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    Chromate-Free Surface Treated Metal Material with Excellent Corrosion Resistance, Heat Resistance, Fingermark Resistance, Conductivity, Coatability, and Blackening Resistance at the Time of Working
    2.
    发明申请
    Chromate-Free Surface Treated Metal Material with Excellent Corrosion Resistance, Heat Resistance, Fingermark Resistance, Conductivity, Coatability, and Blackening Resistance at the Time of Working 审中-公开
    无铬酸盐表面处理金属材料，具有优良的耐腐蚀性，耐热性，抗水印性，电导率，可涂敷性和耐黑化性

    公开(公告)号：US20090110921A1

    公开(公告)日：2009-04-30

    申请号：US11989096

    申请日：2006-07-14

    申请人： Taihei Kaneto ,  Atsushi Morishita ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Shinji Nomura ,  Hidehiro Yamaguchi

    发明人： Taihei Kaneto ,  Atsushi Morishita ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Shinji Nomura ,  Hidehiro Yamaguchi

    IPC分类号： B32B9/04

    CPC分类号： C23C22/44 ,  C08G77/14 ,  C08G77/26 ,  C09D5/084 ,  C23C2222/20 ,  Y10T428/273 ,  Y10T428/31663

    摘要： The present invention provides a metal material given a chrome-free surface treatment satisfying all of the requirements of corrosion resistance, heat resistance, fingermark resistance, conductivity, coatability, and blackening resistance at the time of working, which was difficult to achieve with conventional chromate-free technology. The chromate-free surface treated metal material of the present invention is comprised of a metal material on the surface of which is coated and dried an aqueous metal surface treatment agent comprising an organic silicon compound (W), obtained by blending a silane coupling agent (A) containing one amino group in its molecule and a silane coupling agent (B) containing one glycidyl group in its molecule in a solid weight ratio [(A)/(B)] of 0.5 to 1.7, at least one type of fluorocompound (X) selected from fluorotitanic acid or fluorozirconic acid, phosphoric acid (Y), and a vanadium compound (Z) so as to form a composite coating containing the different ingredients.

    摘要翻译： 本发明提供了赋予无铬表面处理的金属材料，其满足了常规铬酸盐难以达到的耐蚀性，耐热性，防水印性，导电性，可涂布性和耐黑变性的所有要求 免费技术。 本发明的无铬酸盐表面处理金属材料由金属材料构成，其表面涂覆并干燥含有金属表面处理剂，其含有有机硅化合物（W），其通过将硅烷偶联剂（ A），其分子中含有一个氨基和其分子中含有一个缩水甘油基的硅烷偶联剂（B），其固体重量比[（A）/（B）]为0.5至1.7，至少一种氟化合物 X）选自氟钛酸或氟锆酸，磷酸（Y）和钒化合物（Z），以形成含有不同成分的复合涂层。

    SURFACE-TREATED METAL MATERIAL AND AQUEOUS METAL SURFACE-TREATMENT AGENT
    3.
    发明申请
    SURFACE-TREATED METAL MATERIAL AND AQUEOUS METAL SURFACE-TREATMENT AGENT 审中-公开
    表面处理金属材料和水性金属表面处理剂

    公开(公告)号：US20140050939A1

    公开(公告)日：2014-02-20

    申请号：US14113502

    申请日：2012-04-26

    申请人： Atsushi Morishita ,  Taihei Kaneto ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Hidehiro Yamaguchi ,  Shinji Nomura

    发明人： Atsushi Morishita ,  Taihei Kaneto ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Hidehiro Yamaguchi ,  Shinji Nomura

    IPC分类号： C09D7/12

    CPC分类号： C09D7/63 ,  C23C22/361 ,  C23C22/44 ,  C23C2222/20 ,  Y10T428/12569 ,  Y10T428/273 ,  Y10T428/31663

    摘要： A surface-treated metal material of the present invention has a composite film on the surface of a metal material. The composite film includes an organic silicon compound (W) having cyclic siloxane bonds, at least one metal compound (X) selected from a group consisting of a titanium compound and a zirconium compound, a phosphate compound (Y) and a fluorine compound (Z). In each of the components of the composite film, the ratio of XS/WS is from 0.06 to 0.16, where WS is a solid mass of Si derived from the organic silicon compound (W) and XS is a solid mass of at least one metal component selected from a group consisting of Ti and Zr included in the metal compound (X); the ratio of YS/WS is from 0.15 to 0.31, where WS is the solid mass of Si and YS is a solid mass of P derived from the phosphate compound (Y); and the ratio of ZS/WS is from 0.08 to 0.50, where WS is the solid mass of Si and ZS is a solid mass of F derived from the fluorine compound (Z).

    摘要翻译： 本发明的表面处理金属材料在金属材料的表面具有复合膜。 复合膜包括具有环状硅氧烷键的有机硅化合物（W），选自由钛化合物和锆化合物组成的组中的至少一种金属化合物（X），磷化合物（Y）和氟化合物（Z ）。 在复合膜的每个组分中，XS / WS的比例为0.06至0.16，其中WS是来自有机硅化合物（W）的Si的固体质量，XS是至少一种金属的固体质量 选自金属化合物（X）中所含的由Ti和Zr组成的组的组分; YS / WS的比例为0.15〜0.31，其中WS是Si的固体质量，YS是来自磷酸盐化合物（Y）的P的固体质量; 并且ZS / WS的比例为0.08〜0.50，其中WS为Si的固体质量，ZS为来自氟化合物（Z）的F的固体质量。

    SURFACE-TREATED METAL MATERIAL AND PRODUCING METHOD THEREOF
    4.
    发明申请
    SURFACE-TREATED METAL MATERIAL AND PRODUCING METHOD THEREOF 有权
    表面处理金属材料及其制备方法

    公开(公告)号：US20100003529A1

    公开(公告)日：2010-01-07

    申请号：US12312429

    申请日：2007-11-14

    申请人： Ikuo Kikuchi ,  Kimitaka Hayashi ,  Yoshio Kimata ,  Atsushi Morishita ,  Taihei Kanetou ,  Shinji Nomura ,  Hidehiro Yamaguchi

    发明人： Ikuo Kikuchi ,  Kimitaka Hayashi ,  Yoshio Kimata ,  Atsushi Morishita ,  Taihei Kanetou ,  Shinji Nomura ,  Hidehiro Yamaguchi

    IPC分类号： B32B15/04 ,  B05D3/02

    CPC分类号： C23C22/44 ,  C23C2222/20 ,  Y10T428/254 ,  Y10T428/273

    摘要： This surface-treated metal material includes a composite film obtained by applying a metal surface treatment agent on a surface of a metal material and drying the metal surface treatment agent, the metal surface treatment agent containing: an organic silicon compound (W) obtained by combining a silane coupling agent (A) containing one amino group in a molecule and one glycidyl group in a molecule, at a solid content mass ratio [(A)/(B)] of 0.7 to 1.7; at least one kind of fluorine compound (X) selected from titanium hydrofluoric acid and zirconium hydrofluoric acid; a phosphoric acid (Y); a vanadium compound (Z); and at least one kind of lubricant (J).

    摘要翻译： 该表面处理金属材料包括通过在金属材料的表面上施加金属表面处理剂并干燥金属表面处理剂而获得的复合膜，所述金属表面处理剂包含：通过组合获得的有机硅化合物（W） （A）/（B）]为0.7〜1.7的分子中含有一个氨基，分子内含有一个缩水甘油基的硅烷偶联剂（A） 选自氢氟酸钛和氢氟酸锆中的至少一种氟化合物（X）; 磷酸（Y）; 钒化合物（Z）; 和至少一种润滑剂（J）。

    REPLENISHER AND METHOD FOR PRODUCING SURFACE-TREATED STEEL SHEET
    6.
    发明申请
    REPLENISHER AND METHOD FOR PRODUCING SURFACE-TREATED STEEL SHEET 有权
    表面处理钢板的制造方法及其制造方法

    公开(公告)号：US20150021192A1

    公开(公告)日：2015-01-22

    申请号：US14361143

    申请日：2011-11-30

    申请人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

    发明人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

    IPC分类号： C25D9/10 ,  C25D21/18 ,  C25D11/00

    CPC分类号： C25D9/10 ,  C25D9/08 ,  C25D11/00 ,  C25D21/18

    摘要： The purpose of the present invention is to provide a replenisher which is capable of supplying Zr ions to a metal surface treatment solution, while suppressing an increase in the HF concentration in the metal surface treatment solution, so that a chemical conversion coating film can be continuously formed on a steel sheet by electrolysis. A replenisher of the present invention is a replenisher which is used for the purpose of supplying zirconium ions to a metal surface treatment solution that contains zirconium ions and fluorine ions, and the replenisher contains (A) zirconium hydrofluoric acid or a salt thereof and/or (B) hydrofluoric acid or a salt thereof and (C) a fluorine-free zirconium compound. The total concentration (g/l) of zirconium ions derived from the components (A) and (C) is 20 or more, and the ratio of the total molar amount (MF) of the fluorine ions derived from the components (A) and (B) relative to the total molar amount (MZr) of the zirconium ions derived from the components (A) and (C), namely MF/MZr is 0.01 or more but less than 4.00.

    摘要翻译： 本发明的目的是提供一种能够在抑制金属表面处理溶液中的HF浓度增加的同时向金属表面处理溶液供给Zr离子的补充剂，从而能够连续地进行化学转化覆膜 通过电解在钢板上形成。 本发明的补充剂是用于将锆离子供给到含有锆离子和氟离子的金属表面处理溶液中的补充剂，补充剂含有（A）氢氟酸锆或其盐和/或 （B）氢氟酸或其盐和（C）无氟锆化合物。 从（A）成分和（C）成分得到的锆离子的总浓度（g / l）为20以上，来自（A）成分的氟离子的总摩尔量（MF） （A）和（C）衍生的锆离子的总摩尔量（MZr），即MF / MZr为0.01以上且小于4.00。

    Replenisher and method for producing surface-treated steel sheet
    8.
    发明授权
    Replenisher and method for producing surface-treated steel sheet 有权
    表面处理钢板的补充剂和方法

    公开(公告)号：US09284657B2

    公开(公告)日：2016-03-15

    申请号：US14361143

    申请日：2011-11-30

    申请人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

    发明人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

    IPC分类号： C25D9/10 ,  C25D11/00 ,  C25D9/08 ,  C25D21/18

    CPC分类号： C25D9/10 ,  C25D9/08 ,  C25D11/00 ,  C25D21/18

    摘要： A replenisher which is capable of supplying Zr ions to a metal surface treatment solution, while suppressing an increase in the HF concentration in the metal surface treatment solution, so that a chemical conversion coating film can be continuously formed on a steel sheet by electrolysis and contains (A) zirconium hydrofluoric acid or a salt thereof and/or (B) hydrofluoric acid or a salt thereof and (C) a fluorine-free zirconium compound. The total concentration (g/l) of zirconium ions derived from the components (A) and (C) is 20 or more, and the ratio of the total molar amount (MF) of the fluorine ions derived from the components (A) and (B) relative to the total molar amount (MZr) of the zirconium ions derived from the components (A) and (C), namely MF/MZr is 0.01 or more but less than 4.00.

    摘要翻译： 能够在金属表面处理液中抑制金属表面处理液中的HF浓度上升的同时能够向金属表面处理液供给Zr离子的补充剂，能够通过电解在钢板上连续地形成化学转化膜， （A）氢氟酸锆或其盐和/或（B）氢氟酸或其盐和（C）无氟锆化合物。 从（A）成分和（C）成分得到的锆离子的总浓度（g / l）为20以上，来自（A）成分的氟离子的总摩尔量（MF） （A）和（C）衍生的锆离子的总摩尔量（MZr），即MF / MZr为0.01以上且小于4.00。

    MODIFIED POLYVINYL ALCOHOL, MODIFIED POLYVINYL ACETAL AND CERAMIC SLURRY COMPOSITION
    9.
    发明申请
    MODIFIED POLYVINYL ALCOHOL, MODIFIED POLYVINYL ACETAL AND CERAMIC SLURRY COMPOSITION 审中-公开
    改性聚乙烯醇，改性聚乙烯醇和陶瓷浆料组合物

    公开(公告)号：US20130197154A1

    公开(公告)日：2013-08-01

    申请号：US13824498

    申请日：2011-09-16

    申请人： Hidehiro Yamaguchi ,  Yuki Ishikawa ,  Yasuharu Nagai

    发明人： Hidehiro Yamaguchi ,  Yuki Ishikawa ,  Yasuharu Nagai

    IPC分类号： C08F116/06

    CPC分类号： C08F116/06 ,  C04B35/4682 ,  C04B35/63416 ,  C04B35/6342 ,  C04B2235/5445 ,  C04B2235/6025 ,  C08F8/12 ,  C08F8/28 ,  C08F8/50 ,  C08F216/38 ,  C08K3/00 ,  C08F16/06

    摘要： The present invention provides a modified polyvinyl alcohol enabling to produce polyvinyl acetal that is excellent in solubility in a solvent even with a low degree of polymerization while hardly causing reaction inhibition, coloring, and particle coarsening, and a method for producing the modified polyvinyl alcohol. The present invention also provides a modified polyvinyl acetal that is excellent in solubility in a solvent even with a low degree of polymerization, and has high elasticity, mechanical strength, and a film forming property. The present invention further provides a method for producing the modified polyvinyl acetal, a polyvinyl acetal film produced from the modified polyvinyl acetal, a method for producing the polyvinyl acetal film, a ceramic slurry composition, a method for producing the ceramic slurry composition, and a ceramic green sheet. The present invention is a modified polyvinyl alcohol including at least one functional group selected from the group consisting of hydroxyl, aldehyde, carboxyl, and lactone ring groups at a molecular end, and having a degree of saponification of 99.95 mol % or higher and a 1,2-glycol bond content of 1.4 mol % or lower.

    摘要翻译： 本发明提供一种改性聚乙烯醇，其能够生产聚合物缩醛，即使在低聚合反应时溶剂性也优异，同时几乎不引起反应抑制，着色和颗粒粗化，以及改性聚乙烯醇的制备方法。 本发明还提供即使在低聚合度下溶剂性也优异的改性聚乙烯醇缩醛，具有高弹性，机械强度和成膜性。 本发明还提供一种改性聚乙烯醇缩醛的制造方法，由改性聚乙烯醇缩醛制造的聚乙烯醇缩醛膜，聚乙烯醇缩醛膜的制造方法，陶瓷浆料组合物，陶瓷浆料组合物的制造方法以及 陶瓷绿板。 本发明是一种改性聚乙烯醇，其在分子末端具有选自羟基，醛，羧基和内酯环基中的至少一种官能团，皂化度为99.95mol％以上，1 ，2-二醇键含量为1.4摩尔％以下。

    Metal soap-coated particle article made with the same process for production lubricating coating agent and lubricating film
    10.
    发明申请
    Metal soap-coated particle article made with the same process for production lubricating coating agent and lubricating film 审中-公开
    金属皂涂颗粒制品用同样的方法制造润滑涂层剂和润滑膜

    公开(公告)号：US20050119133A1

    公开(公告)日：2005-06-02

    申请号：US10508999

    申请日：2003-03-24

    申请人： Shinobu Komiyama ,  Masayuki Yoshida ,  Hidehiro Yamaguchi

    发明人： Shinobu Komiyama ,  Masayuki Yoshida ,  Hidehiro Yamaguchi

    IPC分类号： C10M169/04 ,  C10M173/02 ,  C10M173/00

    CPC分类号： C10M169/04 ,  C10M173/02 ,  C10M2201/0623 ,  C10M2201/085 ,  C10M2201/0853 ,  C10M2207/12 ,  C10M2207/1203 ,  C10M2207/1253 ,  C10M2207/126 ,  C10N2210/02 ,  C10N2220/084 ,  C10N2230/06 ,  C10N2240/402 ,  C10N2240/405 ,  C10N2250/08 ,  C10M2207/125

    摘要： Particles each of which consists of an inorganic polyvalent metal compound as a nucleus and a coating of a metallic soap of the polyvalent metal coating the nucleus (coated particles); products and preparation processes using the particles; a lubricating coating forming agent wherein particles each of which consists of a polyvalent metal salt of phosphoric acid as a nucleus and a coating of a metallic soap of the polyvalent metal coating the surface of the nucleus are suspended in an aqueous solution of a water soluble inorganic salt and/or a water soluble organic acid salt; and a lubricating coating. The coated particles are novel particles which can be used as an ingredient of coating-type lubricating coating; are excellent in seizure resistance; can inhibit wear of tools at the time of plastic working since the friction coefficient of the surface of the particles is low; and are slow to cause pollution of working oils. Lubricating coating obtained by applying the lubricating coating forming agent onto the surface of a metallic material gives excellent cold plastic working properties, namely lubricity and seizure resistance to the metallic material.

    摘要翻译： 各自由作为核的无机多价金属化合物和包覆核（涂覆颗粒）的多价金属的金属皂的涂层组成的颗粒; 使用颗粒的产品和制备过程; 润滑涂层形成剂，其中由磷酸的多价金属盐作为核的颗粒和涂覆在核表面上的多价金属的金属皂的涂层悬浮在水溶性无机的水溶液中 盐和/或水溶性有机酸盐; 和润滑涂层。 涂层颗粒是可用作涂层型润滑涂层成分的新型颗粒; 抗癫痫发作优良; 由于颗粒表面的摩擦系数低，因此可以抑制塑料加工时工具的磨损; 造成工作油污染缓慢。 通过将润滑涂层形成剂涂覆在金属材料的表面上获得的润滑涂层具有优异的冷塑性加工性能，即对金属材料的润滑性和抗咬合性。