Anionic polymerization of purified monovinylidene aromatic monomer feed
stock
    7.
    发明授权
    Anionic polymerization of purified monovinylidene aromatic monomer feed stock 失效
    纯化的单亚乙烯基芳族单体原料的阴离子聚合

    公开(公告)号:US4883846A

    公开(公告)日:1989-11-28

    申请号:US40508

    申请日:1987-04-20

    IPC分类号: C08F2/06 C08F4/48 C08F12/04

    CPC分类号: C08F12/04

    摘要: The specification discloses a monovinylidene aromatic polymer having a molecular weight of at least 50,000 and an extremely narrow molecular weight distribution of less than 1.5, preferably with at least 80% by weight of the polymer having a molecular weight within plus or minus 30% of the weight average molecular weight. This polymer is produced through anionic polymerization of a pure feed stock which is first cooled to a temperature at which an anionic initiator preferentially reacts with impurities present in the feed stock and initiates the polymerization reaction but does not substantially propagate styrene polymerization. The initiator is uniformly dispersed into the feed stock while maintaining it at the lower temperature and the feed stock temperature is subsequently increased to a temperature at which polymerization of the sytrene proceeds normally. The resulting polymer is especially well adapted to injection molding in that exceptional strength properties are achieved in combination with good processability, e.g., melt flow rate.

    摘要翻译: 该说明书公开了分子量为至少50,000的单亚乙烯基芳族聚合物和小于1.5的极窄分子量分布,优选具有至少80重量%的聚合物的分子量在正或负30%的范围内 重均分子量。 该聚合物通过纯原料的阴离子聚合制备,其首先冷却至阴离子引发剂优先与存在于原料中的杂质反应并引发聚合反应但基本上不传播苯乙烯聚合的温度。 引发剂均匀分散在原料中,同时将其保持在较低的温度,然后将原料温度升高至正常聚合进入的温度。 所得聚合物特别适用于注射成型,因为优异的强度性能与良好的可加工性,例如熔体流动速率相结合。