公开(公告)号：US6087432A

公开(公告)日：2000-07-11

申请号：US126823

申请日：1998-07-31

申请人： John J. Lannutti ,  Robert R. Seghi ,  Jiazhong Luo

发明人： John J. Lannutti ,  Robert R. Seghi ,  Jiazhong Luo

IPC分类号： C08K3/34

CPC分类号： C08K3/34

摘要： The material of the present invention is a filled polymeric material, the material comprising, or consisting essentially of, a thermosetting polymeric material formed from the at least one monomer; the thermosetting polymeric containing a nano-porous inorganic gel material, the inorganic gel material having a sufficient degree of porosity for the monomer(s) such that the inorganic gel material is capable of bonding to the thermosetting polymeric material during polymerization. The present invention also includes an method for the production of such filled polymeric materials.

摘要翻译： 本发明的材料是填充的聚合物材料，该材料包含或基本上由至少一种单体形成的热固性聚合物材料; 含有纳米多孔无机凝胶材料的热固性聚合物，所述无机凝胶材料对于单体具有足够的孔隙度，使得无机凝胶材料能够在聚合过程中与热固性聚合材料结合。 本发明还包括用于生产这种填充的聚合物材料的方法。

公开(公告)号：US08632699B2

公开(公告)日：2014-01-21

申请号：US11547903

申请日：2005-04-07

申请人： Paul J. Glatkowski ,  Joseph W. Piche ,  C. Michael Trottier ,  Philip Wallis ,  David J. Arthur ,  Jiazhong Luo

发明人： Paul J. Glatkowski ,  Joseph W. Piche ,  C. Michael Trottier ,  Philip Wallis ,  David J. Arthur ,  Jiazhong Luo

IPC分类号： H01B1/24 ,  H01B1/18

CPC分类号： B82Y30/00 ,  B82Y10/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/04 ,  C01B2202/06 ,  C01B2202/28 ,  H01B1/24 ,  H01L51/0007 ,  H01L51/0048

摘要： The invention is directed to carbon nanotube-containing compositions that have increased viscosity and stability. In particular, the invention is directed to methods for manufacturing carbon nanotube films and layers that provide superior electrical properties.

摘要翻译： 本发明涉及具有增加的粘度和稳定性的含碳纳米管的组合物。 特别地，本发明涉及制造提供优异电性能的碳纳米管膜和层的方法。

公开(公告)号：US20100151254A1

公开(公告)日：2010-06-17

申请号：US12635640

申请日：2009-12-10

申请人： Jiazhong Luo ,  Tsuyoshi Noguchi

发明人： Jiazhong Luo ,  Tsuyoshi Noguchi

IPC分类号： C08K3/22 ,  B32B15/08 ,  F16J15/10

CPC分类号： F16J15/102 ,  Y10T428/31544

摘要： Provided herein is a fluorine-containing elastomer composition having a first curable perfluoropolymer comprising tetrafluoroethylene, at least one perfluoroalkylvinyl ether and at least one cure site monomer having a functional group to permit crosslinking of the perfluoropolymer; and barium titanate.

摘要翻译： 本发明提供一种含氟弹性体组合物，其具有包含四氟乙烯，至少一种全氟烷基乙烯基醚和至少一种具有官能团的固化部位单体的第一可固化全氟聚合物，以使全氟聚合物交联; 和钛酸钡。

公开(公告)号：US20080287627A1

公开(公告)日：2008-11-20

申请号：US12148014

申请日：2008-04-16

申请人： Tsuyoshi Noguchi ,  Jiazhong Luo ,  Tatsuya Morikawa ,  Hirokazu Komori ,  Takafumi Yamato ,  Meiten Koh

发明人： Tsuyoshi Noguchi ,  Jiazhong Luo ,  Tatsuya Morikawa ,  Hirokazu Komori ,  Takafumi Yamato ,  Meiten Koh

IPC分类号： C08F16/24

CPC分类号： C08L27/18 ,  C08K5/18 ,  C08L2205/02 ,  Y10T428/3154 ,  C08L2666/04

摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).

摘要翻译： 本发明包括交联的全氟弹性体组合物和由可交联的全氟弹性体组合物形成的模塑制品，其具有具有固化部位单体的第一可固化全氟聚合物和具有固化部位单体的第二全氟聚合物。 全氟聚合物中四氟乙烯单体与全氟烷基乙烯基醚的摩尔比在全氟聚合物中为约0至约100至约65至35。 第二聚合物中四氟乙烯单体与全氟烷基乙烯基醚单体的摩尔比在第二全氟聚合物中为约65:35至约95:5。 组合物还包括治疗剂。 具有交联时间短的一种含氟弹性体组合物具有全氟弹性体（A），其具有四氟乙烯单元，全氟烷基乙烯基醚单元（a）和单体单元（b），所述单体单元具有选自以下的至少一种： 腈基，羧基和烷氧基羰基，其中所述组合物具有两种或更多种具有不同全氟烷基乙烯基醚单元（a）含量的全氟弹性体（A）。

公开(公告)号：US20050266162A1

公开(公告)日：2005-12-01

申请号：US11079012

申请日：2005-03-14

申请人： Jiazhong Luo ,  Philip Wallis ,  David Arthur ,  Paul Glatkowski

发明人： Jiazhong Luo ,  Philip Wallis ,  David Arthur ,  Paul Glatkowski

IPC分类号： B05D1/12 ,  C01B31/02 ,  C09D9/00 ,  H01B1/24

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C09D9/005 ,  H01B1/24

摘要： The invention is directed to compositions and methods for forming conductive patterned coatings of carbon nanotubes. Patterns are electrically conductive coatings/films made by exploiting self patterning nanostructures composed of electrically conductive materials. The resulting layer is suitable for conducting electricity in applications where a transparent electrode is required. Typical applications include, but are not limited to; LC displays, touch screens, EMI shielding windows, and architectural windows. Films may be highly transparent. In one embodiment, carbon nanotubes are applied to an insulating substrate to form an electrically conductive network of nanotubes with controlled porosity in the network. The open area between the networks of nanotubes, increases the optical transparency in the visible spectrum while the continuous nanotube phase provides electrical conductivity across the entire surface or patterned area. Through the controlled application of this self assembled network of nanotubes by means of printing or spraying, patterned areas can be formed to function as electrodes in devices. The use of printing technology to form these electrodes obviates the need for more expensive process such as vacuum deposition and photolithography typically employed today during the formation of ITO coatings.

摘要翻译： 本发明涉及用于形成碳纳米管的导电图案化涂层的组合物和方法。 图案是通过利用由导电材料构成的自组装纳米结构制成的导电涂层/薄膜。 所得的层适用于在需要透明电极的应用中导电。 典型应用包括但不限于： LC显示屏，触摸屏，EMI屏蔽窗和建筑窗口。 电影可能非常透明。 在一个实施例中，将碳纳米管施加到绝缘基板上以形成网络中具有受控多孔性的纳米管的导电网络。 纳米管网络之间的开放区域增加了可见光谱中的光学透明度，而连续的纳米管相位提供整个表面或图案区域的导电性。 通过这种通过印刷或喷涂的纳米管自组装网络的受控应用，可以形成图案化的区域以用作器件中的电极。 使用印刷技术形成这些电极消除了在ITO涂层形成期间通常使用的更昂贵的工艺，例如真空沉积和光刻的需要。

公开(公告)号：US20050003217A1

公开(公告)日：2005-01-06

申请号：US10901699

申请日：2004-07-29

申请人： Elizabeth Walker ,  Jiazhong Luo ,  Rose Schultz ,  Katharine Pearce

发明人： Elizabeth Walker ,  Jiazhong Luo ,  Rose Schultz ,  Katharine Pearce

IPC分类号： G01L19/06 ,  C08G77/50 ,  C08K5/5435 ,  C08L83/04 ,  C08L83/05 ,  C08L83/08 ,  C08L83/14 ,  B32B9/04

CPC分类号： C08G77/50 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08K5/5435 ,  C08L83/04 ,  C08L83/08 ,  C08L83/14 ,  H01L23/296 ,  H01L2924/0002 ,  Y10T428/31663 ,  C08L83/00 ,  H01L2924/00

摘要： A cross-linkable and cross-linked organosilicon polymer which is prepared from a mixture of a reactive polysiloxane resin having both reactive carbon-carbon double bonds and silicone-hydrogen groups, characterized by alternating structures of polycyclic polyene residue and cyclic (or tetrahedral) polysiloxane residue, and either vinyl terminated fluorine-containing polysiloxane or vinyl terminated phenyl-substituted siloxane. In an alternative embodiment, the polymer comprises a mixture of vinyl terminated phenyl-substituted polysiloxane and vinyl functional fluorosilicone elastomer with the cross-linkable and cross linked organosilicon polymer.

摘要翻译： 由具有反应性碳 - 碳双键和硅氢基团的反应性聚硅氧烷树脂的混合物制备的可交联和交联的有机硅聚合物，其特征在于多环多烯残基和环（或四面体）聚硅氧烷的交替结构 残基和乙烯基封端的含氟聚硅氧烷或乙烯基封端的苯基取代的硅氧烷。 在替代实施方案中，聚合物包含乙烯基封端的苯基取代的聚硅氧烷和乙烯基官能的氟硅氧烷弹性体与可交联和交联的有机硅聚合物的混合物。

公开(公告)号：US07378040B2

公开(公告)日：2008-05-27

申请号：US11201275

申请日：2005-08-11

申请人： Jiazhong Luo ,  David J. Arthur ,  Paul J. Glatkowski

发明人： Jiazhong Luo ,  David J. Arthur ,  Paul J. Glatkowski

IPC分类号： H01B1/00

CPC分类号： H01B1/24 ,  B82Y10/00 ,  C08J7/045 ,  C08J2367/02 ,  C08J2427/12 ,  Y10T156/10

摘要： This invention relates to flexible, transparent and conductive coatings and films formed using carbon nanotubes (CNT) and, in particular, single wall CNT, with polymer binders. Preferably, coatings and films are formed from CNT applied to transparent substrates forming one or multiple conductive layers at nanometer level of thickness. Polymer binders are applied to the CNT network coating having an open structure to provide protection through infiltration, and may comprise a basecoat, a topcoat, or a combination thereof, providing enhanced optical transparency, conductivity, moisture resistance, thermal resistance, abrasion resistance and interfacial adhesion. Polymers may be thermoplastics, thermosets, insulative, conductive or a combination thereof. A fluoropolymer containing binder is applied onto a CNT-based transparent conductive coating at nanometer level of thickness on a clear substrate. The fluoropolymers or blend can be either semi-crystalline or amorphous. This binder coating and the resulting products can be used for display and electronic applications.

摘要翻译： 本发明涉及使用碳纳米管（CNT），特别是单壁CNT与聚合物粘合剂形成的柔性，透明和导电的涂层和膜。 优选地，涂层和膜由施加到形成纳米级厚度的一个或多个导电层的透明基板上的CNT形成。 将聚合物粘合剂施加到具有开放结构的CNT网络涂层以通过渗透提供保护，并且可以包括底漆，面漆或其组合，提供增强的光学透明度，导电性，耐湿性，耐热性，耐磨性和界面 附着力。 聚合物可以是热塑性塑料，热固性材料，绝缘，导电或其组合。 将含氟聚合物的粘合剂以纳米级的透明基材涂覆在CNT-基透明导电涂层上。 含氟聚合物或共混物可以是半结晶或无定形的。 该粘合剂涂层和所得产品可用于显示和电子应用。

公开(公告)号：US20060113510A1

公开(公告)日：2006-06-01

申请号：US11201275

申请日：2005-08-11

申请人： Jiazhong Luo ,  David Arthur ,  Paul Glatkowski

发明人： Jiazhong Luo ,  David Arthur ,  Paul Glatkowski

IPC分类号： H01B1/12

CPC分类号： H01B1/24 ,  B82Y10/00 ,  C08J7/045 ,  C08J2367/02 ,  C08J2427/12 ,  Y10T156/10

摘要： This invention relates to flexible, transparent and conductive coatings and films formed using carbon nanotubes (CNT) and, in particular, single wall carbon nanotubes, with polymer binders. Preferably, coatings and films are formed from carbon nanotubes applied to transparent substrates forming one or multiple conductive layers at nanometer level of thickness. Polymer binders are applied to the CNT network coating having an open structure to provide protection through infiltration. This provides for enhancement of properties such as moisture resistance, thermal resistance, abrasion resistance and interfacial adhesion. Polymers may be thermoplastics or thermosets, or a combination thereof. Polymers may also be insulative or inherently electrical conductive, or any combination of both. Polymers may comprise single or multiple layers as a basecoat underneath a CNT coating, or a topcoat above a CNT coating, or combination of the basecoat and the topcoat forming a sandwich structure. A fluoropolymer containing binder, which is a solution of one fluoropolymer or a blend of fluoropolymers, which may be formulated with additives, is applied onto a carbon nanotube-based transparent conductive coating at nanometer level of thickness on a clear substrate such as PET and glass. The fluoropolymers or blend can be either semi-crystalline (with low level of crystallinity) or amorphous, preferably to be amorphous with low refraction index. Binder coating thickness can be adjusted by changing binder concentration, coating speed and/or other process conditions. This binder coating significantly improves optical transparency, and also maintain or increases conductivity of the CNT-based coating. With other benefits such as abrasion, thermal and moisture resistance, this binder coating and the resulting products is used for display and electronic applications.

摘要翻译： 本发明涉及柔性，透明和导电的涂层和使用碳纳米管（CNT），特别是单壁碳纳米管与聚合物粘合剂形成的膜。 优选地，涂层和膜由应用于形成纳米级厚度的一个或多个导电层的透明基板上的碳纳米管形成。 将聚合物粘合剂施加到具有开放结构的CNT网络涂层，以通过渗透提供保护。 这提供了诸如耐湿性，耐热性，耐磨性和界面粘附性的增强。 聚合物可以是热塑性塑料或热固性材料，或其组合。 聚合物也可以是绝缘的或固有的导电的，或两者的任何组合。 聚合物可以包含单层或多层作为CNT涂层下的底涂层，或CNT涂层上面的顶涂层，或者底涂层和顶涂层的组合形成夹层结构。 将含氟聚合物的含氟聚合物或可与添加剂一起配制的含氟聚合物的混合物的溶液施加到碳纳米管基透明导电涂层上，该透明导电涂层在透明基材如PET和玻璃上以纳米级 。 含氟聚合物或共混物可以是半结晶（具有低结晶度）或无定形，优选为具有低折射率的无定形。 粘合剂涂层厚度可以通过改变粘合剂浓度，涂布速度和/或其他工艺条件来调节。 该粘合剂涂层显着地改善了光学透明性，并且还维持或增加了基于CNT的涂层的导电性。 具有耐磨，耐热和防潮等其他优点，该粘合剂涂层和所得产品用于显示和电子应用。

公开(公告)号：US06287692B1

公开(公告)日：2001-09-11

申请号：US09330758

申请日：1999-06-11

申请人： Jiazhong Luo ,  Anthony E. Listro

发明人： Jiazhong Luo ,  Anthony E. Listro

IPC分类号： B32B1500

CPC分类号： C08L23/06 ,  C08L23/0853 ,  C08L2201/02 ,  Y10T428/2933 ,  Y10T428/294 ,  C08L2666/04

摘要： A crosslinked coating composition that demonstrates excellent resistance to fuel, flame and high temperature in addition to good mechanical properties including high flexibility, high elongation and tensile strength, abrasion and pinch resistance is provided. The composition is based on a blend of HDPE homopolymers and high-VA-content EVA copolymers and is useful as an insulating material for wires or cables used in automotive gas-tank passthrough applications.

摘要翻译： 提供了一种交联的涂料组合物，除了具有高柔性，高伸长率和拉伸强度，耐磨性和耐挤压性等良好的机械性能外，还显示出优异的耐燃料，火焰和高温性能。 该组合物基于HDPE均聚物和高VA含量的EVA共聚物的共混物，并且可用作用于汽车气罐通道应用中的电线或电缆的绝缘材料。

公开(公告)号：US08367776B2

公开(公告)日：2013-02-05

申请号：US12148014

申请日：2008-04-16

申请人： Tsuyoshi Noguchi ,  Jiazhong Luo ,  Tatsuya Morikawa ,  Hirokazu Komori ,  Takafumi Yamato ,  Meiten Koh

发明人： Tsuyoshi Noguchi ,  Jiazhong Luo ,  Tatsuya Morikawa ,  Hirokazu Komori ,  Takafumi Yamato ,  Meiten Koh

IPC分类号： C08F214/26

CPC分类号： C08L27/18 ,  C08K5/18 ,  C08L2205/02 ,  Y10T428/3154 ,  C08L2666/04

摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).