 Sec。 371日期1995年1月9日 102（e）1995年1月9日PCT PCT 1994年5月6日PCT公布。 第WO94 / 27819号公报 日期1994年12月8日本发明涉及具有至少两层的复合体系，它们包含不同的无机陶瓷相，并通过不同细分的无机材料以层间顺序的同步化而产生。 复合体系的特征在于至少两个相邻的层包含大部分不含大孔的密相。 这些层通过在相边界或边界处将不同材料的颗粒烧结在一起而相互粘合在一起。 复合系统及其制造方法例如用于气体传感器的制造中。