METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT
    1.
    发明申请
    METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT 审中-公开
    在先前脱氢植物中氧化钛的方法

    公开(公告)号:US20120296131A1

    公开(公告)日:2012-11-22

    申请号:US13457507

    申请日:2012-04-27

    IPC分类号: C07C2/88

    摘要: A process for making styrene in a pre-existing facility including an infrastructure capable of producing styrene, wherein the infrastructure includes at least one dehydrogenation unit. The process includes coupling an alkylation unit including an alkylation reactor to the infrastructure and contacting toluene with a C1 source in the presence of a first catalyst and a co-feed in the alkylation reactor to form a first product stream comprising styrene and ethylbenzene. The styrene and ethylbenzene from the first product stream are routed for further processing to a portion of the pre-existing facility.

    摘要翻译: 一种在预先存在的设施中制备苯乙烯的方法,包括能够生产苯乙烯的基础设施,其中基础设施包括至少一个脱氢单元。 该方法包括将包括烷基化反应器的烷基化单元与基础设施偶联,并在烷基化反应器中在第一催化剂和共进料存在下将甲苯与C1源接触以形成包含苯乙烯和乙苯的第一产物流。 来自第一产物流的苯乙烯和乙苯被路由以进一步处理到一部分预先存在的设施。

    Method for providing a co-feed in the coupling of toluene with a carbon source
    3.
    发明授权
    Method for providing a co-feed in the coupling of toluene with a carbon source 有权
    在甲苯与碳源的偶合中提供共进料的方法

    公开(公告)号:US08653314B2

    公开(公告)日:2014-02-18

    申请号:US13457503

    申请日:2012-04-27

    IPC分类号: C07C1/207 C07C1/20

    摘要: A process for making styrene is disclosed that includes reacting toluene with a C1 source and a co-feed in the presence of a catalyst in a reactor to form a first product stream comprising styrene, ethylbenzene, carbon monoxide, and hydrogen; separating the hydrogen and carbon monoxide from the first product stream to form a second stream; separating the hydrogen from the second stream to form a third stream comprising hydrogen and a fourth stream comprising carbon monoxide; wherein the fourth stream is recycled to the reactor and forms at least a portion of the co-feed.

    摘要翻译: 公开了一种制备苯乙烯的方法,其包括在反应器中在催化剂存在下使甲苯与C1源和共进料反应以形成包含苯乙烯,乙苯,一氧化碳和氢的第一产物流; 将氢和一氧化碳与第一产物流分离以形成第二流; 从第二流分离氢气以形成包含氢的第三料流和包含一氧化碳的第四料流; 其中第四料流被再循环到反应器中并形成共进料的至少一部分。

    METHOD FOR PROVIDING A CO-FEED IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE
    5.
    发明申请
    METHOD FOR PROVIDING A CO-FEED IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE 有权
    在碳源与碳源的耦合中提供共同供料的方法

    公开(公告)号:US20120296139A1

    公开(公告)日:2012-11-22

    申请号:US13457503

    申请日:2012-04-27

    IPC分类号: C07C2/86

    摘要: A process for making styrene is disclosed that includes reacting toluene with a C1 source and a co-feed in the presence of a catalyst in a reactor to form a first product stream comprising styrene, ethylbenzene, carbon monoxide, and hydrogen; separating the hydrogen and carbon monoxide from the first product stream to form a second stream; separating the hydrogen from the second stream to form a third stream comprising hydrogen and a fourth stream comprising carbon monoxide; wherein the fourth stream is recycled to the reactor and forms at least a portion of the co-feed.

    摘要翻译: 公开了一种制备苯乙烯的方法,其包括在反应器中在催化剂存在下使甲苯与C1源和共进料反应以形成包含苯乙烯,乙苯,一氧化碳和氢的第一产物流; 将氢和一氧化碳与第一产物流分离以形成第二流; 从第二流分离氢气以形成包含氢的第三料流和包含一氧化碳的第四料流; 其中第四料流被再循环到反应器中并形成共进料的至少一部分。

    Process for the Oxidative Coupling of Hydrocarbons
    7.
    发明申请
    Process for the Oxidative Coupling of Hydrocarbons 有权
    碳氢化合物的氧化偶合过程

    公开(公告)号:US20130231513A1

    公开(公告)日:2013-09-05

    申请号:US13867295

    申请日:2013-04-22

    IPC分类号: C07C2/84

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷氧化偶联甲苯,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。

    Process for the oxidative coupling of hydrocarbons
    9.
    发明授权
    Process for the oxidative coupling of hydrocarbons 失效
    碳氢化合物的氧化偶合方法

    公开(公告)号:US08450546B2

    公开(公告)日:2013-05-28

    申请号:US12494138

    申请日:2009-06-29

    IPC分类号: C07C2/66

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷氧化偶联甲苯,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。