摘要:
A needle-shaped ceramic body having as its base material a cordierite porous body having a high specific surface area and superior thermal shock resistance, and a needle-shaped catalyst-ceramic body are provided. The present invention relates to a needle-shaped ceramic body having as its base material a needle-shaped cordierite in which the tips thereof are rounded, a needle-shaped catalyst-ceramic body loaded with a catalyst, and a method of production of a ceramic body in which a portion of a raw material (fluoride) gasified by a reaction between raw materials is grown into a needle like shape on the metal catalyst (Fe), wherein the tips of needle-shaped particles are rounded, using a vapor-liquid-solid (VLS) reaction, in a raw material burning process. A honeycomb structure composed of the needle-shaped ceramic for supporting a catalyst is provided, in which decreases in specific surface area caused by sintering can be inhibited, and it enables early catalyst activation due to the low thermal capacity, and has low pressure loss.
摘要:
A needle-shaped ceramic body having as its base material a cordierite porous body having a high specific surface area and superior thermal shock resistance, and a needle-shaped catalyst-ceramic body are provided.The present invention relates to a needle-shaped ceramic body having as its base material a needle-shaped cordierite in which the tips thereof are rounded, a needle-shaped catalyst-ceramic body loaded with a catalyst, and a method of production of a ceramic body in which a portion of a raw material (fluoride) gasified by a reaction between raw materials is grown into a needle like shape on the metal catalyst (Fe), wherein the tips of needle-shaped particles are rounded, using a vapor-liquid-solid (VLS) reaction, in a raw material burning process.A honeycomb structure composed of the needle-shaped ceramic for supporting a catalyst is provided, in which decreases in specific surface area caused by sintering can be inhibited, and it enables early catalyst activation due to the low thermal capacity, and has low pressure loss.
摘要:
The present invention provides a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a case material is a high specific surface area porous cordierite body that is stable at high temperatures, and also provides methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body. The present invention relates to a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high temperature-stable, high specific surface area porous cordierite body comprising a porous structure having a prescribed porosity and formed of a needle-shaped cordierite crystal phase and further relates to methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body, and by using porous cordierite constituted of needle-shaped crystals as a catalyst-supporting honeycomb structure, the present invention is able to inhibit sintering-induced reduction in the specific surface area. Since a honeycomb can be directly produced as the cordierite sinter itself, an inexpensive product can be provided through the simplifying the prior-art step of coating the interior of the honeycomb.
摘要:
The present invention provides a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high specific surface area porous cordierite body that is stable at high temperatures, and also provides methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body. The present invention relates to a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high temperature-stable, high specific surface area porous cordierite body comprising a porous structure having a prescribed porosity and formed of a needle-shaped cordierite crystal phase, and further relates to methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body, and by using porous cordierite constituted of needle-shaped crystals as a catalyst-supporting honeycomb structure, the present invention is able to inhibit sintering-induced reduction in the specific surface area. Since a honeycomb can be directly produced as the cordierite sinter itself, an inexpensive product can be provided through the simplifying the prior-art step of coating the interior of the honeycomb.
摘要:
A ceramic body, a ceramic catalyst body, a ceramic catalyst body and related manufacturing methods are disclosed wherein a cordierite porous base material has a surface, formed with acicular particles made of a component different from that of cordierite porous base material, which has an increased specific surface area with high resistance to a sintering effect. The ceramic body is manufactured by preparing a slurry containing an acicular particle source material, preparing a porous base material, applying the slurry onto a surface of the porous base material and firing the porous base material, whose surface is coated with the slurry, to cause acicular particles to develop on the surface of the porous base material. A part of or a whole of surfaces of the acicular particles is coated with a constituent element different from that of the acicular particles.
摘要:
A ceramic body, a ceramic catalyst body, a ceramic catalyst body and related manufacturing methods are disclosed wherein a cordierite porous base material has a surface, formed with acicular particles made of a component different from that of cordierite porous base material, which has an increased specific surface area with high resistance to a sintering effect. The ceramic body is manufactured by preparing a slurry containing an acicular particle source material, preparing a porous base material, applying the slurry onto a surface of the porous base material and firing the porous base material, whose surface is coated with the slurry, to cause acicular particles to develop on the surface of the porous base material. A part of or a whole of surfaces of the acicular particles is coated with a constituent element different from that of the acicular particles.
摘要:
A ceramic body that can support a required amount of catalyst component, without lowering the characteristics such as strength, manufactured without forming a coating layer and providing a high performance ceramic catalyst body that is excellent in practical utility and durability. This ceramic body is made by substituting at least one of the constituent elements of cordierite that constitutes the substrate ceramic, for example Al, with W that is the element having an empty orbit in d or f orbit, has high bonding strength and is less susceptible to deterioration since the catalyst component Pt is supported by means of chemical bonding.
摘要:
A cordierite honeycomb body is produced by forming a cordierite material including kaoline into a honeycomb shape and sintering it. The kaoline included in the cordierite material is at least partly composed of kaolinite having a Hinckley crystallinity index of 0.5 or more thereby having a less amorphous phase portion in a kaolinite particle. Therefore, when the cordierite material is sintered, the number of micropores generated in the cordierite is decreased due to the less amorphous phase portion in the kaolinite particles. As a result, density of the cordierite is increased without increasing a C.T.E. thereof. Thus, the cordierite honeycomb body has sufficient strength even when thickness of a cell wall thereof is decreased.
摘要:
There is provided a process for obtaining a cordierite honeycomb structural body with thin cell walls and no molding defects such as cell breakage or the like. Cell breakage is prevented by limiting the maximum particle size of the cordierite starting material powder to no greater than 85% of the slit width of the extrusion molding die so that the starting material particles will not clog inside the slits or the introduction port of the slits. As one cordierite starting material, talc with a mean particle size of 5 &mgr;m or greater is used to give a honeycomb structural body with a void volume of greater than 30%, for production of a honeycomb structural body, with good moldability, having a small thickness and a low heat capacity. It is preferred to add to the starting material at least a lubricant/humectant, a binder and/or a mixture of a water-soluble polyhydric alcohol derivative and a polyhydric alcohol.
摘要:
There are provided thin-walled honeycomb structural bodies with high strength and excellent thermal shock resistance by using as the starting material for cordierite honeycomb structural bodies a combination of talc with a median particle diameter exceeding 7 .mu.m and not greater than 20 .mu.m and with a CaO content of 0.2 wt % or less and another cordierite material such as kaolin with a median particle diameter of not greater than 1 .mu.m, molding the starting material into a honeycomb shape with a cell wall thickness of 130 .mu.m or less, and firing the mold.