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公开(公告)号：US08536395B2
公开(公告)日：2013-09-17
申请号：US13334397
申请日：2011-12-22
申请人： Joseph E. Pelati , Taylor Rives
发明人： Joseph E. Pelati , Taylor Rives
IPC分类号： C07C15/067 , C07C2/66 , C07C2/58
CPC分类号： B01J23/75 , B01J29/06 , B01J29/061 , B01J29/072 , B01J29/7615 , B01J29/90 , B01J37/0009 , B01J37/0018 , B01J2229/20 , B01J2229/42 , C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/18 , C07C2523/22 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2523/75 , Y02P20/584 , Y02P20/588 , C07C15/073
摘要： A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene.
摘要翻译： 诸如分子筛催化剂或固体酸催化剂的固体催化剂由诸如无定形二氧化硅或氧化铝的粘合剂负载，其中粘合剂装有金属离子以形成离子改性的粘合剂。 离子改性的粘合剂能够附着于极性污染物并且抑制它们与催化剂的接触。 催化剂可以是沸石，并且可以是用于烷基化反应的催化剂，例如苯与乙烯的烷基化。
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公开(公告)号：US20120095250A1
公开(公告)日：2012-04-19
申请号：US13334397
申请日：2011-12-22
申请人： Joseph E. Pelati , Taylor Rives
发明人： Joseph E. Pelati , Taylor Rives
CPC分类号： B01J23/75 , B01J29/06 , B01J29/061 , B01J29/072 , B01J29/7615 , B01J29/90 , B01J37/0009 , B01J37/0018 , B01J2229/20 , B01J2229/42 , C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/18 , C07C2523/22 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2523/75 , Y02P20/584 , Y02P20/588 , C07C15/073
摘要： A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene.
摘要翻译： 诸如分子筛催化剂或固体酸催化剂的固体催化剂由诸如无定形二氧化硅或氧化铝的粘合剂负载，其中粘合剂装有金属离子以形成离子改性的粘合剂。 离子改性的粘合剂能够附着于极性污染物并且抑制它们与催化剂的接触。 催化剂可以是沸石，并且可以是用于烷基化反应的催化剂，例如苯与乙烯的烷基化。
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公开(公告)号：US20100167913A1
公开(公告)日：2010-07-01
申请号：US12345593
申请日：2008-12-29
申请人： Joseph E. Pelati , Taylor Rives
发明人： Joseph E. Pelati , Taylor Rives
IPC分类号： B01J29/072 , B01J29/04 , B01J29/06
CPC分类号： B01J23/75 , B01J29/06 , B01J29/061 , B01J29/072 , B01J29/7615 , B01J29/90 , B01J37/0009 , B01J37/0018 , B01J2229/20 , B01J2229/42 , C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/18 , C07C2523/22 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2523/75 , Y02P20/584 , Y02P20/588 , C07C15/073
摘要： A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene.
摘要翻译： 诸如分子筛催化剂或固体酸催化剂的固体催化剂由诸如无定形二氧化硅或氧化铝的粘合剂负载，其中粘合剂装有金属离子以形成离子改性的粘合剂。 离子改性的粘合剂能够附着于极性污染物并且抑制它们与催化剂的接触。 催化剂可以是沸石，并且可以是用于烷基化反应的催化剂，例如苯与乙烯的烷基化。
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公开(公告)号：US20100022813A1
公开(公告)日：2010-01-28
申请号：US12181276
申请日：2008-07-28
申请人： James R. Butler , Joseph E. Pelati , Darek Wachowicz , Taylor Rives , Xin Xiao
发明人： James R. Butler , Joseph E. Pelati , Darek Wachowicz , Taylor Rives , Xin Xiao
CPC分类号： C07C6/123 , C07C5/2708 , C07C2529/08 , C07C2529/24 , C07C2529/70 , C10G2400/30 , C07C15/08
摘要： A method of reducing the ethylbenzene content in a stream containing xylene is disclosed. The method includes the reaction of ethylbenzene, such as a disproportionation or transalkylation reaction, to produce benzene and other hydrocarbon compound and can include the separation of at least a portion of the resulting benzene and other hydrocarbon compounds to produce a xylene stream having reduced ethylbenzene content.
摘要翻译： 公开了一种降低含二甲苯的流中的乙苯含量的方法。 该方法包括乙苯的反应，例如歧化或烷基转移反应，以产生苯和其他烃化合物，并且可以包括至少部分所得苯和其它烃化合物的分离，以产生具有降低的乙苯含量的二甲苯料流 。
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公开(公告)号：US08734737B2
公开(公告)日：2014-05-27
申请号：US13604760
申请日：2012-09-06
申请人： James R. Butler , Joseph E. Pelati
发明人： James R. Butler , Joseph E. Pelati
IPC分类号： B01J8/04
CPC分类号： C07C15/46 , C07C2/66 , C07C2/84 , C07C5/48 , Y10S585/921 , Y10S585/943 , C07C15/073
摘要： A process for making ethylbenzene and/or styrene by reacting toluene with methane is disclosed. In one embodiment the process can include reacting toluene with methane to form a product stream comprising ethylbenzene and further processing the ethylbenzene to form styrene in an existing styrene production facility.
摘要翻译： 公开了通过使甲苯与甲烷反应制备乙苯和/或苯乙烯的方法。 在一个实施方案中，该方法可以包括使甲苯与甲烷反应以形成包含乙苯的产物流，并进一步处理乙苯以在现有的苯乙烯生产设备中形成苯乙烯。
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公开(公告)号：US20130165722A9
公开(公告)日：2013-06-27
申请号：US12685892
申请日：2010-01-12
申请人： Joseph E. Pelati , James R. Butler , Hollie Craig
发明人： Joseph E. Pelati , James R. Butler , Hollie Craig
CPC分类号： B01F5/0403 , B01B1/005 , B01D7/00 , B01F5/045 , B01J4/001 , B01J8/02 , B01J38/06 , B01J38/64 , C07C5/32
摘要： An apparatus and method for vaporizing and transporting an alkali metal salt is shown. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam forming a solution that can be transported, such as to a remote reaction zone. The solution can be transported via a third conduit that is capable of being heated by a heat source. The method can be used to add a promoter to a dehydrogenation catalyst during a dehydrogenation reaction.
摘要翻译： 示出了用于蒸发和运输碱金属盐的装置和方法。 该设备具有能够输送碱金属盐溶液的第一导管和与第一导管流体连通的第二导管，第二导管能够输送蒸汽，使得碱金属盐被散发到形成可以是 运送到远程反应区。 该溶液可以经由能够被热源加热的第三导管输送。 该方法可用于在脱氢反应期间向脱氢催化剂中加入助催化剂。
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公开(公告)号：US08134036B2
公开(公告)日：2012-03-13
申请号：US12047873
申请日：2008-03-13
申请人： Joseph E. Pelati , James R. Butler , Marcus Ledoux
发明人： Joseph E. Pelati , James R. Butler , Marcus Ledoux
CPC分类号： C07C2/66 , C07C2523/10 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/02
摘要： A method for the liquid-phase alkylation of an aromatic substrate is disclosed. A reaction zone has at least one catalyst bed containing a first catalyst modified by the inclusion of a rare earth metal ion.
摘要翻译： 公开了一种用于芳族基底的液相烷基化的方法。 反应区具有至少一个含有通过包含稀土金属离子而改性的第一催化剂的催化剂床。
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公开(公告)号：US08076527B2
公开(公告)日：2011-12-13
申请号：US12047953
申请日：2008-03-13
申请人： James R. Butler , Joseph E. Pelati
发明人： James R. Butler , Joseph E. Pelati
CPC分类号： C07C15/46 , C07C2/66 , C07C2/84 , C07C5/48 , Y10S585/921 , Y10S585/943 , C07C15/073
摘要： A process for making ethylbenzene and/or styrene by reacting toluene with methane is disclosed. In one embodiment the process can include reacting toluene with methane to form a product stream comprising ethylbenzene and further processing the ethylbenzene to form styrene in an existing styrene production facility.
摘要翻译： 公开了通过使甲苯与甲烷反应制备乙苯和/或苯乙烯的方法。 在一个实施方案中，该方法可以包括使甲苯与甲烷反应以形成包含乙苯的产物流，并进一步处理乙苯以在现有的苯乙烯生产设备中形成苯乙烯。
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公开(公告)号：US20110270006A1
公开(公告)日：2011-11-03
申请号：US13113064
申请日：2011-05-22
IPC分类号： C07C2/00 , B01J29/04 , B01J23/78 , B01J23/26 , C01B39/00 , B01J23/28 , B01J23/14 , B01J23/18 , B01J23/66 , B01J37/30 , B01J23/04 , B01J23/10
CPC分类号： C01B39/22 , B01J29/082 , B01J29/143 , B01J29/90 , B01J37/0201 , B01J37/0207 , B01J37/08 , B01J37/30 , B01J38/10 , B01J38/12 , C07C2/864 , C07C2/865 , C07C2/867 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/78 , C07C2529/08 , C07C2529/83 , C07C2529/85 , Y02P20/584 , C07C15/46 , C07C15/073
摘要： A method is disclosed of preparing a catalyst, including contacting a substrate with at least one solution including a first promoter being Cs and at least one solution including a second promoter. The contact subjects the substrate to the addition of the first and second promoters, thereby forming the catalyst comprising the first and second promoters. In the method disclosed, the second promoter is capable of undergoing a redox reaction.
摘要翻译： 公开了一种制备催化剂的方法，包括使底物与至少一种溶液接触，所述溶液包括第一促进剂为Cs和至少一种包含第二促进剂的溶液。 接触剂使基材加入第一和第二助催化剂，从而形成包含第一和第二助催化剂的催化剂。 在所公开的方法中，第二促进剂能够进行氧化还原反应。
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10.发明申请Method and Apparatus for Addition of an Alkali Metal Promoter to a Dehydrogenation Catalyst 有权用于向脱氢催化剂中加入碱金属促进剂的方法和装置公开(公告)号：US20090264278A1
公开(公告)日：2009-10-22
申请号：US12107748
申请日：2008-04-22
申请人： James R. Butler , Joseph E. Pelati
发明人： James R. Butler , Joseph E. Pelati
CPC分类号： B01J4/001 , B01J4/002 , B01J23/78 , B01J2219/00024 , F17D1/06 , Y10T29/49718 , Y10T29/4973 , Y10T137/4891
摘要： An apparatus and method for adding an alkali metal promoter into steam and contacting the solution with a dehydrogenation catalyst during a dehydrogenation reaction is disclosed. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam prior to entry into a dehydrogenation reaction zone.
摘要翻译： 公开了一种在脱氢反应中将碱金属促进剂加入蒸汽并使该溶液与脱氢催化剂接触的装置和方法。 该设备具有能够输送碱金属盐溶液的第一导管和与第一导管流体连通的第二导管，第二导管能够输送蒸汽，使得碱金属盐在进入脱氢之前消散到蒸汽中 反应区。
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