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1.发明授权Fluidized-bed catalysts for production of synthetic natural gas by methanization of carbon monoxide 失效用于通过一氧化碳甲烷化生产合成天然气的流化床催化剂
公开(公告)号：US4253991A
公开(公告)日：1981-03-03
申请号：US28428
申请日：1979-04-09
IPC分类号： C07C1/04 , B01J23/755 , B01J23/78 , B01J23/85 , B01J37/00 , C07C1/00 , C07C9/04 , C07C67/00 , C10K3/02 , C10L3/08 , B01J21/08 , B01J21/12
CPC分类号： B01J23/755 , B01J37/0009 , C10L3/08 , B01J37/0036 , Y10S502/504
摘要： A fluidized-bed catalyst for the production of synthetic natural gas by the methanization of carbon monoxide which catalyst in the unreduced state contains nickel oxide on a carrier material resistant to temperature changes, and a hydraulic cement, said catalyst obtainable by compressing a composition comprising a carrier material and nickel oxide in admixture with hydraulic cement as binder in the wetted condition at a pressure above 1600 kp/cm.sup.2 into a formed body, calcining the so-compressed formed body, curing the so-calcined formed body by treatment with water or steam, recalcining the so-cured formed body and comminuting the same and recovering a comminuted material having a particle size fraction ranging from 40 to 350.mu.. Also disclosed is a process for production of synthetic natural gas by fluidized-bed methanization of carbon monoxide with hydrogen employing such a catalyst.
摘要翻译： 一种用于通过一氧化碳甲烷化生产合成天然气的流化床催化剂，其中未还原状态的催化剂在耐温度变化的载体材料上含有氧化镍，以及水硬性水泥，所述催化剂可通过将包含 载体材料和氧化镍与水硬性水泥作为粘合剂在湿度条件下在1600kp / cm2以上的压力下进入成型体，煅烧如此压缩的成形体，通过用水或蒸汽处理固化如此煅烧的成形体 重新煅烧固化的成形体并粉碎，并回收粒度分数为40至350μm的粉碎材料。 还公开了通过使用这种催化剂的氢气通过一氧化碳与氢气的流化床甲烷化生产合成天然气的方法。
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2.发明授权SiO.sub.2 -containing cooper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters 失效含氧化合物氧化铬氧化物催化剂用于加氢脂肪酸和脂肪酸
公开(公告)号：US5217937A
公开(公告)日：1993-06-08
申请号：US795493
申请日：1991-11-21
申请人： Michael Schneider , Gerd Maletz , Karl Kochloefl
发明人： Michael Schneider , Gerd Maletz , Karl Kochloefl
IPC分类号： B01J23/86 , C07B61/00 , C07C29/149 , C07C31/125
CPC分类号： B01J23/868 , C07C29/149 , Y10S502/524
摘要： An SiO.sub.2 -containing copper oxide-chromium oxide catalyst is obtained through heat treatment of copper oxide and chromium oxide, or of a precursor compound convertible into copper oxide or chromium oxide in the presence of an SiO.sub.2 component; it is characterized by the fact that, after the heat treatment,(a) the intensity ratio between the X-ray diffraction lines (XRD reflexes) of the copper oxide with d=0.232 nm and of the CuCr.sub.2 O.sub.4 spinel with d=0.240 nm formed through heat treatment, determined as the ratio of the reflex amplitudes, is 0.7 to 4.0:1, and(b) the copper mass, which is dissolved by stirring 10 g of the catalyst in 100 ml of 10 weight percent acetic acid at 20.degree. C. for 2 minutes, amounts to a maximum of 200 mg.
摘要翻译： 通过氧化铜和氧化铬的热处理，或在SiO2组分存在下可转化为氧化铜或氧化铬的前体化合物，得到含SiO 2的氧化铜 - 氧化铬催化剂; 其特征在于，在热处理后，（a）形成d = 0.232nm的氧化铜的X射线衍射线（XRD反射）与d = 0.240nm的CuCr 2 O 4尖晶石之间的强度比 通过作为反射幅度的比率确定的热处理为0.7〜4.0:1，（b）通过在10g 20重量％乙酸中在20℃下搅拌10g催化剂而溶解的铜质量 2分钟，最多达200毫克。
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公开(公告)号：US4722918A
公开(公告)日：1988-02-02
申请号：US895406
申请日：1986-08-11
IPC分类号： B01J21/16 , B01D53/56 , B01D53/86 , B01D53/94 , B01J8/00 , B01J20/12 , B01J21/12 , B01J23/10 , B01J23/16 , B01J23/22 , B01J23/24 , B01J37/00 , C01B21/20
CPC分类号： B01J21/16 , B01D53/8628 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/1066
摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate). The three-layer silicate is acid-activated while essentially retaining its crystalline layer structure. The three-layer silicate has a cation-exchange capacity of 30 mvals/100 g or more before acid activation. The acid activation lowers the concentration of interlayer cations and increases the BET surface at least 15% and preferably at least 50% in terms of the BET surface of the three-layer silicate before acid activation. The atomic ratio of the silicon in the acid-activated three-layer silicate to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.
摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 该催化剂含有一种或多种氧化物与具有三层结构的硅酸盐（三层硅酸盐）结合的钛，锆，钒，钨，钼或铈中的至少一种。 三层硅酸盐是酸活化的，同时基本保持其结晶层结构。 三层硅酸盐在酸活化之前的阳离子交换容量为30mΩ/ 100g以上。 酸活化降低了层间阳离子的浓度，并且在酸活化之前，三层硅酸盐的BET表面以BET表示增加至少15％，优选至少为50％。 酸活化三层硅酸盐中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。
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4.发明授权
公开(公告)号：US5386066A
公开(公告)日：1995-01-31
申请号：US212686
申请日：1994-03-11
IPC分类号： B01J23/84 , B01J23/889 , C07B61/00 , C07C29/141 , C07C29/149 , C07C31/02 , C07C31/125 , B01J23/32
CPC分类号： B01J23/8892 , C07C29/149
摘要： A catalyst for the hydrogenation of carboxylic acid alkyl esters to higher alcohols which in the oxide form comprises a chemical composition represented by the formulaCuZn.sub.0.5-2 Mn.sub.0.01-0.5 O.sub.xwherein x is the number of oxygen atoms needed per formula unit for electrical neutrality.
摘要翻译： 用于将羧酸烷基酯氢化成氧化物形式的高级醇的催化剂包括由式CuZn0.5-2Mn0.01-0.5Ox表示的化学组成，其中x是每个用于电气的每个配方单元所需的氧原子数 中立性
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5.发明授权Acid-resistant copper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters 失效用于加氢脂肪酸和脂肪酸的耐酸铜氧化物氧化物催化剂
公开(公告)号：US5206203A
公开(公告)日：1993-04-27
申请号：US795491
申请日：1991-11-21
申请人： Michael Schneider , Gerd Maletz , Karl Kochloefl
发明人： Michael Schneider , Gerd Maletz , Karl Kochloefl
IPC分类号： B01J23/86 , C07B61/00 , C07C29/149 , C07C31/02 , C07C31/125
CPC分类号： B01J23/868 , C07C29/149
摘要： Acid-resistant copper oxide-chromium oxide catalysts for hydrogenation of fatty acids or fatty acid mixtures and/or the esters thereof are obtained through heat treatment of copper oxide and chromium oxide or of precursor compounds that are convertible into copper oxide or chromium oxide and which contain aluminum zirconium, cerium and/or lanthanum oxide as an additional metal component. The acid resistance is defined by the fact that the amount of copper which is dissolved by stirring 10 g of the catalyst for 2 minutes in 100 ml of 10 weight percent acetic acid at 20.degree. C., is a maximum of 200 mg.
摘要翻译： 通过热处理氧化铜和氧化铬或可转化为氧化铜或氧化铬的前体化合物，可获得用于脂肪酸或脂肪酸混合物和/或其酯氢化的耐酸氧化铜 - 氧化铬催化剂，其中 含有锆锆，铈和/或氧化镧作为附加金属组分。 耐酸性由以下事实定义：通过在20℃下在100ml 10重量％乙酸中搅拌10g催化剂2分钟而溶解的铜的量最多为200mg。
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公开(公告)号：US4734391A
公开(公告)日：1988-03-29
申请号：US895559
申请日：1986-08-11
CPC分类号： B01J21/16 , B01D53/8628
摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) selected from the group consisting of illite and mica. The atomic ratio of the silicon in the three-layer silicate to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.
摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈，其中一种或多种氧化物与具有三层结构（三层硅酸盐）的硅酸盐形式组合，所述三层结构（三层硅酸盐）选自 由伊利石和云母组成的组。 三层硅酸盐中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。
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7.发明授权
公开(公告)号：US5830425A
公开(公告)日：1998-11-03
申请号：US766391
申请日：1996-12-12
IPC分类号： B01J23/745 , B01J23/83 , B01J23/89 , C01B3/16 , C01B31/20
CPC分类号： B01J23/8946 , B01J23/745 , B01J23/83 , B01J23/8926 , C01B3/16 , Y02P20/52
摘要： The invention relates to a catalyst for conversion of carbon monoxide with steam into hydrogen, carbon dioxide and hydrogen-rich synthesis gases. The conversion can be done at temperatures above roughly 300.degree. C. In addition, a chromium-free catalyst for the aforementioned purpose is described which contains the following in "application form:" (a) 30-98% by weight iron oxide, computed as Fe.sub.2 O.sub.3 ; (b) 0.1-20% by weight copper oxide, computed as CuO; (c) 0.1-20% by weight of an oxide of the rare earth levels computed as Me.sub.2 O.sub.3 (in which Me is a rare earth metal) and/or zirconium oxide, computed as ZrO.sub.2 ; (d) 0.1-30% by weight of at least one oxide of one or several other base metals with an ionic radius from 50 to 72 pm (other than chromium) (e) 0-0.1% by weight of at least one oxide of one or several precious metals from the platinum group; (f) 0-30% by weight barium oxide.
摘要翻译： 本发明涉及一氧化碳与蒸汽转化为氢气，二氧化碳和富氢合成气体的催化剂。 该转化可以在高于约300℃的温度下进行。此外，描述了用于上述目的的无铬催化剂，其在“申请形式”中包含以下内容：（a）30-98重量％的氧化铁，计算 作为Fe2O3; （b）0.1-20重量％的氧化铜，以CuO计算; （c）以ZrO 2计算的作为Me 2 O 3（其中Me是稀土金属）和/或氧化锆计算的稀土含量的0.1-20重量％ （d）0.1-30重量％的至少一种氧化物，其一种或多种其它贱金属的氧化物，其离子半径为50至72μm（不同于铬）（e）0-0.1重量％的至少一种氧化物 来自铂族的一种或几种贵金属; （f）0-30重量％的氧化钡。
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公开(公告)号：US5407886A
公开(公告)日：1995-04-18
申请号：US200585
申请日：1994-02-22
IPC分类号： B01J23/72 , B01J23/70 , B01J23/74 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/03 , C07C5/10 , C07C13/18
CPC分类号： B01J37/031 , B01J23/70 , B01J35/023 , B01J35/10 , C07C5/10 , B01J35/006 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , C07C2101/14 , C07C2521/08 , C07C2523/00 , C07C2523/755
摘要： A molded catalyst body that contains in a reduced state a metal of the ferrous group and/or copper on a support and is characterized by the following features:(a) Metal content: about 5 to about 40 weight percent, based on the total weight of the catalyst;(b) Metal-crystal size: .ltoreq.3 nm;(c) Volume of the pores with a diameter of 7.5 nm to 15 .mu.m: 0.05 to 0.9 ml/g catalyst;(d) BET surface area: 80-400 m.sup.2 /g catalyst;(e) Fracture strength: >30N (based on cylindrical molded body with a diameter of 1.5 mm and a length of 5 mm);(f) Bulk density: 250-350 g/l.
摘要翻译： 一种模制催化剂体，其在还原状态下含有亚铁基团和/或铜的金属在载体上，其特征在于以下特征：（a）金属含量：约5至约40重量％，基于总重量 的催化剂; （b）金属晶体尺寸： 30N（基于直径为1.5mm，长度为5mm的圆筒形成型体）; （f）体积密度：250-350g / l。
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9.发明授权Ferruginous catalyst for decreasing the content of nitrogen oxides in flue gases 失效用于降低烟气中氮氧化物含量的铁质催化剂
公开(公告)号：US4774213A
公开(公告)日：1988-09-27
申请号：US940361
申请日：1986-12-11
CPC分类号： B01D53/8628 , B01J21/16
摘要： A ferruginous catalyst for decreasing the content of nitrogen oxide in flue gases. The catalyst comprising an active constituent in the form of a combination of a compound of iron and of an acid aluminosilicate that has a layered structure.
摘要翻译： 用于降低烟道气中氮氧化物含量的铁质催化剂。 该催化剂包含具有层状结构的铁化合物和酸性硅铝酸盐的组合形式的活性成分。
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公开(公告)号：US4719192A
公开(公告)日：1988-01-12
申请号：US895558
申请日：1986-08-11
IPC分类号： B01J21/16 , B01D53/56 , B01D53/86 , B01D53/94 , B01J8/00 , B01J20/12 , B01J21/12 , B01J23/10 , B01J23/16 , B01J23/22 , B01J23/24 , B01J37/00 , C01B21/20
CPC分类号： B01J21/16 , B01D53/8628 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/1066
摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) which is or comprises talc. The three-layer silicate is preferably acid-activated while essentially retaining its crystalline layer structure and being not yet X-ray amorphous. The acid activation increases the BET surface area at least 15% and preferably at least 50% in terms of the BET surface area of the talc before acid activation. The atomic ratio of the silicon in the talc to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.
摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈，其中一种或多种氧化物与具有三层结构的硅酸盐（三层硅酸盐）结合的形式，其是或 包括滑石。 三层硅酸盐优选是酸活化的，同时基本保持其结晶层结构并且还不是X射线无定形的。 在酸活化之前，酸活化使得BET表面积以滑石粉的BET表面积计增加至少15％，优选至少50％。 滑石中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。
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