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    Stable alkyl and/or aryl silyl ether capped polyether surfactants for liquid cleaning agents containing hypohalite bleaches
    1.
    发明授权
    Stable alkyl and/or aryl silyl ether capped polyether surfactants for liquid cleaning agents containing hypohalite bleaches 失效
    用于含有次卤酸盐漂白剂的液体清洁剂的稳定的烷基和/或芳基甲硅烷基醚封端的聚醚表面活性剂

    公开(公告)号：US5073286A

    公开(公告)日：1991-12-17

    申请号：US438312

    申请日：1989-11-20

    申请人： Jay G. Otten ,  Edward J. Parker ,  Michael G. Kinnaird

    发明人： Jay G. Otten ,  Edward J. Parker ,  Michael G. Kinnaird

    IPC分类号： C07F7/18 ,  C11D1/72 ,  C11D1/82 ,  C11D3/37 ,  C11D3/395

    CPC分类号： C11D3/3956 ,  C07F7/1852 ,  C11D1/721 ,  C11D1/82 ,  C11D3/3738

    摘要： An alkyl and/or aryl silyl ether capped polyether surfactant useful in cleaning compositions. The polyether is described in conjunction with automatic dishwashing detergent composition having improved chlorine bleach stability comprising:(a) an active chlorine containing compound selected from the group consisting of chlorinated trisodium phosphate, chlorinated cyanuric acid and alkali metal salts thereof, 2,3-dichloro-5,5-dimethylhydantoin, hypochlorite bleach and mixtures thereof to yield available chlorine in an amount of from about 0.1 percent to 5 percent;(b) about 0.1 percent to 5 percent of a chlorine bleach stable nonionic surfactant having the general formula:Y[A.sub.1 O).sub.n (A.sub.2 O.sub.m (A.sub.3 O).sub.p (X).sub.q A.sub.4 ].sub.z wherein Y is the residue of an organic compound having from 1 to 8, preferably 1 to 4, reactive hydrogens as measured by the Zerevitinov determination method; z is a number from 1 to 8, A.sub.1, A.sub.2 and A.sub.3 are C.sub.2 to C.sub.4 alkylene groups, tetramethylene, and mixtures thereof; n+m+p are numbers such that the total molecular weight of the uncapped portion of the molecule is from about 500 to 25,000 and the molecular weight of the hydrophile is 5 to 35 weight percent and the molecular weight of the hydrophobe is from 65 to 95 weight percent of the total weight of the molecule; X is a hydrocarbon residue containing 2 to 30 carbon atoms, preferably the residue (--CR.sub.1 R.sub.2 CR.sub.3 R.sub.4 CR.sub.5 R.sub.6 --) where R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are H, methyl, and mixtures thereof, q is a number from 0 to 1, A.sub.4 is an Si R'.sub.3 group wherein R' is a C.sub. 1 to C.sub.30 alkyl, a C.sub.1 to C.sub.30 oxyalkyl, a C.sub.6 to C.sub.30 aryl group, and mixtures thereof; and(c) the balance water.

    摘要翻译： 用于清洁组合物的烷基和/或芳基甲硅烷基醚封端的聚醚表面活性剂。 聚醚是结合具有改进的氯漂白稳定性的自动餐具洗涤剂组合物来描述的，其包括：（a）选自氯化磷酸三钠，氯化氰尿酸及其碱金属盐，2,3-二氯 -5,5-二甲基乙内酰脲，次氯酸盐漂白剂及其混合物，以产生约0.1％至5％的有效氯; （b）约0.1％至5％的具有通式Y [A1O] n（A2Om（A3O）p（X）q A4] z的氯漂白稳定性非离子表面活性剂，其中Y是有机化合物的残基， 1至8个，优选1至4个，通过Zerevitinov测定方法测量的反应性氢; z为1至8的数，A1，A2和A3为C2至C4亚烷基，四亚甲基及其混合物; n + m + p是分子的未封端部分的总分子量为约500〜25,000，亲水体的分子量为5〜35重量％，疏水基的分子量为65〜95重量％ 分子的总重量; X是含有2至30个碳原子的烃基，优选残基（-CR 1 R 2 CR 3 R 4 CR 5 R 6 - ），其中R 1，R 2，R 3，R 4，R 5和R 6是H，甲基及其混合物，q 是0至1的数，A4是SiR'3基团，其中R'是C 1至C30烷基，C1至C30烷氧基，C6至 C30芳基及其混合物; 和（c）余量的水。

    Sterically hindered polyether polyols as chlorine bleach stable surfactants
    2.
    发明授权
    Sterically hindered polyether polyols as chlorine bleach stable surfactants 失效
    作为氯漂白剂稳定的表面活性剂

    公开(公告)号：US4913833A

    公开(公告)日：1990-04-03

    申请号：US204634

    申请日：1988-06-09

    申请人： Jay G. Otten ,  Michael G. Kinnaird ,  Ronald E. Greenough ,  Edward J. Parker

    发明人： Jay G. Otten ,  Michael G. Kinnaird ,  Ronald E. Greenough ,  Edward J. Parker

    IPC分类号： C11D17/00 ,  C08G65/32 ,  C08G65/48 ,  C11D1/722 ,  C11D3/395

    CPC分类号： C11D3/3956 ,  C11D1/722

    摘要： Cleaning compositions, especially liquid detergent compositions containing chlorine bleach, are disclosed. The compositions include a chlorine bleach stable nonionic surfactant which is a mixture of the formulay[A.sub.1 O).sub.n (A.sub.2 O).sub.n' (A.sub.3 O).sub.n' H].sub.mwherein A.sub.1 and A.sub.2 are C.sub.2 -C.sub.4 alkylene groups, tetramethylene and mixtures thereof, A.sub.3 is a sterically hindered C.sub.4 -C.sub.30 alkylene group, C.sub.4 -C.sub.30 arylalkylene group, and mixtures thereof, n+n'=a value such that the total molecular weight of the uncapped portion of the molecule is about 500 to 25,000, n" is a number from 1 to 8, m is a number from 1 to 8, and Y is the residue of an organic compound having from about 1 to 30 carbon atoms and at least 1 reactive hydrogen atom. The surfactant has a hydrophilic content of from about 5 to 40 weight percent.

    摘要翻译： 公开了清洁组合物，特别是含有氯漂白剂的液体洗涤剂组合物。 该组合物包括氯化漂白稳定的非离子表面活性剂，其为式y [A1O] n（A2O）n'（A3O）n'H] m的混合物，其中A1和A2为C2-C4亚烷基，四亚甲基及其混合物， A3是空间位阻C4-C30亚烷基，C4-C30芳基亚烷基及其混合物，n + n'=使得分子的未封端部分的总分子量为约500至25,000，n“ 是1至8的数，m是1至8的数，Y是具有约1至30个碳原子和至少1个反应性氢原子的有机化合物的残基。 表面活性剂具有约5至40重量％的亲水含量。

    Method of Cleaning Rubber from Runways that is Alkylphenol-Free
    5.
    发明申请
    Method of Cleaning Rubber from Runways that is Alkylphenol-Free 审中-公开
    从不含烷基酚的跑道清洗橡胶的方法

    公开(公告)号：US20130269726A1

    公开(公告)日：2013-10-17

    申请号：US13446029

    申请日：2012-04-13

    申请人： Michael G. Kinnaird ,  David L. Rigsbee

    发明人： Michael G. Kinnaird ,  David L. Rigsbee

    IPC分类号： B08B1/00

    CPC分类号： C11D1/72 ,  C11D1/34 ,  C11D1/83 ,  C11D3/3418 ,  C11D3/43 ,  C11D11/0023

    摘要： This invention relates to a method of cleaning rubber off of rubber-soiled runways that is free from the usual alkylphenol alkoxylates, which are becoming increasingly scrutinized and discouraged due to environmental considerations. Instead, it is surprisingly found that linear alcohol alkoxylates provide cleaning compositions that are actually more effective, while simultaneously providing an enhanced environmental profile to the formulation.

    摘要翻译： 本发明涉及一种从橡胶污染的跑道上清除橡胶的方法，该跑道不含常见的烷基酚烷氧基化物，由于环境考虑，这些烷基酚逐渐变得越来越多地受到关注和劝阻。 相反，令人惊讶地发现线性醇烷氧基化物提供实际上更有效的清洁组合物，同时为制剂提供增强的环境特征。

    Solubilization of salts of pyridine-2-thiol-1-oxide
    7.
    发明授权
    Solubilization of salts of pyridine-2-thiol-1-oxide 失效
    吡啶-2-硫醇-1-氧化物盐的溶解

    公开(公告)号：US4835149A

    公开(公告)日：1989-05-30

    申请号：US930009

    申请日：1986-11-13

    申请人： John J. Burke ,  Robert R. Roelofs ,  Michael G. Kinnaird

    发明人： John J. Burke ,  Robert R. Roelofs ,  Michael G. Kinnaird

    IPC分类号： A01N43/40 ,  A61K8/44 ,  A61K8/49 ,  A61K31/14 ,  A61K31/555 ,  A61K47/00 ,  A61K47/18 ,  A61Q5/02 ,  A61Q17/00 ,  C11D3/28

    CPC分类号： A61K8/4933 ,  A61K8/44 ,  A61Q17/005 ,  A61Q5/02 ,  Y10S514/852 ,  Y10S514/864

    摘要： A composition of matter comprising a metal pyrethione salt, an amine having the following formulaH.sub.x N((CH.sub.2).sub.y X).sub.zwherein x is 0 to 2, y is 1 to 3, z is 1 to 3, x+z=3 and X is H, OH or COOH and an aminocarboxylic acid selected from the group consisting of ethylenediaminetetraaceteic acid, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, N(hydroxide ethyl) ethylenediaminetriacetic acid, cyclohexanediamine tetracetic acid, triethanolamine ethylenediamine tetracetic acid and acids having the formulas: ##STR1## where X is H, lithium, sodium, potassium, cesium, magnesium, calcium, nickel, copper, zinc and mixtures thereof. A is H or COOX and n is an integer or zero.

    摘要翻译： 包含金属pyththione盐的物质组合物，具有下式H x N（（CH 2）y X）z的胺，其中x为0至2，y为1至3，z为1至3，x + z = 3，X 是H，OH或COOH和选自乙二胺四乙酸，二亚乙基三胺五乙酸，次氮基三乙酸，N（氢氧化乙基乙基）乙二胺三乙酸，环己烷二胺四乙酸，三乙醇胺乙二胺四乙酸和具有下列结构式的酸的氨基羧酸： 其中X是H，锂，钠，钾，铯，镁，钙，镍，铜，锌及其混合物。 A是H或COOX，n是整数或零。