公开(公告)号：US07981275B2

公开(公告)日：2011-07-19

申请号：US10574944

申请日：2003-10-10

申请人： José Antonio Toledo Antonio ,  José Escobar Aguilar ,  María Antonia Cortés Jacome ,  Maria de Lourdes Mosqueira Mondragon ,  Víctor Pérez Moreno ,  Carlos Angeles Chávez ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

发明人： José Antonio Toledo Antonio ,  José Escobar Aguilar ,  María Antonia Cortés Jacome ,  Maria de Lourdes Mosqueira Mondragon ,  Víctor Pérez Moreno ,  Carlos Angeles Chávez ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

IPC分类号： C10G45/08 ,  C10G45/04 ,  C10G45/06

CPC分类号： B01J37/0201 ,  B01J21/063 ,  B01J23/85 ,  B01J23/882 ,  B01J35/06 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0205 ,  B01J37/08 ,  B01J37/20 ,  B01J37/28 ,  B82Y30/00 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/104 ,  C10G2300/1048 ,  C10G2300/70

摘要： The present invention relates to the novel catalytic composition having a high specific activity in reactions involving hydroprocessing of light and intermediate petroleum fractions, and preferably in hydrodesulphurization and hydrodenitrogenation reactions. The inventive catalyst contains at least one element of a non-noble metal from group VIII, at least one element from group VIB and, optionally, a group one element of the VA group, which are deposited on a novel catalytic support comprising of an inorganic metal oxide from group IVB, consisting of an (1D) one-dimensional nanostructured material having nanofibers and/or nanotube morphology with high specific surface area of between 10 and 500 m2/g.

摘要翻译： 本发明涉及在涉及加氢处理光和中间石油馏分的反应中具有高比活性的新催化组合物，优选在加氢脱硫和加氢脱氮反应中。 本发明的催化剂含有至少一种元素的VIII族非贵金属，至少一种来自VIB族的元素和任选的一组VA族基团，它们沉积在新型催化载体上，该载体包含无机 由IVB组成的金属氧化物，其由具有10-500m 2 / g的高比表面积的具有纳米纤维和/或纳米管形态的（1D）一维纳米结构材料组成。

公开(公告)号：US08946110B2

公开(公告)日：2015-02-03

申请号：US12065116

申请日：2006-08-22

申请人： José Antonio Toledo Antonio ,  Miguel Pérez Luna ,  María Antonia Cortés Jacome ,  José Escobar Aguilar ,  María de Lourdes Mosqueira Mondragón ,  Carlos Angeles Chávez ,  Esteban López Salinas ,  Víctor Pérez Moreno ,  Gerardo Ferrat Torres ,  Rodolfo Juventino Mora Vallejo ,  Marcelo Lozada y Cassou

发明人： José Antonio Toledo Antonio ,  Miguel Pérez Luna ,  María Antonia Cortés Jacome ,  José Escobar Aguilar ,  María de Lourdes Mosqueira Mondragón ,  Carlos Angeles Chávez ,  Esteban López Salinas ,  Víctor Pérez Moreno ,  Gerardo Ferrat Torres ,  Rodolfo Juventino Mora Vallejo ,  Marcelo Lozada y Cassou

IPC分类号： B01J23/22 ,  B01J37/03 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/00 ,  B01J37/00 ,  B01J37/08 ,  B01J37/20 ,  C10G45/08 ,  C10G45/50 ,  B01J35/10

CPC分类号： B01J27/0515 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/03 ,  B01J37/084 ,  B01J37/20 ,  C10G45/08 ,  C10G45/50

摘要： The invention relates to a method of preparing a catalytic composition comprising at least one non-noble metal from group VIII and at least one metal from group VIB of the periodic table. The invention also relates to the catalytic composition thus produced, which has a high specific activity in reactions involving the hydroprocessing of light and intermediate fractions, preferably in reactions involving the hydrotreatment of hydrocarbon streams, including hydrodesulphurization (HDS), hydrodenitrogenation (HDN) and hydro-dearomatization (HDA).

摘要翻译： 本发明涉及一种制备催化组合物的方法，所述催化组合物包含至少一种来自VIII族的非贵金属和至少一种来自元素周期表VIB族的金属。 本发明还涉及如此生产的催化组合物，其在涉及光加氢处理和中间馏分的反应中具有高比活度，优选在涉及烃流加氢处理的反应（包括加氢脱硫（HDS）），加氢脱氮（HDN）和氢 - 脱（HDA）。

公开(公告)号：US20100038285A1

公开(公告)日：2010-02-18

申请号：US10574944

申请日：2003-10-10

申请人： José Antonio Toledo Antonio ,  José Escobar Aguilar ,  Maria Antonia Cortés Jacome ,  Maria de Lourdes Mosqueira Mondragon ,  Vitor Pérez Moreno ,  Calos Angeles Chávez ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

发明人： José Antonio Toledo Antonio ,  José Escobar Aguilar ,  Maria Antonia Cortés Jacome ,  Maria de Lourdes Mosqueira Mondragon ,  Vitor Pérez Moreno ,  Calos Angeles Chávez ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

IPC分类号： C10G45/60 ,  B01J23/24 ,  B01J27/185 ,  B01J27/02

CPC分类号： B01J37/0201 ,  B01J21/063 ,  B01J23/85 ,  B01J23/882 ,  B01J35/06 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0205 ,  B01J37/08 ,  B01J37/20 ,  B01J37/28 ,  B82Y30/00 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/104 ,  C10G2300/1048 ,  C10G2300/70

摘要： The present invention relates to the novel catalytic composition having a high specific activity in reactions involving hydroprocessing of light and intermediate petroleum fractions, and preferably in hydrodesulphurization and hydrodenitrogenation reactions. The inventive catalyst contains at least one element of a non-noble metal from group VIII, at least one element from group VIB and, optionally, a group one element of the VA group, which are deposited on a novel catalytic support comprising of an inorganic metal oxide from group IVB, consisting of an (ID) one-dimensional nanostructured material having nanofibers and/or nanotube morphology with high specific surface area of between 10 and 500 m2/g.

摘要翻译： 本发明涉及在涉及加氢处理光和中间石油馏分的反应中具有高比活性的新催化组合物，优选在加氢脱硫和加氢脱氮反应中。 本发明的催化剂含有至少一种元素的VIII族非贵金属，至少一种来自VIB族的元素和任选的一组VA族基团，它们沉积在新型催化载体上，该载体包含无机 由IVB组成的金属氧化物，其由具有10-500m 2 / g的高比表面积的纳米纤维和/或纳米管形态的（ID）一维纳米结构材料组成。

公开(公告)号：US07645439B2

公开(公告)日：2010-01-12

申请号：US11121178

申请日：2005-05-04

申请人： José Antonio Toledo Antonio ,  Carlos Angeles Chávez ,  María Antonia Cortés Jacome ,  Fernando Alvarez Ramírez ,  Yosadara Ruiz Morales ,  Gerardo Ferrat Torres ,  Luis Francisco Flores Ortiz ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

发明人： José Antonio Toledo Antonio ,  Carlos Angeles Chávez ,  María Antonia Cortés Jacome ,  Fernando Alvarez Ramírez ,  Yosadara Ruiz Morales ,  Gerardo Ferrat Torres ,  Luis Francisco Flores Ortiz ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

IPC分类号： C01G23/04 ,  C01G23/047

CPC分类号： C01G23/043 ,  B82Y30/00 ,  C01G23/04 ,  C01G23/047 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/13 ,  C01P2004/16 ,  Y10S977/811 ,  Y10T428/256 ,  Y10T428/2975 ,  Y10T428/298 ,  Y10T428/2982

摘要： Nanomaterials of the JT phase of the titanium oxide TiO2-x, where 0≦x≦1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. These nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes. The nanomaterials are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite. The titanates are submitted to dynamic thermal treatment in an inert, oxidizing or reducing atmosphere to produce the JT phase of the TiO2-x, where 0≦x≦1 with an orthorhombic structure.

摘要翻译： 氧化钛TiO 2-x的JT相的纳米材料，其中0 <= x <= 1具有正交对称性并具有至少一个空间群59 Pmmn，63Amma，71的晶体结构 Immm或63 Bmmb。 这些纳米材料是纳米纤维，纳米线，纳米棒，纳米线和/或纳米管的形式。 所述纳米材料是从钛酸钛和/或与JT晶体结构同构的混合的钛酸钠和氢氧化钛前体化合物获得的。 钛酸盐是由钛化合物如具有锐钛矿晶体结构的钛氧化物，无定形氧化钛和具有金红石结晶结构的氧化钛获得的JT结晶相的氢化，质子化，水合和/或碱化相 ，和/或直接来自金红石矿物和/或钛铁矿。 钛酸盐在惰性，氧化或还原气氛中进行动态热处理，以产生TiO 2-x的JT相，其中0 <= x <= 1，具有正交结构。

公开(公告)号：US07416655B2

公开(公告)日：2008-08-26

申请号：US11121179

申请日：2005-05-04

申请人： José Antonio Toledo Antonio ,  María Antonia Cortés Jacome ,  Gerardo Ferrat Torres ,  Carlos Angeles Chávez ,  Luis Francisco Flores Ortiz ,  Maria de Lourdes Araceli Mosqueira Mondragon ,  Esteban López Salinas ,  Jose Escobar Aguilar ,  Rodolfo Juventino Mora Vallejo ,  Fernando Alvarez Ramírez ,  Yosadara Ruiz Morales ,  Marcelo Lozada y Cassou

发明人： José Antonio Toledo Antonio ,  María Antonia Cortés Jacome ,  Gerardo Ferrat Torres ,  Carlos Angeles Chávez ,  Luis Francisco Flores Ortiz ,  Maria de Lourdes Araceli Mosqueira Mondragon ,  Esteban López Salinas ,  Jose Escobar Aguilar ,  Rodolfo Juventino Mora Vallejo ,  Fernando Alvarez Ramírez ,  Yosadara Ruiz Morales ,  Marcelo Lozada y Cassou

IPC分类号： C10G29/00 ,  C10G17/00 ,  C10G29/04 ,  C10G25/00 ,  C01G23/047

CPC分类号： B01J20/06 ,  B01J20/0211 ,  B01J20/28007 ,  B01J21/063 ,  B01J23/04 ,  B01J23/70 ,  B01J35/0013 ,  B01J2220/42 ,  B82Y30/00 ,  C10G25/003 ,  Y10S977/734

摘要： An adsorbent composition comprising a nanostructured titanium oxide material of the formula TiO2-, where 0≦×≦1 with nanotubular and/or nanofibrilar morphology, high oxygen deficiency, having an orthorhombic JT crystalline phase described by at least one of the space groups 59 Pmmn, 63 Amma, 71Immm or 63 Bmmb, and comprising between 0 and 20 weight percent of a transition metal oxide is used for the selective adsorption of nitrogen compounds and/or sulfur compounds from light and intermediate petroleum fractions.

摘要翻译： 一种吸附剂组合物，其包含式TiO 2 2-的纳米结构氧化钛材料，其中0 <= x <= 1，具有纳米管和/或纳米纤维形态，具有高氧缺陷，具有所述的正交JT结晶相 通过至少一个空间组59 Pmmn，63Amma，71Immm或63Bmmb，并且包含0至20重量％的过渡金属氧化物，用于从光和中间体选择性吸附氮化合物和/或硫化合物 石油馏分。

公开(公告)号：US20120301526A1

公开(公告)日：2012-11-29

申请号：US13527245

申请日：2012-06-19

申请人： José Antonio Toledo Antonio ,  Carlos Angeles Chávez ,  Maria Antonia Cortés Jacome ,  Fernando Alvarez RamÍrez ,  Yosadara Ruiz Morales ,  Gerardo Ferrat Torres ,  Luis Francisco Flores Ortiz ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

发明人： José Antonio Toledo Antonio ,  Carlos Angeles Chávez ,  Maria Antonia Cortés Jacome ,  Fernando Alvarez RamÍrez ,  Yosadara Ruiz Morales ,  Gerardo Ferrat Torres ,  Luis Francisco Flores Ortiz ,  Esteban López Salinas ,  Marcelo Lozada y Cassou

IPC分类号： C01G23/04 ,  B01J20/28 ,  B01J20/30 ,  A61K8/02 ,  A61K8/29 ,  C08K3/22 ,  B01J21/06 ,  H01B1/08 ,  B82Y40/00 ,  B82Y30/00

CPC分类号： C01G23/043 ,  B82Y30/00 ,  C01G23/04 ,  C01G23/047 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/13 ,  C01P2004/16 ,  Y10S977/811 ,  Y10T428/256 ,  Y10T428/2975 ,  Y10T428/298 ,  Y10T428/2982

摘要： Nanomaterials of the JT phase of the titanium oxide TiO2-x, where 0≦x≦1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. The nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes and are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite.

摘要翻译： 氧化钛TiO 2-x的JT相的纳米材料，其中具有正交对称性的具有正交对称性并由至少一个空间群59 Pmmn，63Amma，71Immmm或以上的空间群描述的0和n1E; x＆ 63 Bmmb。 纳米材料是纳米纤维，纳米线，纳米棒，纳米线和/或纳米管的形式，并且是由氢化钛酸盐和/或与JT晶体结构同构的混合的钛酸钠和氢氧化钛前体化合物获得的。 钛酸盐是由钛化合物如具有锐钛矿晶体结构的钛氧化物，无定形氧化钛和具有金红石结晶结构的氧化钛获得的JT结晶相的氢化，质子化，水合和/或碱化相 ，和/或直接来自金红石矿物和/或钛铁矿。