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1.再颁专利
公开(公告)号：USRE36892E
公开(公告)日：2000-10-03
申请号：US792303
申请日：1997-01-31
CPC分类号： H01J49/165 , G01N30/7253 , H01J49/04
摘要： .[.The invention teaches the uses of a plurality of electric fields and of orthogonal spray configurations of vaporized analyte which combine so as to operate to enhance the efficiency of analyte detection and mass analysis with a mass spectrometer by reducing vapor in the vacuum system and concomitant noise. Several embodiments of the invention are described for purposes of illustration..]. .Iadd.The invention relates to a method and apparatus for improving signal relative to noise without loss of ion collection efficiency in electrospray mass spectrometry, including liquid chromatography/mass spectrometry..Iaddend.
摘要翻译： [本发明教导了多个电场和汽化分析物的正交喷雾构型的使用，其结合起来以便通过减少真空系统中的蒸气和伴随的噪声来提高分析物检测和质谱分析的效率 。 为了说明的目的，描述了本发明的几个实施例。]本发明涉及一种用于在电喷雾质谱（包括液相色谱/质谱）中改善相对于噪声的信号而不损失离子收集效率的方法和装置。
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公开(公告)号：US06797946B2
公开(公告)日：2004-09-28
申请号：US10640138
申请日：2003-08-13
IPC分类号： H01J4926
CPC分类号： H01J49/145 , G01N30/7253 , H01J49/0431 , H01J49/165 , H01J49/168
摘要： A method and apparatus are disclosed wherein a plurality of electric fields and of orthogonal spray configurations of vaporized analyte are so combined as to enhance the efficiency of analyte detection and mass analysis. The invention provides reduced noise and increased signal sensitivity in both API electrospray and APCI operating modes.
摘要翻译： 公开了一种方法和装置，其中将多个电场和蒸发的分析物的正交喷雾构型组合，以提高分析物检测和质量分析的效率。 本发明在API电喷雾和APCI操作模式中提供降低的噪声和增加的信号灵敏度。
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公开(公告)号：US06639216B2
公开(公告)日：2003-10-28
申请号：US10265943
申请日：2002-10-07
IPC分类号： H01J4926
CPC分类号： H01J49/145 , G01N30/7253 , H01J49/0431 , H01J49/165 , H01J49/168
摘要： A method and apparatus are disclosed wherein a plurality of electric fields and of orthogonal spray configurations of vaporized analyte are so combined as to enhance the efficiency of analyte detection and mass analysis. The invention provides reduced noise and increased signal sensitivity in both API electrospray and APCI operating modes.
摘要翻译： 公开了一种方法和装置，其中将多个电场和蒸发的分析物的正交喷雾构型组合，以提高分析物检测和质量分析的效率。 本发明在API电喷雾和APCI操作模式中提供降低的噪声和增加的信号灵敏度。
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4.发明授权
公开(公告)号：US5838003A
公开(公告)日：1998-11-17
申请号：US723201
申请日：1996-09-27
CPC分类号： H01J49/165
摘要： The invention relates to an ionization chamber. More particularly, the invention relates to a mass spectrometer system having an electrospray ionization chamber incorporating an asymmetric electrode.
摘要翻译： 本发明涉及电离室。 更具体地，本发明涉及一种质谱仪系统，其具有结合有不对称电极的电喷雾离子化室。
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5.发明授权Ionization chamber and mass spectrometry system containing an easily removable and replaceable capillary 失效电离室和质谱系统包含易于拆卸和可更换的毛细管
公开(公告)号：US5736741A
公开(公告)日：1998-04-07
申请号：US688586
申请日：1996-07-30
申请人： James L. Bertsch , Kent D. Henry
发明人： James L. Bertsch , Kent D. Henry
IPC分类号： H01J49/04
CPC分类号： H01J49/0404
摘要： The invention relates to an ionization chamber. More particularly, the invention relates to a mass spectrometry system having an ionization chamber containing an easily removable and replaceable capillary.
摘要翻译： 本发明涉及电离室。 更具体地，本发明涉及一种具有电离室的质谱系统，该离子化室含有容易移除和可更换的毛细管。
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公开(公告)号：US07002146B2
公开(公告)日：2006-02-21
申请号：US10863967
申请日：2004-06-08
IPC分类号： H01J49/26
CPC分类号： G01N30/7253 , H01J27/24 , H01J49/0431 , H01J49/145 , H01J49/162
摘要： An atmospheric pressure ion source, e.g. for a mass spectrometer, that produces ions by atmospheric pressure photoionization (APPI). It includes a vaporizer, a photon source for photoionizing vapor molecules upon exit from the vaporizer, a passageway for transporting ions to, for example, a mass spectrometer system, and a means for directing the ions into the passageway. The center axis of the vaporizer and the center axis of the passageway form an angle that may be about 90 degrees. Included in the invention is a method for creating ions by atmospheric pressure photoionization along an axis and directing them into a passageway oriented at an angle to that axis.
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公开(公告)号：US06278110B1
公开(公告)日：2001-08-21
申请号：US09030676
申请日：1998-02-25
IPC分类号： H01J4426
CPC分类号： H01J49/165 , G01N30/7253
摘要： A method and apparatus wherein a plurality of electric fields and of orthogonal spray configurations of vaporized analyte are so combined as to enhance the efficiency of analyte detection and mass analysis. The invention provides reduced noise and increased signal sensitivity in both API electrospray and APCI operating modes.
摘要翻译： 一种方法和装置，其中将多个电场和蒸发的分析物的正交喷雾构型如此组合以提高分析物检测和质量分析的效率。 本发明在API电喷雾和APCI操作模式中提供降低的噪声和增加的信号灵敏度。
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8.发明授权
公开(公告)号：US5726447A
公开(公告)日：1998-03-10
申请号：US679647
申请日：1996-07-12
申请人： Edward Aisawa , James L. Bertsch , J. Michael Flanagan , Darrell L. Gourley , Val C. Robinson , Joseph Vandenburg
发明人： Edward Aisawa , James L. Bertsch , J. Michael Flanagan , Darrell L. Gourley , Val C. Robinson , Joseph Vandenburg
CPC分类号： H01J49/145
摘要： The invention relates to an ionization chamber. More particularly, the invention relates to a mass spectrometer system having an ionization chamber incorporating a corona needle removable from outside the closed ionization chamber. In preferred embodiments, the corona needle is self-positioning and engages and disengages operational or safety electrical connections.
摘要翻译： 本发明涉及电离室。 更具体地说，本发明涉及一种质谱仪系统，其具有电离室，该离子化室包含从封闭电离室外部可去除的电晕针。 在优选实施例中，电晕针是自定位的，并接合和分离操作或安全的电连接。
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公开(公告)号：US07507955B2
公开(公告)日：2009-03-24
申请号：US11395026
申请日：2006-03-31
CPC分类号： H01J49/4215 , H01J49/063 , H01J49/4255
摘要： The invention provides a multipole device for a mass spectrometer system. In general, the multipole device contains a plurality of conductive rods each comprising a conductive layer, a resistive layer, and an insulative layer between the conductive and resistive layers. The invention finds use in a variety of applications, including ion transport, ion fragmentation and ion mass filtration. Accordingly, the invention may be employed in a variety of mass spectrometer systems.
摘要翻译： 本发明提供了一种用于质谱仪系统的多极装置。 通常，多极器件包含多个导电棒，每个导电棒包括导电层，电阻层和导电层和电阻层之间的绝缘层。 本发明可用于各种应用，包括离子迁移，离子碎片和离子质量过滤。 因此，本发明可以用于各种质谱仪系统中。
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公开(公告)号：US06359275B1
公开(公告)日：2002-03-19
申请号：US09352467
申请日：1999-07-14
IPC分类号： H01J4904
CPC分类号： H01J49/0404
摘要： A conduit for conducting ions from a high pressure ion source to a mass analyzer in mass spectrometry apparatus includes a capillary tube in which the lumenal surface of the bore near at least one end is a surface of an electrically conductive material. In one embodiment the conduit is constructed of a dielectric material and has an electrically conductive coating on an end portion of the lumenal surface.
摘要翻译： 用于将离子从高压离子源引导到质谱分析仪的质谱分析仪的导管包括毛细管，其中在至少一端附近的孔的内腔表面是导电材料的表面。 在一个实施例中，导管由电介质材料构成，并且在腔表面的端部上具有导电涂层。
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