NOVEL BRANCHED ALKOXYLATES
    1.
    发明申请
    NOVEL BRANCHED ALKOXYLATES 审中-公开
    新型分支烷基酯

    公开(公告)号:US20100168450A1

    公开(公告)日:2010-07-01

    申请号:US12596919

    申请日:2008-04-24

    IPC分类号: C07D301/00 C07D303/18

    摘要: Novel alkylene oxide-extended alkoxylates of a branched 1,3-dialkyl-oxy-2-propanol may be prepared by a convenient process comprising adding epichlorohydrin to a stoichiometric excess of a branched alcohol, wherein the molar ratio of branched alcohol:epichlorohydrin is at least about 3:1, preferably in the presence of a Group 1 A metal hydroxide and a phase transfer catalyst, followed by alkoxylation in the presence of an ionic catalyst. The branched alkyl chain may be saturated or unsaturated and may contain one or more heteroatoms. The repeating alkoxy units from the alkylene oxide are in the 2-position. The compositions are useful as surfactants, diluents, and the like, and may be less expensive than other branched surfactants.

    摘要翻译: 支链1,3-二烷基 - 氧-2-丙醇的新型环氧烷延展的烷氧基化物可以通过方便的方法制备,包括将表氯醇加入到化学计量过量的支链醇中,其中支链醇:表氯醇的摩尔比为 至少约3:1,优选在第1AA族金属氢氧化物和相转移催化剂存在下,然后在离子催化剂存在下进行烷氧基化。 支链烷基链可以是饱和或不饱和的,并且可以含有一个或多个杂原子。 来自环氧烷烃的重复烷氧基单元为2-位。 该组合物可用作表面活性剂,稀释剂等,并且可能比其它支链表面活性剂便宜。

    NOVEL ALKOXY-ETHERS AND ALKOXYLATES THEREOF
    2.
    发明申请
    NOVEL ALKOXY-ETHERS AND ALKOXYLATES THEREOF 审中-公开
    新的烷氧基和其烷氧基

    公开(公告)号:US20100179354A1

    公开(公告)日:2010-07-15

    申请号:US12596914

    申请日:2008-04-24

    IPC分类号: C07C41/03 C07C43/13

    摘要: Novel 1,3-dialkyloxy-2-propanol and alkoxylates thereof may be prepared in good yield by a convenient process comprising adding epichlorohydrin to a stoichiometric excess of alcohol, wherein the ratio of alcohol:epichlorohydrin is at least about 3:1, preferably in the presence of a Group 1A metal hydroxide and a phase transfer catalyst. The result shows excellent selectivity of to the 1,3-substitution positions, and the alkyl chain may be saturated or unsaturated and may contain one or more heteroatoms. The alkoxylates may include repeating alkoxy units in the 2-position. The compositions are useful as surfactants, diluents, and the like.

    摘要翻译: 新的1,3-二烷氧基-2-丙醇及其烷氧基化物可以通过方便的方法以良好的收率制备,包括将表氯醇加入到化学计量过量的醇中,其中醇:表氯醇的比例为至少约3:1, 存在1A族金属氢氧化物和相转移催化剂。 结果显示出优异的1,3-取代位置的选择性,并且烷基链可以是饱和或不饱和的,并且可以含有一个或多个杂原子。 烷氧基化物可以包括2-位上的重复烷氧基单元。 该组合物可用作表面活性剂,稀释剂等。

    Polyfunctional liquid urethane composition
    4.
    发明授权
    Polyfunctional liquid urethane composition 失效
    多功能液体氨基甲酸酯组合物

    公开(公告)号:US06162862A

    公开(公告)日:2000-12-19

    申请号:US391132

    申请日:1999-09-07

    摘要: Disclosed is a urethane-based composition of value in surface coating applications, including treatment of glass or textiles, in adhesives and in the manufacture of a stabilized latex. The composition comprises a polyfunctional liquid urethane-containing adduct wherein said adduct contains as a first functional group at least one isocyanate moiety per molecule, and a second functional group per molecule which is not an isocyanate moiety and which is not reactive towards isocyanate functionality. The second functional group can comprise ester, nitrile, halogen, halocarbon, siloxyl, silyl, alkyne or alkene, or combinations of two or more thereof.

    摘要翻译: 公开了一种在表面涂层应用中的价值的氨基甲酸酯基组合物,包括玻璃或纺织品的处理,粘合剂和稳定胶乳的制造。 该组合物包含多官能含液氨基甲酸酯的加合物,其中所述加合物每分子含有至少一个异氰酸酯部分作为第一官能团,每分子含有不是异氰酸酯部分的第二官能团,并且对于异氰酸酯官能团不具有反应性。 第二官能团可包括酯,腈,卤素,卤代烃,甲硅烷氧基,甲硅烷基,炔烃或烯烃,或其两种或更多种的组合。

    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids
    7.
    发明申请
    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids 有权
    由含羟基甲基的脂肪酸或这种脂肪酸的烷基酯制成的聚氨酯

    公开(公告)号:US20090264548A1

    公开(公告)日:2009-10-22

    申请号:US11663466

    申请日:2005-10-24

    IPC分类号: C08G18/36 C08J9/00

    摘要: Polyurethane polymers are made from a reaction mixture that contains a polyisocyanate, a hydroxylmethyl-containing fatty acid or ester, and another polyol, polyamine or aminoalcohol. The carboxylic acid or ester group on the hydroxymethyl-containing fatty acid or ester are capable of engaging in a variety of reactions with the polyisocyanate and/or amine or hydroxyl groups present in the reaction mixture. This allows for good quality, high molecular weight polymers to be produced even though the hydroxymethyl-containing fatty acid or ester tends to be a low functionality material.

    摘要翻译: 聚氨酯聚合物由含有多异氰酸酯,含羟甲基脂肪酸或酯的反应混合物和另一种多元醇,多胺或氨基醇制成。 含有羟甲基的脂肪酸或酯上的羧酸或酯基能够与存在于反应混合物中的多异氰酸酯和/或胺或羟基发生各种反应。 即使含有羟甲基的脂肪酸或酯倾向于低官能度材料,也可以生产高质量的高分子量聚合物。

    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids
    9.
    发明授权
    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids 有权
    由含羟基甲基的脂肪酸或这种脂肪酸的烷基酯制成的聚氨酯

    公开(公告)号:US08686057B2

    公开(公告)日:2014-04-01

    申请号:US11663466

    申请日:2005-10-24

    IPC分类号: C08G18/28

    摘要: Polyurethane polymers are made from a reaction mixture that contains a polyisocyanate, a hydroxylmethyl-containing fatty acid or ester, and another polyol, polyamine or aminoalcohol. The carboxylic acid or ester group on the hydroxymethyl-containing fatty acid or ester are capable of engaging in a variety of reactions with the polyisocyanate and/or amine or hydroxyl groups present in the reaction mixture. This allows for good quality, high molecular weight polymers to be produced even though the hydroxymethyl-containing fatty acid or ester tends to be a low functionality material.

    摘要翻译: 聚氨酯聚合物由含有多异氰酸酯,含羟甲基脂肪酸或酯的反应混合物和另一种多元醇,多胺或氨基醇制成。 含有羟甲基的脂肪酸或酯上的羧酸或酯基能够与存在于反应混合物中的多异氰酸酯和/或胺或羟基发生各种反应。 即使含有羟甲基的脂肪酸或酯倾向于低官能度材料,也可以生产高质量的高分子量聚合物。