摘要:
Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.
摘要:
A packaged battery (60) is provided having a thin film lithium battery cell (62) sealed with a packaging foil or layer (67). The battery cell (60) includes a substrate (61) and an active cell (62) with an anode current collector (65) and a cathode current collector (64). The packaged battery is produced by heat sealing a packaging foil (67) to the exterior surfaces of the active cell (62).
摘要:
Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.
摘要:
The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.
摘要:
Methods for making composite anodes, such as macroporous composite anodes, are disclosed. Embodiments of the methods may include forming a tape from a slurry including a substrate metal precursor, an anode active material, a pore-forming agent, a binder, and a solvent. A laminated structure may be prepared from the tape and sintered to produce a porous structure, such as a macroporous structure. The macroporous structure may be heated to reduce a substrate metal precursor and/or anode active material. Macroporous composite anodes formed by some embodiments of the disclosed methods comprise a porous metal and an anode active material, wherein the anode active material is both externally and internally incorporated throughout and on the surface of the macroporous structure.
摘要:
A packaged battery (10) and method of producing such is provided having a thin film lithium battery cell (11) sealably encased within a packaging layer (12). The battery cell (11) includes a substrate (13), an anode (16), an electrolyte (15), a cathode (14), a passivation layer (19), an anode current collector (17) and a cathode current collector (18). The packaged battery is produced by heat sealing a packaging foil (21, 22) to the exterior surfaces of the battery cell (11).
摘要:
The slitting assembly includes a grinding wheel with a wide flat grinding face for first cutting a multilayer sheet of soft and compressible, electronic device material, such as lithium-ion polymer material for a uni-cell battery, to a first depth and includes a cutting wheel with a blade-like edge for completing the slit by cutting through uncut layers of the multilayer sheet. The grinding face has a width of at least the thickness of the multilayer sheet, and in practice, the depth of the cut is preferably one half the sheet thickness, which in a uni-cell battery sheet is midway through a separator layer. The grinding wheel is positioned to apply cutting forces to the multilayer sheet in a direction that is substantially parallel to the feed direction to control the application of compressive forces that may compress the soft sheet material and if uncontrolled, may create short circuits between electrically conductive layers. Further, the unique combination of cut width and cut depth function to prevent shorting of the electrically conductive sheet layers during the second cutting by the blade-like edge of the cutting wheel which is completed by resiliently forcing the edge through the final layers of the sheet. In another preferred embodiment, a single, multistage or stepped grinding stone is utilized in the slitting assembly to concurrently grind, and provide lateral support to maintain separation of, multiple layers of a multilayer sheet of electronic device material such as material for a bi-cell lithium ion polymer battery. Alternatively, a single, sloped or angled grinding wheel may be included to provide two grinding faces that establish a grinding angle sufficient to enable concurrent grinding of multiple layers of soft electronic material without compressing or pinching the layers into a shorting contact. Furthermore, a more symmetric cutting or slitting can be made by a slitting assembly having two grinding wheels to concurrently slit a soft, multilayered sheet from opposing sides of the sheet.
摘要:
The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.
摘要:
A solid-state lithium ion battery is disclosed. The battery includes an anode containing an anode active material. The battery also includes a cathode containing a cathode active material. The battery further includes a solid-state electrolyte material. The electrolyte material contains a salt or salt mixture with a melting point below approximately 300 degrees Celsius. The battery has an operating temperature of less than about 80 degrees Celsius.
摘要:
A rechargeable lithium-air battery (10) comprises a non-aqueous, organic-solvent-based electrolyte (16) including a lithium salt and an additive containing an alkylene group, disposed between a spaced-apart pair of a lithium anode (12) and an air cathode (14). The alkylene additive may be alkylene carbonate, alkylene siloxane, or a combination of alkylene carbonate and alkylene siloxane. The alkylene carbonate may be vinylene carbonate, butylene carbonate, or a combination of vinylene carbonate and butylene carbonate. The alkylene siloxane may be a polymerizable silane. The polymerizable silane is triacetoxyvinylsilane.