Apparatus for treating a flow of an aqueous solution containing arsenic
    1.
    发明授权
    Apparatus for treating a flow of an aqueous solution containing arsenic 失效
    用于处理含砷水溶液流动的装置

    公开(公告)号:US08066874B2

    公开(公告)日:2011-11-29

    申请号:US11932837

    申请日:2007-10-31

    IPC分类号: C02F1/58 C02F101/10

    摘要: An apparatus for treating an aqueous solution containing arsenic. The apparatus comprises a container that includes a housing, an inlet located at a first end of the housing and an outlet located at a second end opposite the first end. An outer wall extends between the first and second ends and enclosing a fluid flow path between the inlet and the outlet and an arsenic fixing agent is disposed in the fluid flow path. The arsenic fixing agent can include an insoluble rare earth-containing compound, more specifically, a compound comprising one or more of cerium, lanthanum, or praseodymium. The inlet and the outlet are adapted to be closed during transport and storage. The container is adapted to be sealed for long term disposal after exposure to an aqueous solution containing arsenic.

    摘要翻译: 一种处理含砷水溶液的设备。 该装置包括容器,该容器包括壳体,位于壳体的第一端的入口和位于与第一端相对的第二端的出口。 外壁在第一和第二端之间延伸并且包围入口和出口之间的流体流动路径,并且砷固定剂设置在流体流动路径中。 砷固定剂可以包括不溶性稀土化合物,更具体地,包括铈,镧或镨中的一种或多种的化合物。 入口和出口适于在运输和储存期间关闭。 该容器适于在暴露于含有砷的水溶液之后进行密封以进行长期处置。

    APPARATUS FOR TREATING A FLOW OF AN AQUEOUS SOLUTION CONTAINING ARSENIC
    2.
    发明申请
    APPARATUS FOR TREATING A FLOW OF AN AQUEOUS SOLUTION CONTAINING ARSENIC 失效
    用于处理含有ARSENIC的水溶液流动的装置

    公开(公告)号:US20080156734A1

    公开(公告)日:2008-07-03

    申请号:US11932837

    申请日:2007-10-31

    IPC分类号: B01D15/08 B01D15/38 C02F1/42

    摘要: An apparatus for treating an aqueous solution containing arsenic. The apparatus comprises a container that includes a housing, an inlet located at a first end of the housing and an outlet located at a second end opposite the first end. An outer wall extends between the first and second ends and enclosing a fluid flow path between the inlet and the outlet and an arsenic fixing agent is disposed in the fluid flow path. The arsenic fixing agent can include an insoluble rare earth-containing compound, more specifically, a compound comprising one or more of cerium, lanthanum, or praseodymium. The inlet and the outlet are adapted to be closed during transport and storage. The container is adapted to be sealed for long term disposal after exposure to an aqueous solution containing arsenic.

    摘要翻译: 一种处理含砷水溶液的设备。 该装置包括容器,该容器包括壳体,位于壳体的第一端的入口和位于与第一端相对的第二端的出口。 外壁在第一和第二端之间延伸并且包围入口和出口之间的流体流动路径,并且砷固定剂设置在流体流动路径中。 砷固定剂可以包括不溶性稀土化合物,更具体地,包括铈,镧或镨中的一种或多种的化合物。 入口和出口适于在运输和储存期间关闭。 该容器适于在暴露于含有砷的水溶液之后进行密封以进行长期处置。

    METHOD AND APPARATUS FOR REMOVING ARSENIC FROM A SOLUTION
    3.
    发明申请
    METHOD AND APPARATUS FOR REMOVING ARSENIC FROM A SOLUTION 审中-公开
    从解决方案中去除砷的方法和装置

    公开(公告)号:US20120138530A1

    公开(公告)日:2012-06-07

    申请号:US11958968

    申请日:2007-12-18

    摘要: A method and apparatus for separating arsenic from an aqueous solution containing arsenic. The method includes the steps of contacting an arsenic-containing solution with a first portion of fixing agent to remove at least a portion of the arsenic. An arsenic-laden fixing agent is separated from the solution and the partially depleted solution is contacted with a second portion of fixing agent. The fixing agent can include a high surface area insoluble compound containing one or more of cerium, lanthanum, or praseodymium. Following removal of the arsenic, the arsenic-depleted solution can be further processed to separate a recoverable metal through metal refining. The arsenic-laden fixing agent can be filtered to recover and recycle a filtrate to the solution for additional treatment, as well as using a partially saturated fixing agent to remove arsenic from fresh solution. An arsenic-containing solution can be formed from arsenic-containing solids such as contaminated soils, industrial byproducts and waste materials.

    摘要翻译: 从含有砷的水溶液中分离砷的方法和装置。 该方法包括使含砷溶液与固定剂的第一部分接触以除去至少一部分砷的步骤。 将含砷的固定剂与溶液分离,并将部分耗尽的溶液与固定剂的第二部分接触。 固定剂可以包括含有一种或多种铈,镧或镨的高表面积不溶性化合物。 在除去砷之后,可以进一步处理贫砷溶液以通过金属精炼分离可回收金属。 可以过滤含砷的固定剂以回收并再循环到溶液中以进行另外的处理,以及使用部分饱和的固定剂从新鲜的溶液中除去砷。 含砷溶液可以由含砷固体,如污染土壤,工业副产品和废料形成。

    METHOD AND APPARATUS FOR REMOVING ARSENIC FROM AN ARSENIC BEARING MATERIAL
    4.
    发明申请
    METHOD AND APPARATUS FOR REMOVING ARSENIC FROM AN ARSENIC BEARING MATERIAL 审中-公开
    从ARSENIC轴承材料中去除ARSENIC的方法和装置

    公开(公告)号:US20120138528A1

    公开(公告)日:2012-06-07

    申请号:US11958602

    申请日:2007-12-18

    摘要: A method and apparatus for removing arsenic from an arsenic-bearing material. The method includes the steps of contracting an arsenic-bearing material with an arsenic leaching agent to form an arsenic-containing solution and arsenic-depleted solids. The leaching agent can be an inorganic salt, an inorganic acid, an organic acid, and/or an alkaline agent. The arsenic-depleted solids are separated from the arsenic-containing solution, which is contacted with a fixing agent to produce an arsenic-depleted solution and an arsenic-laden fixing agent. The fixing agent comprises a rare earth-containing compound that can include cerium, lanthanum, or praseodymium. The fixing agent is then separated from the arsenic-depleted solution. A recoverable metal in the arsenic-depleted solids, arsenic-containing solution or arsenic-depleted solution can be separated and recovered. Recoverable metals can include metal from Group IA, Group IIA, Group VIII and the transition metals.

    摘要翻译: 一种从含砷材料中除砷的方法和装置。 该方法包括以下步骤:用砷浸出剂收集含砷材料以形成含砷溶液和贫砷固体。 浸出剂可以是无机盐,无机酸,有机酸和/或碱性试剂。 将含砷的固体与含砷溶液分离,其与定影剂接触以产生贫砷溶液和含砷的固定剂。 固定剂包括可包括铈,镧或镨的含稀土化合物。 然后将固色剂与贫砷溶液分离。 可以分离和回收砷贫化固体,含砷溶液或贫砷溶液中的可回收金属。 可回收金属可以包括来自IA组,IIA族,VIII族和过渡金属的金属。

    METHOD AND APPARATUS FOR RECOVERING A METAL AND SEPARATING ARSENIC FROM AN ARSENIC CONTAINING SOLUTION
    5.
    发明申请
    METHOD AND APPARATUS FOR RECOVERING A METAL AND SEPARATING ARSENIC FROM AN ARSENIC CONTAINING SOLUTION 审中-公开
    用于从含有ARSENIC的溶液中回收金属和分离ARSENIC的方法和装置

    公开(公告)号:US20120138529A1

    公开(公告)日:2012-06-07

    申请号:US11958644

    申请日:2007-12-18

    摘要: A method and apparatus for recovering a metal and separating arsenic from an arsenic-containing solution. The method includes contacting the arsenic-containing solution with a fixing agent that comprises a rare earth compound to produce an arsenic-depleted solution and an arsenic-laden fixing agent. The fixing agent comprises a rare earth-containing compound that can include cerium, lanthanum, or praseodymium. The fixing agent is separated from the arsenic-depleted solution and a recoverable metal is separated from one or more of the arsenic-containing solution and the arsenic-depleted solution. Recoverable metals can include metal from Group IA, Group IIA, Group VIII and the transition metals. The arsenic-containing solution can be formed by contacting an arsenic-containing material with a leaching agent. Arsenic-depleted solids formed during the leach can also be separated and recovered. An apparatus of the invention can include two or more arsenic fixing units configured to conduct the method on a continuous basis.

    摘要翻译: 一种用于回收金属并从含砷溶液中分离砷的方法和装置。 该方法包括使含砷溶液与包含稀土化合物的固定剂接触以产生贫砷溶液和含砷载体固定剂。 固定剂包括可包括铈,镧或镨的含稀土化合物。 将固定剂与贫砷溶液分离,并将可回收金属与一种或多种含砷溶液和贫砷溶液分离。 可回收金属可以包括来自IA组,IIA族,VIII族和过渡金属的金属。 含砷溶液可以通过使含砷材料与浸出剂接触而形成。 在浸出过程中形成的贫砷固体也可以分离和回收。 本发明的装置可以包括被配置为连续进行该方法的两个或更多个砷固定单元。