摘要:
[PROBLEMS] To provide a polymer composition that simultaneously has excellent paintability and high oil resistance and is also excellent in thin-wall moldability and flexibility; and a molded article produced by injection-molding of the composition and being suitable for composite-molded grips, automotive interior and exterior trims, and so on. [MEANS FOR SOLVING PROBLEMS] A polymer composition and a molded article that are comprising 33 to 67% by mass of a polybutylene terephthalate-based resin (A) and 67 to 33% by mass of an acrylic block copolymer (B); and in the acrylic block copolymer (B), two polymer blocks (b2) comprising a unit of methacrylic ester such as methyl methacrylate are bonded to the both ends of a polymer block (b1) comprising a unit of acrylic ester such as butyl acrylate, the total mass of the polymer block (b2) is 20 to 35% by mass with respect to the acrylic block copolymer (B), the weight-average molecular weight is 50000 to 100000, and the order-disorder transition temperature is 180 to 230° C.
摘要:
A polylactic acid composition comprising (A) a polylactic acid-series resin and (B) an acrylic triblock copolymer is prepared. The composition fulfills the following requirements: (1) the acrylic triblock copolymer (B) is a triblock polymer comprising (B1) a polymer block having a glass-transition temperature of not higher than 25° C., (B2a) a polymer block which has a glass-transition temperature of not lower than 60° C. and is bound to a terminal of the polymer block (B1), and (B2b) a polymer block which has a glass-transition temperature of not lower than 60° C. and is bound to another terminal thereof; (2) the polymer block (B1) comprises a main structural unit derived from an acrylate, and the polymer block (B2a) and the polymer block (B2b) independently comprise a main structural unit derived from a methacrylate; and (3) both of the weight-average molecular weights of the polymer block (B2a) and polymer block (B2b) are smaller than the weight-average molecular weight of the polymer block (B1). The polylactic acid-series resin (A) and the acrylic triblock copolymer (B) may form a phase separation structure.
摘要:
[Problems] To provide a polymer composition that simultaneously has excellent paintability and high oil resistance and is also excellent in thin-wall moldability and flexibility; and a molded article produced by injection-molding of the composition and being suitable for composite-molded grips, automotive interior and exterior trims, and so on.[Means for Solving Problems] A polymer composition and a molded article that are comprising 33 to 67% by mass of a polybutylene terephthalate-based resin (A) and 67 to 33% by mass of an acrylic block copolymer (B); and in the acrylic block copolymer (B), two polymer blocks (b2) comprising a unit of methacrylic ester such as methyl methacrylate are bonded to the both ends of a polymer block (b1) comprising a unit of acrylic ester such as butyl acrylate, the total mass of the polymer block (b2) is 20 to 35% by mass with respect to the acrylic block copolymer (B), the weight-average molecular weight is 50000 to 100000, and the order-disorder transition temperature is 180 to 230° C.
摘要:
A polylactic acid composition comprising (A) a polylactic acid-series resin and (B) an acrylic triblock copolymer is prepared. The composition fulfills the following requirements: (1) the acrylic triblock copolymer (B) is a triblock polymer comprising (B1) a polymer block having a glass-transition temperature of not higher than 25° C., (B2a) a polymer block which has a glass-transition temperature of not lower than 60° C. and is bound to a terminal of the polymer block (B1), and (B2b) a polymer block which has a glass-transition temperature of not lower than 60° C. and is bound to another terminal thereof; (2) the polymer block (B1) comprises a main structural unit derived from an acrylate, and the polymer block (B2a) and the polymer block (B2b) independently comprise a main structural unit derived from a methacrylate; and (3) both of the weight-average molecular weights of the polymer block (B2a) and polymer block (B2b) are smaller than the weight-average molecular weight of the polymer block (B1). The polylactic acid-series resin (A) and the acrylic triblock copolymer (B) may form a phase separation structure.
摘要:
[Object] Provided are a sheet-like molded article having excellent surface smoothness, moldability, flexibility, and a high transmittance of short-wavelength light, and a thermoplastic polymer composition used to produce the sheet-like molded article.[Solution] A thermoplastic polymer composition containing an acrylic block copolymer (A) and an acrylic resin (B), in which the acrylic block copolymer (A) has, in its molecule, at least one structure where polymer blocks (a2) mainly composed of a methacrylic ester unit are bonded to both ends of a polymer block (a1) mainly composed of an acrylic ester unit, the acrylic block copolymer (A) having a specific weight-average molecular weight range, the acrylic block copolymer (A) contains an acrylic block copolymer (A1) having a polymer block (a2) content of 40% by mass or more and not less than 80% by mass and contains an acrylic block copolymer (A2) having a polymer block (a2) content of 10% by mass or more and less than 40% by mass, the acrylic resin (B) is mainly composed of a methacrylic ester unit, and the mass ratio [(A)/(B)] is in the range of 97/3 to 10/90.
摘要:
[Object] Provided are a sheet-like molded article having excellent surface smoothness, moldability, flexibility, and a high transmittance of short-wavelength light, and a thermoplastic polymer composition used to produce the sheet-like molded article.[Solution] A thermoplastic polymer composition containing an acrylic block copolymer (A) and an acrylic resin (B), in which the acrylic block copolymer (A) has, in its molecule, at least one structure where polymer blocks (a2) mainly composed of a methacrylic ester unit are bonded to both ends of a polymer block (a1) mainly composed of an acrylic ester unit, the acrylic block copolymer (A) having a specific weight-average molecular weight range, the acrylic block copolymer (A) contains an acrylic block copolymer (A1) having a polymer block (a2) content of 40% by mass or more and not less than 80% by mass and contains an acrylic block copolymer (A2) having a polymer block (a2) content of 10% by mass or more and less than 40% by mass, the acrylic resin (B) is mainly composed of a methacrylic ester unit, and the mass ratio [(A)/(B)] is in the range of 97/3 to 10/90.
摘要:
The present invention relates to a method of obtaining a (meth)acrylate-based polymer from a reaction solution containing the (meth)acrylate-based polymer, the method including (a) adding an acid to the reaction solution containing the (meth)acrylate-based polymer which is obtained by polymerizing a monomer composed mainly of a (meth)acrylate in a water-insoluble organic solvent in the presence of a metal compound, (b) washing the reaction solution to which the acid has been added by admixing water at 90° C. or more, (c) separating the mixed solution of the reaction solution and water generated by the washing in (b) into an organic solvent solution layer and an aqueous solution layer, and (d) isolating each of the organic solvent solution layer and the aqueous solution layer in order to obtain the (meth)acrylate-based polymer from the isolated organic solvent solution layer.
摘要:
Problems: To easily and efficiently obtain a high quality (meth)acrylate-based polymer containing small residual amount of metal components (an aluminum component, an alkali metal component and other metal components) and having high purity and excellent properties such as heat resistance, transparency and others.Means for Solving the Problems: The present invention provides a method of obtaining a (meth)acrylate-based polymer by adding an acid to a reaction solution containing the (meth)acrylate-based polymer obtained by polymerizing a (meth)acrylate-based monomer in a water-insoluble organic solvent in the presence of a metal compound such as a metal-containing polymerization initiator, an organoaluminum compound and the like, washing the reaction solution to which the acid has been added by admixing water at 90° C. or more, separating the mixed solution of the reaction solution and water generated by washing into an organic solvent solution layer and an aqueous solution layer, isolating the organic solvent solution separated into a layer, and obtaining the (meth)acrylate-based polymer out of the solution. Also provided is a high-purity (meth)acrylate-based polymer having excellent transparency obtained by the method.
摘要:
A mower unit includes a housing, a pair of cutting blades arranged inside the housing, each of the cutting blades being rotatable about a respective vertical axis supported by the housing, the cutting blades being driven to be rotated in opposite directions, and a baffle arranged generally between rotation regions of the cutting blades to guide air flows generated by the cutting blades. The baffle defines an upper baffle portion located adjacent an upper region of the housing, a lower baffle portion located adjacent a lower region of the housing, and an air passage formed for allowing the air flows to flow between the upper baffle portion and lower baffle portion.
摘要:
A mower unit includes a mower deck, a plurality of blades mounted inside the mower deck and rotatable about vertical shafts supported to the mower deck, the mower deck defining, on one lateral side thereof, a discharge outlet for discharging cut grass cut by the plurality of blades, and an opening and closing member configured to be movable to a closing position for closing the discharge outlet and also to an opening position away from the discharge outlet for opening the discharge outlet, the opening and closing member at the opening position being disposed along an outer face of the mower deck.