公开(公告)号：US10086365B2

公开(公告)日：2018-10-02

申请号：US12198459

申请日：2008-08-26

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard A. Bley ,  Jesse W. Taylor ,  Sara L. Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard A. Bley ,  Jesse W. Taylor ,  Sara L. Rolfe ,  Harold A. Wright

IPC分类号： B01J37/03 ,  B01J23/78 ,  B01J21/00 ,  C10G2/00 ,  B01J21/08

摘要： A method of strengthening a precipitated unsupported iron catalyst by: preparing a precipitated unsupported iron catalyst containing copper and potassium; adding a solution comprising a structural promoter to the previously prepared catalyst; drying the mixture; and calcining the dried catalyst. A method for preparing an iron catalyst, the method comprising: precipitating a catalyst precursor comprising iron phases selected from hydroxides, oxides, and carbonates; adding a promoter to the catalyst precursor to yield a promoted precursor; drying the promoted precursor to yield dried catalyst; and calcining the dried catalyst, wherein the catalyst further comprises copper and potassium. A method of preparing a strengthened precipitated iron catalyst comprising: co-precipitating iron, copper, magnesium, and aluminum; washing the precipitate; alkalizing the precipitate; and drying the precipitate to yield a dried catalyst precursor. The dried catalyst precursor may be calcined and treated with a gas comprising carbon monoxide.

公开(公告)号：US20110313061A1

公开(公告)日：2011-12-22

申请号：US12984902

申请日：2011-01-05

申请人： Harold A. Wright ,  Belma Demirel ,  Sergio Mohedas ,  Bahman Rejai ,  Ray Huang ,  Deena Ferdous ,  Jesse W. Taylor ,  Dawid J. Duvenhage ,  Sara L. Rolfe

发明人： Harold A. Wright ,  Belma Demirel ,  Sergio Mohedas ,  Bahman Rejai ,  Ray Huang ,  Deena Ferdous ,  Jesse W. Taylor ,  Dawid J. Duvenhage ,  Sara L. Rolfe

IPC分类号： B01J8/18 ,  C07C1/04 ,  B01J37/18 ,  B01J31/02 ,  B01J37/16

CPC分类号： B01J8/006 ,  B01J8/18 ,  B01J8/1809 ,  B01J23/745 ,  B01J33/00 ,  B01J35/023 ,  B01J37/0045 ,  B01J37/18 ,  C10G2/32 ,  C10G2/33 ,  C10G2/332 ,  C10G2300/703

摘要： A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.

摘要翻译： 通过将喷雾干燥的催化剂颗粒与蜡组合来制备喷雾干燥的催化剂的方法，使喷雾干燥的催化剂颗粒用蜡涂覆，产生蜡涂覆的催化剂颗粒，并使蜡涂覆的催化剂成形以提供成形的涂蜡催化剂。 通过使催化剂颗粒与活化容器中的还原气体接触以产生活化的催化剂来活化含有氧化物的费 - 托催化剂颗粒的方法，其中在不存在液体介质的条件下进行接触。 一种用于活化费 - 托催化剂的系统，其包含活化反应器，所述活化反应器配置成在没有液体介质的情况下将活化气体引入费 - 托催化剂的固定或流化床，以及至少一个分离装置，其被配置为分离气流 包括夹带的催化剂细粒，其具有低于来自活化反应器的所需截留尺寸的平均粒度。

公开(公告)号：US07879756B2

公开(公告)日：2011-02-01

申请号：US12189424

申请日：2008-08-11

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US08530366B2

公开(公告)日：2013-09-10

申请号：US12984902

申请日：2011-01-05

申请人： Harold A. Wright ,  Belma Demirel ,  Sergio Mohedas ,  Bahman Rejai ,  Ray Huang ,  Deena Ferdous ,  Jesse W. Taylor ,  Dawid J. Duvenhage ,  Sara L. Rolfe

发明人： Harold A. Wright ,  Belma Demirel ,  Sergio Mohedas ,  Bahman Rejai ,  Ray Huang ,  Deena Ferdous ,  Jesse W. Taylor ,  Dawid J. Duvenhage ,  Sara L. Rolfe

IPC分类号： B01J20/34 ,  C07C27/00

CPC分类号： B01J8/006 ,  B01J8/18 ,  B01J8/1809 ,  B01J23/745 ,  B01J33/00 ,  B01J35/023 ,  B01J37/0045 ,  B01J37/18 ,  C10G2/32 ,  C10G2/33 ,  C10G2/332 ,  C10G2300/703

摘要： A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.

摘要翻译： 通过将喷雾干燥的催化剂颗粒与蜡组合来制备喷雾干燥的催化剂的方法，使喷雾干燥的催化剂颗粒用蜡涂覆，产生蜡涂覆的催化剂颗粒，并使蜡涂覆的催化剂成形以提供成形的涂蜡催化剂。 通过使催化剂颗粒与活化容器中的还原气体接触以产生活化的催化剂来活化含有氧化物的费 - 托催化剂颗粒的方法，其中在不存在液体介质的条件下进行接触。 一种用于活化费 - 托催化剂的系统，其包含活化反应器，所述活化反应器配置成在没有液体介质的情况下将活化气体引入费 - 托催化剂的固定或流化床，以及至少一个分离装置，其被配置为分离气流 包括夹带的催化剂细粒，其具有低于来自活化反应器的所需截留尺寸的平均粒度。

公开(公告)号：US20130034464A1

公开(公告)日：2013-02-07

申请号：US13558898

申请日：2012-07-26

申请人： Jesse W. Taylor

发明人： Jesse W. Taylor

IPC分类号： A62D3/30 ,  B01D53/30 ,  C02F1/50 ,  C02F1/58 ,  A61L9/00 ,  B01J19/00

CPC分类号： B01D53/02 ,  B01D53/82 ,  B01D2251/106 ,  B01D2251/108 ,  B01D2251/302 ,  B01D2251/304 ,  B01D2251/404 ,  B01D2251/70 ,  B01D2257/91 ,  B01D2257/93 ,  B01D2258/06 ,  B01D2259/4583 ,  C02F1/50

摘要： Filtration devices, methods, and systems comprising a decontamination filtration medium. The filtration medium comprises a remotely-triggered decontamination material stored in microcapsules that are embedded in or attached to a filter element. The microcapsules contain a decontamination agent that will detoxify one or more toxins, including but not limited to chemical and biological warfare agents, and industrial materials and chemicals, among other things. The microcapsules can be locally or remotely triggered to release the detoxifying agent by a triggering agent such as light, electrical potential, pressure, temperature, or other methods. One method of use of the filtration device comprises the following: when a target toxin is detected in the vicinity of the device, the microcapsules are actively triggered to release the detoxifying agent, thereby neutralizing the toxic agent.

摘要翻译： 过滤装置，方法和系统包括净化过滤介质。 过滤介质包括存储在微胶囊中的远程触发的去污材料，其被嵌入或附着到过滤元件上。 微胶囊含有去污剂，其将使一种或多种毒素解毒，包括但不限于化学和生物战剂，以及工业材料和化学品等。 微胶囊可以局部或远程触发，以通过引发剂如光，电势，压力，温度或其它方法释放解毒剂。 使用过滤装置的一种方法包括：当在装置附近检测到目标毒素时，主动触发微胶囊释放解毒剂，从而中和毒性剂。

公开(公告)号：US20100152036A1

公开(公告)日：2010-06-17

申请号：US12713358

申请日：2010-02-26

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： B01J23/745 ,  B01J23/72

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US20090111684A1

公开(公告)日：2009-04-30

申请号：US12272960

申请日：2008-11-18

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

IPC分类号： B01J23/72 ,  B01J21/06 ,  B01J27/20 ,  B01J31/28 ,  B01J23/02

CPC分类号： B01J37/18 ,  B01J21/08 ,  B01J23/745 ,  B01J23/78 ,  B01J37/03 ,  C10G2/332 ,  C10G2300/4006 ,  C10G2300/703

摘要： A method of activating an iron Fischer-Tropsch catalyst by introducing an inert gas into a reactor comprising a slurry of the catalyst at a first temperature, increasing the reactor temperature from the first temperature to a second temperature at a first ramp rate, wherein the second temperature is in the range of from about 150° C. to 250° C., introducing synthesis gas having a ratio of H2:CO to the reactor at a space velocity, and increasing the reactor temperature from the second temperature to a third temperature at a second ramp rate, wherein the third temperature is in the range of from about 270° C. to 300° C. The iron Fischer-Tropsch catalyst may be a precipitated unsupported iron catalyst, production of which is also provided.

摘要翻译： 一种通过将惰性气体引入反应器中来激活铁费 - 托催化剂的方法，所述反应器包括在第一温度下的催化剂浆料，以第一升高速率将反应器温度从第一温度升至第二温度，其中第二 温度在约150℃至250℃的范围内，以空间速度将具有H 2 :CO比例的合成气引入反应器，并将反应器温度从第二温度升至第三温度 第二斜坡率，其中第三温度在约270℃至300℃的范围内。费 - 托催化剂铁可以是沉淀的未负载的铁催化剂，也提供其生产。

公开(公告)号：US20090069451A1

公开(公告)日：2009-03-12

申请号：US12189424

申请日：2008-08-11

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： C07C27/06 ,  B01J23/72

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US07988766B2

公开(公告)日：2011-08-02

申请号：US12257811

申请日：2008-10-24

申请人： James H. White ,  Jesse W. Taylor

发明人： James H. White ,  Jesse W. Taylor

IPC分类号： B01D53/04

CPC分类号： B01J20/186 ,  B01D15/00 ,  B01D53/02 ,  B01D2253/112 ,  B01D2257/40 ,  B01D2257/406 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/602 ,  B01D2257/7022 ,  B01D2257/708 ,  B01D2259/40086 ,  B01D2259/4009 ,  B01D2259/40092 ,  B01D2259/816 ,  B01D2259/818 ,  B01J20/06 ,  B01J20/28007 ,  B01J20/28057 ,  B01J20/28083 ,  B01J20/28097 ,  B01J20/3078 ,  B01J20/3433 ,  B82Y30/00 ,  Y02C10/08 ,  Y02P30/42

摘要： Provided herein are adsorbents and methods of using the adsorbents to at least partially remove one or more adsorbates. In an aspect, an adsorbate within a phase is at least partially removed by providing an adsorbent material and contacting the adsorbent material with the phase having an adsorbate, to at least partially remove the adsorbate. Various adsorbents are disclosed having the chemical formula RE1-x-y-zBxB′yB″zOw, where RE is RE is a rare earth metal, B is a trivalent metal ion, B′ is a transition metal ion or an alkaline earth element, B″ is a transition metal ion, 0≦x≦0.25, 0≦y≦0.95, 0≦z≦0.75, w is a number which results in charge balance, and x+y+z

摘要翻译： 本文提供吸附剂和使用吸附剂至少部分去除一种或多种吸附物质的方法。 在一个方面，通过提供吸附材料并使吸附剂材料与具有被吸附物的相位接触，至少部分地除去相中的吸附物，以至少部分地除去被吸附物。 公开了具有化学式RE1-xy-zBxB'yB“zOw的各种吸附剂，其中RE是稀土金属，B是三价金属离子，B'是过渡金属离子或碱土金属元素，B” 是过渡金属离子，0＆nlE; x＆nlE; 0.25,0和nlE; y＆nlE; 0.95,0和nlE; z＆nlE; 0.75，w是导致电荷平衡的数，x + y + z <1。

公开(公告)号：US07915193B2

公开(公告)日：2011-03-29

申请号：US12272960

申请日：2008-11-18

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

IPC分类号： B01J23/42

CPC分类号： B01J37/18 ,  B01J21/08 ,  B01J23/745 ,  B01J23/78 ,  B01J37/03 ,  C10G2/332 ,  C10G2300/4006 ,  C10G2300/703

摘要： A method of activating an iron Fischer-Tropsch catalyst by introducing an inert gas into a reactor comprising a slurry of the catalyst at a first temperature, increasing the reactor temperature from the first temperature to a second temperature at a first ramp rate, wherein the second temperature is in the range of from about 150° C. to 250° C., introducing synthesis gas having a ratio of H2:CO to the reactor at a space velocity, and increasing the reactor temperature from the second temperature to a third temperature at a second ramp rate, wherein the third temperature is in the range of from about 270° C. to 300° C. The iron Fischer-Tropsch catalyst may be a precipitated unsupported iron catalyst, production of which is also provided.

摘要翻译： 一种通过将惰性气体引入反应器中来激活铁费 - 托催化剂的方法，所述反应器包括在第一温度下的催化剂浆料，以第一升高速率将反应器温度从第一温度升至第二温度，其中第二 温度在约150℃至250℃的范围内，以空间速度将具有H 2 :CO比例的合成气引入反应器，并将反应器温度从第二温度升至第三温度 第二斜坡率，其中第三温度在约270℃至300℃的范围内。费 - 托催化剂铁可以是沉淀的未负载的铁催化剂，也提供其生产。