Quick removal of mercaptans from hydrocarbons
    4.
    发明授权
    Quick removal of mercaptans from hydrocarbons 有权
    快速从碳氢化合物中除去硫醇

    公开(公告)号:US08048175B2

    公开(公告)日:2011-11-01

    申请号:US12420605

    申请日:2009-04-08

    Abstract: Mercaptans and/or hydrogen sulfide (H2S) in hydrocarbons, naphthas, gasolines, and the like may be scavenged therefrom by being brought into intimate contact with a mercaptan scavenger formulation containing at least one disubstituted azodicarboxylate of the formula R1OOCN═NCOOR2, where R1 and R2 are independently alkyl groups, alkenyl groups and aromatic groups having from 1 to 18 carbon atoms. These scavengers remove mercaptans and/or H2S from hydrocarbons faster than many conventional mercaptan scavengers. An effective scavenging amount of disubstituted azodicarboxylate in the hydrocarbon fluid ranges from about 5 to about 20 parts by weight based on 1 part as sulfur of mercaptan and/or H2S.

    Abstract translation: 烃,石脑油,汽油等中的硫醇和/或硫化氢(H2S)可通过与含有至少一种式R 1 OOCN = NCOOR 2的二取代偶氮二羧酸的硫醇清除剂配方紧密接触而清除,其中R 1和 R2独立地为烷基,烯基和具有1至18个碳原子的芳基。 这些清除剂比许多常规的硫醇清除剂更快地从碳氢化合物中除去硫醇和/或硫化氢。 在烃流体中有效清除量的二取代偶氮二甲酸酯的量为约5至约20重量份,基于1份作为硫醇和/或硫化氢。

    Additives to Enhance Metal Removal in Refinery Desalting Processes
    5.
    发明申请
    Additives to Enhance Metal Removal in Refinery Desalting Processes 有权
    在炼油脱盐工艺中加强金属去除添加剂

    公开(公告)号:US20110172473A1

    公开(公告)日:2011-07-14

    申请号:US13008667

    申请日:2011-01-18

    Abstract: It has been discovered that metals can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains a demulsifier (for instance, an oxyalkylated alkyl resin and/or a crosslinked polypropylene glycol), a surfactant, a diketone and a solvent (for instance an aromatic solvent). The method may also include introducing a hydroxyl carboxylic acid and/or at least one mineral acid to reduce the pH of the desalter wash water. The method permits transfer of metals into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase. The composition is particularly useful in treating crude oil emulsions, and in removing iron therefrom.

    Abstract translation: 已经发现,通过使用含有破乳剂(例如,烷氧基化烷基树脂和/或交联聚丙二醇)的组合物,可以在乳液破乳过程中将烃类从烃相中除去或转移到水相, 表面活性剂,二酮和溶剂(例如芳族溶剂)。 该方法还可以包括引入羟基羧酸和/或至少一种无机酸以降低脱盐洗涤水的pH。 该方法允许将金属转移到水相中,很少或没有烃相载入水相。 该组合物特别可用于处理原油乳液和从其中除去铁。

    Additives for Cetane Improvement in Middle Distillate Fuels
    6.
    发明申请
    Additives for Cetane Improvement in Middle Distillate Fuels 审中-公开
    中间馏分燃料十六烷改进添加剂

    公开(公告)号:US20100325944A1

    公开(公告)日:2010-12-30

    申请号:US12793463

    申请日:2010-06-03

    Abstract: The cetane number of middle distillate fuels may be increased using an additive composition including a polymer that may be a homopolymer or copolymer of olefins, and the like, where the polymer has a weight average molecular weight ranging from about 200,000 to about 5,000,000. The additive composition also includes a free radical initiator component, which may be an alkyl nitrate such as 2-ethylhexylnitrate (2-EHN), and/or a peroxide, such as t-butyl peroxide. In one non-limiting embodiment the amount of polymer in the additive composition is greater than the free radical initiator component. A solvent is also present, which the solvent may include alcohol, an alkyl substituted phenol and/or a heavy aromatic distillate.

    Abstract translation: 中间馏分燃料的十六烷值可以使用包括可以是烯烃的均聚物或共聚物的聚合物等的添加剂组合物来提高,其中聚合物的重均分子量为约20万至约5,000,000。 添加剂组合物还包括自由基引发剂组分,其可以是硝酸烷基酯如硝酸2-乙基己酯(2-EHN)和/或过氧化物,如叔丁基过氧化物。 在一个非限制性实施方案中,添加剂组合物中的聚合物的量大于自由基引发剂组分。 还存在溶剂,溶剂可包括醇,烷基取代的苯酚和/或重芳族馏分。

    Additives to enhance metal removal in refinery desalting processes
    9.
    发明授权
    Additives to enhance metal removal in refinery desalting processes 有权
    在炼油厂脱盐过​​程中增强金属去除的添加剂

    公开(公告)号:US08372270B2

    公开(公告)日:2013-02-12

    申请号:US13008667

    申请日:2011-01-18

    Abstract: It has been discovered that metals can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains a demulsifier (for instance, an oxyalkylated alkyl resin and/or a crosslinked polypropylene glycol), a surfactant, a diketone and a solvent (for instance an aromatic solvent). The method may also include introducing a hydroxyl carboxylic acid and/or at least one mineral acid to reduce the pH of the desalter wash water. The method permits transfer of metals into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase. The composition is particularly useful in treating crude oil emulsions, and in removing iron therefrom.

    Abstract translation: 已经发现,通过使用含有破乳剂(例如,烷氧基化烷基树脂和/或交联聚丙二醇)的组合物,可以在乳液破乳过程中将烃类从烃相中除去或转移到水相, 表面活性剂,二酮和溶剂(例如芳族溶剂)。 该方法还可以包括引入羟基羧酸和/或至少一种无机酸以降低脱盐洗涤水的pH。 该方法允许将金属转移到水相中,很少或没有烃相载入水相。 该组合物特别可用于处理原油乳液和从其中除去铁。

    Fullerene-based amino acids
    10.
    发明授权
    Fullerene-based amino acids 有权
    富勒烯基氨基酸

    公开(公告)号:US08217137B2

    公开(公告)日:2012-07-10

    申请号:US10585277

    申请日:2005-01-14

    Abstract: The present invention is directed to a series of new compounds, combining the unique properties of fullerenes and bio-active amino acid residues, and to methods for making such compounds. The present invention is directed toward fullerene-based amino acids, and to amino acid residues, peptide chains, proteins, and polypeptides made from such fullerene-based amino acids. The present invention is further directed to amino acid residues, peptide chains, proteins, and polypeptides comprising such fullerene-based amino acids and into which such fullerene-based amino acids have been incorporated. Exemplary compounds have been prepared, and these compounds have been characterized and confirmed with infrared (IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, mass spectrometry (MS), etc. These new compounds, which are additions to the existing amino acid residue family, may potentially possess useful pharmaceutical application and may provide a new platform for further exploration in cancer therapy, and peptide and protein engineering.

    Abstract translation: 本发明涉及一系列新的化合物,其结合了富勒烯和生物活性氨基酸残基的独特性质,以及制备这些化合物的方法。 本发明涉及基于富勒烯的氨基酸以及由这种基于富勒烯的氨基酸制成的氨基酸残基,肽链,蛋白质和多肽。 本发明进一步涉及包含这种基于富勒烯的氨基酸的氨基酸残基,肽链,蛋白质和多肽,并且其中掺入了这种基于富勒烯的氨基酸。 已经制备了示例性化合物,并且已经用红外(IR)光谱,核磁共振(NMR)光谱,质谱(MS)等来表征和证实了这些化合物。这些新化合物是现有氨基酸残基的添加物 家族,可能潜在地拥有有用的药物应用,并可能为癌症治疗和肽和蛋白质工程的进一步探索提供新的平台。

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