摘要:
A thermoplastic resin composition (Y) characterized by comprising (A) 20 to 64.9 wt % one or more ethylene copolymers comprising an ethylene/α-olefin copolymer, (B) 35 to 70 wt % metal hydroxide, and (C) 0.1 to 30 wt % grafted ethylene polymer. The resin composition has excellent flame retardancy and has satisfactory pliability/flexibility and excellent tensile properties. It is suitable for use as an insulating material or sheath for electric wires. Also provided are: a polymer composition (Z) having high flame retardancy, characterized by comprising relative to (AA) 100 parts by weight of a polymer such as a thermoplastic polymer or thermosetting polymer, in the ratio of (BB) 50 to 250 parts by weight of a metal hydroxide, (E) 0.1 to 40 parts by weight of a triazine ring containing compound, and (F) 0.1 to 40 parts by weight of a polyhydric alcohol; and a molded object obtained from the polymer composition. These are suitable for use as an insulating material or sheath for electric wires.
摘要:
A thermoplastic resin composition (Y) characterized by comprising (A) 20 to 64.9 wt % one or more ethylene copolymers comprising an ethylene/α-olefin copolymer, (B) 35 to 70 wt % metal hydroxide, and (C) 0.1 to 30 wt % grafted ethylene polymer. The resin composition has excellent flame retardancy and has satisfactory pliability/flexibility and excellent tensile properties. It is suitable for use as an insulating material or sheath for electric wires. Also provided are: a polymer composition (Z) having high flame retardancy, characterized by comprising relative to (AA) 100 parts by weight of a polymer such as a thermoplastic polymer or thermosetting polymer, in the ratio of (BB) 50 to 250 parts by weight of a metal hydroxide, (E) 0.1 to 40 parts by weight of a triazine ring containing compound, and (F) 0.1 to 40 parts by weight of a polyhydric alcohol; and a molded object obtained from the polymer composition. These are suitable for use as an insulating material or sheath for electric wires.
摘要:
A composition which can provide a foamed product (non-crosslinked or crosslinked foamed product) having low specific gravity and low compression set (CS), excelling in the tensile strength properties and the tear strength properties, as well as in impact resilience, and exhibiting a less decrease in hardness at high temperatures; a foamed product produced therefrom; and a laminate produced using the foamed product are provided. A resin composition for a foamed product comprising 5 to 95 pars by weight of an ethylene/α-olefin copolymer (A1), 5 to 95 parts by weight of a styrene block copolymer (B), and based on 100 parts by weight of the total of components (A1) and (B), 0 to 1900 parts by weight of an ethylene/polar monomer copolymer (A2).
摘要:
A multilayered article and vessel, which are superior in the properties, such as shock resistance, rigidity, an ability to barrier against gasoline and interlayer adhesion, and are permissible of being recycled for reuse, comprising a base layer (A1) comprising a polyetylene resin (a1) having an MFR (ASTM D 1238, 190° C., 2160 g) of 0.001 to 0.5 g/10 min. and a density of 0.945 to 0.980 g/cm3, an adhesive layer (A2) comprising a modified etylene/&agr;-olefin copolymer (a2) which is modified by having grafted thereon an unsaturated carboxylic acid or its derivative and has a density of 0.900 to 0.940 and a barriering layer (B) comprising an ethylene/vinyl alcohol copolymer (b), wherein the Izod impact strength (with notch) (ASTM D 256, −40° C.) for a sheet specimen which is prepared by mechanically crushing the laminate into powder, granulating the resulting powder on a monoaxial extruder to form a resin composition and pressing the granular composition on a press molding machine into a sheet of 3 mm thickness at a temperature of 230° C. under a pressure of 50 kgf/cm2 with cooling under the condition defined by ASTM D 1928, is at least 100 J/m.
摘要翻译:具有优异性能的多层制品和容器,例如耐冲击性,刚性,阻挡汽油的能力和层间粘合性,并且是允许再循环使用的,包括:包含聚乙烯树脂的基层(A1) a1)具有0.001至0.5g / 10min的MFR(ASTM D 1238,190℃,2160g)。 和密度为0.945至0.980g / cm 3的粘合剂层(A2),包含改性的亚乙烯/α-烯烃共聚物(a2)的粘合剂层(A2),其通过在其上接枝不饱和羧酸或其衍生物并具有密度 为0.900〜0.940,以及包含乙烯/乙烯醇共聚物(b)的阻挡层(B),其中用于片材试样的悬臂梁式冲击强度(具有切口)(ASTM D 256,-40℃) 将层压体机械破碎成粉末,将所得粉末在单轴挤出机上造粒,形成树脂组合物,并将压制成型机上的粒状组合物在压力为50℃的压力下在230℃的温度下压制成3mm厚的片材 kgf / cm 2,在ASTM D1928规定的条件下冷却至少为100J / m。
摘要:
The adhesive ethylene copolymer composition of the invention comprises a specific long-chain branched ethylene/&agr;-olefin copolymer (or this copolymer and its graft-modified product) and a tackifier (or a specific ethylene/vinyl acetate copolymer), and has specific density, MFR, crystallinity and graft quantity. The composition containing the tackifier can form a layer having good adhesive force to polystyrene resins, ABS resin, polyacrylonitrile resins and ethylene/vinyl acetate copolymer saponified resins even in an atmosphere of high temperatures. The composition containing the ethylene/vinyl acetate copolymer can form a layer having good adhesive force to polyester resins, polycarbonate resins, polyvinylidene chloride resins and ethylene/vinyl acetate saponified resins even in an atmosphere of high temperatures. The other adhesive ethylene copolymer composition of the invention comprises a blend of a graft-modified linear ethylene/&agr;-olefin copolymer and an olefin elastomer. This composition has excellent heat stability, moldability and transparency, and can form a film layer having good adhesive force to metals and materials of high polarity.
摘要:
The present invention provides a multi-layer laminate consisting essentially of:(A) a layer formed from an ethylene/cycloolefin random copolymer which is a copolymer of ethylene and a cycloolefin represented by a specific formula (e.g., tetracyclododecene), or a layer formed from a cycloolefin resin which is a graft modified product of the ethylene/cycloolefin random copolymer, or a layer formed from a cycloolefin resin composition comprising the cycloolefin resin and a polyolefin, and(B) a barrier layer consisting essentially of ethylene/vinyl alcohol copolymer, polyvinylidene chloride, or polyacrylonitrile, with the barrier layer having an oxygen permeability, as measured at 23.degree. C. and RH of 0%, of not more than 10 cc(STP).mm/m.sup.2.24 hr.atm; said multi-layer laminate having a moisture permeability of not more than 0.2 g.mm/m.sup.2.24 hr.atm and an oxygen permeability of not more than 5 cc(STP).mm/m.sup.2.24 hr.atm. This multi-layer laminate has excellent gas-barrier properties and high rigidity. The present invention also provides a packaging material and a film using the multi-layer laminate.
摘要:
The modified polypropylene composition of the invention comprises (A) modified polypropylene having been partially or wholly graft modified with an unsaturated carboxylic acid or its derivative, (B) an amorphous or low-crystalline ethylene/&agr;-olefin copolymer having a specific MFR and a specific density and (C) a styrene elastomer, in a specific ratio. The component (A) is a graft modification product of a propylene homopolymer and/or a graft modification product of a propylene/&agr;-olefin random copolymer. The laminate of the invention comprises a composition layer comprising the modified polypropylene composition and a resin layer provided on one or both surfaces of the composition layer. By the use of the modified polypropylene composition as a laminate-forming composition or an adhesive resin composition, there can be obtained a laminate which has excellent interlaminar strength and which can be prevented from lowering of the interlaminar strength even if it is subjected to a heat treatment at a high temperature such as a temperature of 80 to 125° C.
摘要:
A multilayered article and vessel, which are superior in the properties, such as shock resistance, rigidity, an ability to barrier against gasoline and interlayer adhesion, and are permissible of being recycled for reuse, comprising a base layer (A1) comprising a polyetylene resin (a1) having an MFR (ASTM D 1238, 190° C., 2160 g) of 0.001 to 0.5 g/10 min. and a density of 0.945 to 0.980 g/cm3, an adhesive layer (A2) comprising a modified etylene/&agr;-olefin copolymer (a2) which is modified by having grafted thereon an unsaturated carboxylic acid or its derivative and has a density of 0.900 to 0.940 and a barriering layer (B) comprising an ethylene/vinyl alcohol copolymer (b), wherein the Izod impact strength (with notch) (ASTM D 256, −40° C.) for a sheet specimen which is prepared by mechanically crushing the laminate into powder, granulating the resulting powder on a monoaxial extruder to form a resin composition and pressing the granular composition on a press molding machine into a sheet of 3 mm thickness at a temperature of 230° C. under a pressure of 50 kgf/cm2 with cooling under the condition defined by ASTM D 1928, is at least 100 J/m.
摘要翻译:具有优异性能的多层制品和容器,例如耐冲击性,刚性,阻挡汽油的能力和层间粘合性,并且是允许再循环使用的,包括:包含聚乙烯树脂的基层(A1) a1)具有0.001至0.5g / 10min的MFR(ASTM D 1238,190℃,2160g)。 和密度为0.945〜0.980g / cm3的粘合剂层(A2),其包含改性乙烯/α-烯烃共聚物(a2)的粘合剂层(A2),其通过在其上接枝不饱和羧酸或其衍生物并且具有0.900至 0.940和包含乙烯/乙烯醇共聚物(b)的阻塞层(B),其中用于通过机械破碎所得到的片材试样的悬臂梁式冲击强度(具有切口)(ASTM D 256,-40℃) 层压成粉末,将得到的粉末在单轴挤出机上造粒,形成树脂组合物,并将压制成型机上的粒状组合物在压力为50kgf / cm2的温度下在230℃的温度下压制成3mm厚的片材 在ASTM D 1928规定的条件下冷却至少为100J / m。
摘要:
An adhesive resin composition contains at least a partially or wholly graft-modified .alpha.-olefin/aromatic vinyl compound random copolymer having a graft quantity of an unsaturated carboxylic acid or its derivative ranging from 0.01 to 30% by weight. A laminate comprises (I) a polyester resin layer or a polycarbonate layer, (II) an adhesive layer formed from the above-mentioned adhesive resin composition and (III) a saponified olefin/vinyl acetate copolymer layer. The adhesive resin composition is free from lowering of adhesive strength even when contacted with, for example, hot water. The laminate has excellent gas barrier properties and is capable of being subjected to retorting treatment.
摘要:
An adhesive ethylene copolymer resin composition blend of a modified ethylene/&agr;-olefin copolymer obtained by graft-modifying an unmodified linear ethylene/&agr;-olefin copolymer comprising ethylene and an a-olefin of 3 to 20 carbon atoms with an unsaturated carboxylic acid or its derivative, or the unmodified ethylene/&agr;-olefin copolymer and the modified ethylene/&agr;-olefin copolymer and an olefin elastomer (F) The linear ethylene/&agr;-olefin copolymer being prepared by the use of an olefin polymerization catalyst including a Group IV transition metal compound (a) containing a ligand having cyclopentadienyl skeleton and an organoaluminum oxy-compound (b). The adhesive ethylene copolymer resin composition can be used as a layer to form a laminate with a layer of a polar material or a layer of a metal. The polar material layer can be a layer of an ethylene/vinyl alcohol copolymer, a layer of a polyamide or a layer of a polyester.