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    Unsaturated accelerators for hydrosilation
    1.
    发明授权
    Unsaturated accelerators for hydrosilation 失效
    用于硅氢化的不饱和促进剂

    公开(公告)号：US5756795A

    公开(公告)日：1998-05-26

    申请号：US775229

    申请日：1996-12-30

    申请人： Howard Marvin Bank ,  Aroop Kumar Roy

    发明人： Howard Marvin Bank ,  Aroop Kumar Roy

    IPC分类号： B01J23/40 ,  B01J31/22 ,  C07B61/00 ,  C07F7/12 ,  C07F7/14 ,  C07F7/08

    CPC分类号： C07F7/14

    摘要： A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from the group consisting of 1,7-octadiyne, 1,5-hexadiyne, cyclooctadiene, 5-vinyl-2-norbornene, 4-vinyl-1-cyclohexene, 2,5-bis(t-butylperoxy)-2,5-dimethylhexane, furan, 4H-Pyran-4-one, cis-4,7-dihydro-1,3-dioxepin, maleic anhydride, and dimethyldiallylmalonate. The accelerators are especially useful for facilitating the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene.

    摘要翻译： 一种硅氢化方法，其中氢化硅与不饱和反应物在铂催化剂和选自由1,7-辛二炔，1,5-己二炔，环辛二烯，5-乙烯基-2-降冰片烯 ，4-乙烯基-1-环己烯，2,5-双（叔丁基过氧）-2,5-二甲基己烷，呋喃，4H-吡喃-4-酮，顺式-4,7-二氢-1,3-二氧杂环庚烯， 马来酸酐和二甲基二烯丙基丙二酸酯。 促进剂特别有助于促进不饱和反应物的氢化硅化，其中不饱和键在反应物结构的内部，例如在环戊烯和环己烯中。

    Polymerizable Silicone Copolymer Macromers and Polymers Made Therefrom
    5.
    发明申请
    Polymerizable Silicone Copolymer Macromers and Polymers Made Therefrom 审中-公开
    可聚合的硅酮共聚物大分子单体和聚合物

    公开(公告)号：US20070203311A1

    公开(公告)日：2007-08-30

    申请号：US11677610

    申请日：2007-02-22

    申请人： Aroop Kumar Roy ,  Krishnan Tamareselvy

    发明人： Aroop Kumar Roy ,  Krishnan Tamareselvy

    IPC分类号： C08B37/00

    CPC分类号： C08G77/50 ,  A61K8/891 ,  A61K8/894 ,  A61K8/895 ,  A61Q19/00 ,  C08F283/124 ,  C08F290/068 ,  C08G77/20 ,  C08G77/38 ,  C08G77/46 ,  C08L83/12

    摘要： A polymerizable dimethicone copolyol macromer composition is synthesized by reacting itaconic anhydride with a dimethicone copolyol. During the reaction itaconic anhydride spontaneously isomerizes to citraconic anhydride which in turn is esterified by the dimethicone copolyol. The obtained macromers are copolymerizable with olefinically unsaturated monomers. Polymers containing the macromer repeating units are useful in a variety of applications including personal care, textile and industrial formulations to deliver softness, lubricity, fixative, water repellency, gloss, surface modification, and surfactant properties.

    摘要翻译： 通过将衣康酸酐与二甲聚硅氧烷共聚醇反应合成可聚合的聚二甲基硅氧烷共聚多元醇大分子单体组合物。 在反应期间，衣康酸酐自发异构化成柠康酸酐，其又被二甲聚硅氧烷共聚醇酯化。 所获得的大分子单体可与烯属不饱和单体共聚。 含有大分子单体重复单元的聚合物可用于各种应用，包括个人护理，织物和工业制剂，以提供柔软度，润滑性，固定剂，防水性，光泽度，表面改性和表面活性剂性质。

    Living cationic polymers prepared from silyl-functional aromatic initiators
    6.
    发明授权
    Living cationic polymers prepared from silyl-functional aromatic initiators 失效
    由甲硅烷基官能的芳族引发剂制备的活性阳离子聚合物

    公开(公告)号：US06194597B1

    公开(公告)日：2001-02-27

    申请号：US09292333

    申请日：1999-04-15

    申请人： Rudolf Faust ,  Savvas E. Hadjikyriacou ,  Aroop Kumar Roy ,  Toshio Suzuki

    发明人： Rudolf Faust ,  Savvas E. Hadjikyriacou ,  Aroop Kumar Roy ,  Toshio Suzuki

    IPC分类号： C07P712

    CPC分类号： C08F297/00 ,  C08F2/38 ,  C08F4/42 ,  C08F8/00 ,  C08F10/10 ,  C08F12/00 ,  C08F10/00 ,  C08F4/16 ,  C08F4/00

    摘要： There is disclosed a method for preparing a silyl-functional living cationic polymer which can be subsequently coupled to form a moisture-curable telechelic system, said method comprising reacting, in the presence of a Lewis acid, (A) at least one cationically polymerizable monomer with (B) an initiator of the formula wherein R is selected from H or methyl group, R′ is a divalent non-aromatic hydrocarbon group having, 1 to 6 carbon atoms, R″ is selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having, 6 to 10 carbon atoms, X is halogen, Y is halogen and n is 1, 2 or 3.

    摘要翻译： 公开了一种制备甲硅烷基官能的活性阳离子聚合物的方法，其可以随后偶联以形成湿气固化遥爪系统，所述方法包括在路易斯酸存在下使（A）至少一种阳离子可聚合单体 （B）式中R的引发剂选自H或甲基，R'是具有1至6个碳原子的二价非芳族烃基，R“选自具有1-10个碳原子的烷基 或具有6〜10个碳原子的芳基，X为卤素，Y为卤素，n为1,2或3。

    Virtually telechelic silyl-functional polyisobutylene
    10.
    发明授权
    Virtually telechelic silyl-functional polyisobutylene 有权
    几乎遥爪甲硅烷基官能的聚异丁烯

    公开(公告)号：US06469115B1

    公开(公告)日：2002-10-22

    申请号：US09572135

    申请日：2000-05-16

    申请人： Rudolf Faust ,  Savvas E. Hadjikyriacou ,  Aroop Kumar Roy ,  Toshio Suzuki

    发明人： Rudolf Faust ,  Savvas E. Hadjikyriacou ,  Aroop Kumar Roy ,  Toshio Suzuki

    IPC分类号： C08F400

    CPC分类号： C08F210/10 ,  C08F4/00 ,  C08F2/38

    摘要： A method for preparing a moisture-curable, virtually telechelic, silyl-functional polyisobutylene is disclosed, said method comprising reacting, in the presence of a Lewis acid, (A) isobutylene; (B) an initiator of the formula (C) a styryl comonomer of the formula wherein R is selected from H or methyl group, R′ is a divalent non-aromatic hydrocarbon group having 1 to 6 carbon atoms, R″ is independently selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having 6 to 10 carbon atoms, R′″ is a divalent non-aromatic hydrocarbon group having 2 to 6 carbon atoms, X is independently a halogen group, Y is halogen and n is independently 1, 2 or 3.

    摘要翻译： 公开了一种制备湿气固化的，实际上是遥爪的甲硅烷基官能的聚异丁烯的方法，所述方法包括在路易斯酸存在下使（A）异丁烯反应;（B）式（C）的引发剂，苯乙烯基 式中R的共聚单体选自H或甲基，R'是具有1至6个碳原子的二价非芳族烃基，R“独立地选自具有1至10个碳原子的烷基或具有6个 至10个碳原子，R“是具有2至6个碳原子的二价非芳族烃基，X独立地为卤素基团，Y为卤素且n独立地为1,2或3。