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公开(公告)号：US08017742B2
公开(公告)日：2011-09-13
申请号：US10465402
申请日：2003-06-19
申请人： Kazuo Sakurai , Seiji Shinkai , Taro Kimura , Kengo Tabata , Kazuya Koumoto , Oliver Gronwald
发明人： Kazuo Sakurai , Seiji Shinkai , Taro Kimura , Kengo Tabata , Kazuya Koumoto , Oliver Gronwald
CPC分类号： C07H15/04 , A61K47/61 , A61K47/645 , A61K48/00 , C07B2200/11 , C07H21/00 , C08B37/0024 , C12N15/87
摘要： Disclosed is a gene carrier composed of a hydrogen-bonding polymer having a polymer chain with hydrogen-bonding sites formed on the polymer chain, in which the polymer chain has a conformation similar to the conformation of a nucleic acid, and particularly, the polymer chain has helix parameters similar to the helix parameters of a nucleic acid of a helix structure. In a preferred embodiment, the hydrogen-bonding polymer is composed of β-1,3-glucan such as schizophyllan. The carrier can be expected to be applied as a vector and a separator for nucleic acids because it is capable of interacting with a nucleic acid to form a complex with the nucleic acid and thus carrying the nucleic acid.
摘要翻译： 公开了一种基因载体，其由具有在聚合物链上形成的氢键位置的聚合物链的氢键聚合物组成，其中聚合物链具有与核酸构象相似的构象，特别是聚合物链 具有类似于螺旋结构的核酸的螺旋参数的螺旋参数。 在一个优选的实施方案中，氢键聚合物由诸如裂枝菌碱等的β-葡聚糖组成。 可以期望载体作为核酸的载体和分离子应用，因为它能够与核酸相互作用以与核酸形成复合物，从而携带核酸。
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公开(公告)号：US20110301230A1
公开(公告)日：2011-12-08
申请号：US13214580
申请日：2011-08-22
申请人： Kazuo SAKURAI , Seiji Shinkai , Taro Kimura , Kengo Tabata , Kazuya Koumoto , Oliver Gronwald
发明人： Kazuo SAKURAI , Seiji Shinkai , Taro Kimura , Kengo Tabata , Kazuya Koumoto , Oliver Gronwald
CPC分类号： C07H15/04 , A61K47/61 , A61K47/645 , A61K48/00 , C07B2200/11 , C07H21/00 , C08B37/0024 , C12N15/87
摘要： Disclosed is a gene carrier composed of a hydrogen-bonding polymer having a polymer chain with hydrogen-bonding sites formed on the polymer chain, in which the polymer chain has a conformation similar to the conformation of a nucleic acid, and particularly, the polymer chain has helix parameters similar to the helix parameters of a nucleic acid of a helix structure. In a preferred embodiment, the hydrogen-bonding polymer is composed of β-1,3-glucan such as schizophyllan. The carrier can be expected to be applied as a vector and a separator for nucleic acids because it is capable of interacting with a nucleic acid to form a complex with the nucleic acid and thus carrying the nucleic acid.
摘要翻译： 公开了一种基因载体，其由具有在聚合物链上形成的氢键位置的聚合物链的氢键聚合物构成，其中聚合物链具有与核酸构象相似的构象，特别是聚合物链 具有类似于螺旋结构的核酸的螺旋参数的螺旋参数。 在一个优选的实施方案中，氢键聚合物由诸如裂枝菌碱等的β-葡聚糖组成。 可以期望载体作为核酸的载体和分离子应用，因为它能够与核酸相互作用以与核酸形成复合物，从而携带核酸。
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3.发明申请MECHANICALLY STABILIZED POLYAZOLES COMPRISING AT LEAST ONE POLYVINYL ALCOHOL 有权包含至少一种聚乙烯醇的机械稳定聚对苯二甲酸公开(公告)号：US20120289654A1
公开(公告)日：2012-11-15
申请号：US13467485
申请日：2012-05-09
CPC分类号： C08G73/22 , C08G73/0616 , C08G73/0633 , C08G73/0694 , C08G73/08 , C08K3/24 , C08L79/04 , C08L79/06 , C08L29/04
摘要： A process for preparing mechanically stabilized polyazoles, comprising the following steps: I) treating at least one polyazole having at least one amino group in a repeat unit with a solution comprising (i) at least one strong acid and (ii) at least one stabilizing reagent, the total content of stabilizing reagents in the solution being in the range from 0.01 to 30% by weight, II) performing the stabilization reaction directly and/or in a subsequent processing step by heating to a temperature greater than 25° C., the stabilizing reagent used being at least one polyvinyl alcohol. The polyazoles thus obtainable are notable especially for a high conductivity and a very good mechanical stability. They are therefore especially suitable for applications in fuel cells.
摘要翻译： 一种制备机械稳定化的多唑的方法，包括以下步骤：I）用包含（i）至少一种强酸和（ii）至少一种稳定的酸的溶液，在重复单元中处理至少一种具有至少一个氨基的聚唑 试剂，溶液中稳定试剂的总含量在0.01至30重量％的范围内，II）直接和/或在随后的加工步骤中通过加热至大于25℃的温度进行稳定化反应， 使用的稳定剂为至少一种聚乙烯醇。 因此获得的聚唑特别是对于高导电性和非常好的机械稳定性而言尤其如此。 因此，它们特别适用于燃料电池中的应用。
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公开(公告)号：US20120184702A1
公开(公告)日：2012-07-19
申请号：US13353780
申请日：2012-01-19
CPC分类号： C08G77/52 , B01J20/223 , B01J20/3078 , B01J20/3085 , C01B3/0015 , C08G79/00 , C08G79/04 , C08G79/08 , H01M4/13 , H01M4/362 , Y02E60/328
摘要： The present invention relates to a process for producing composite materials which consist essentially of a) at least one oxidic phase; and b) at least one organic polymer phase; by copolymerizing at least one compound A selected from aryloxy metalates, aryloxy semimetalates and aryloxy esters of nonmetals which form oxo acids and are different than carbon and nitrogen with at least one compound B selected from formaldehyde and formaldehyde equivalents, in a reaction medium which is essentially anhydrous, wherein the compound B is used in such an amount that the molar ratio of formaldehyde to the aryloxy groups in compound A is at least 0.9:1.
摘要翻译： 本发明涉及一种生产复合材料的方法，其基本上由a）至少一种氧化相组成; 和b）至少一个有机聚合物相; 通过使本反应介质中的至少一种选自芳氧基金属盐，芳氧基半金属盐和非金属的芳氧基酯与至少一种选自甲醛和甲醛当量的化合物B不同的碳和氮的芳氧基酯共聚合， 无水，其中化合物B的用量使得化合物A中甲醛与芳氧基的摩尔比至少为0.9:1。
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公开(公告)号：US09105937B2
公开(公告)日：2015-08-11
申请号：US13489101
申请日：2012-06-05
IPC分类号： H01M10/056 , H01M4/60 , H01M10/02 , H01B1/04 , C08G75/14 , H01M10/05 , H01B1/24 , H01M4/38 , H01M4/58 , H01M10/052 , H01M4/36 , H01M4/587 , H01M4/62 , H01M10/0568
CPC分类号： H01M10/05 , H01B1/24 , H01M4/364 , H01M4/382 , H01M4/5815 , H01M4/587 , H01M4/602 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0568 , H01M2220/10 , H01M2220/20 , Y02E60/122
摘要： The present invention relates to electrode materials for charged electrical cells, comprising at least one polymer comprising polysulfide bridges, and carbon in a polymorph comprising at least 60% sp2-hybridized carbon atoms. The present invention further relates to electrical cells comprising the inventive electrode material, to specific polymers comprising polysulfide bridges, to processes for preparation thereof and to the use of the inventive cells.
摘要翻译： 本发明涉及带电电池的电极材料，其包含至少一种包含多硫键的聚合物和包含至少60％sp2杂化碳原子的多晶型物中的碳。 本发明还涉及包含本发明电极材料，包含多硫桥的特定聚合物，其制备方法和本发明细胞的用途的电池。
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公开(公告)号：US20110262835A1
公开(公告)日：2011-10-27
申请号：US13091341
申请日：2011-04-21
申请人： Ömer Ünsal , Sigmar Bräuninger , Jörg Belack , Oliver Gronwald
发明人： Ömer Ünsal , Sigmar Bräuninger , Jörg Belack , Oliver Gronwald
CPC分类号： H01M8/103 , C08J5/2256 , H01M8/1027 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1081 , Y02E60/521 , Y02P70/56
摘要： Proton-conducting polymer electrolyte membrane based on a polyazole salt of an inorganic or organic acid which is doped with an acid as electrolyte, wherein the polyazole salt of the organic or inorganic acid has a lower solubility in the acid used as electrolyte than the polyazole salt of the acid used as electrolyte, a process for producing the inventive proton-conducting polymer electrolyte membrane, a membrane-electrode assembly comprising at least two electrochemically active electrodes which are separated by a polymer electrolyte membrane, wherein the polymer electrolyte membrane is a proton-conducting polymer electrolyte membrane according to the invention, and a fuel cell comprising at least one membrane-electrode assembly according to the invention.
摘要翻译： 基于掺杂有酸作为电解质的无机或有机酸的多唑盐的质子导电聚合物电解质膜，其中有机或无机酸的聚唑盐在作为电解质的酸中的溶解度低于多唑盐 的用作电解质的酸，制造本发明的导电聚合物电解质膜的方法，包括由聚合物电解质膜分离的至少两个电化学活性电极的膜 - 电极组件，其中所述聚合物电解质膜是质子 - 根据本发明的导电聚合物电解质膜，以及包括至少一个根据本发明的膜 - 电极组件的燃料电池。
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公开(公告)号：US20100068593A1
公开(公告)日：2010-03-18
申请号：US12555021
申请日：2009-09-08
申请人： Annette Reiche , Dieter Melzner , Ulrich Mähr , Oliver Gronwald , Werner Obrecht , Thomas Früh , Torsten Ziser
发明人： Annette Reiche , Dieter Melzner , Ulrich Mähr , Oliver Gronwald , Werner Obrecht , Thomas Früh , Torsten Ziser
CPC分类号： H01M8/1069 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1046 , H01M8/1048 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： The present invention relates to a polymer electrolyte membrane for fuel cells, comprising a polymer matrix of at least one basic polymer and one or more doping agents, wherein particles containing ionogenic groups and having a mean particle diameter in the nanometer range are embedded in the polymer matrix and the particles containing ionogenic groups are distributed homogeneously in the polymer matrix in a concentration of less than 50% relative to the weight of the polymer matrix, as well as to the production and use of same, especially in high-temperature fuel cells.
摘要翻译： 本发明涉及一种用于燃料电池的聚合物电解质膜，其包含至少一种碱性聚合物和一种或多种掺杂剂的聚合物基质，其中含有离子型基团并且具有纳米范围内的平均粒径的颗粒嵌入聚合物 基质，并且含有离子基团的颗粒相对于聚合物基质的重量，以及其生产和使用，特别是在高温燃料电池中的浓度小于50％，均匀分布在聚合物基质中。
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公开(公告)号：US09048478B2
公开(公告)日：2015-06-02
申请号：US13091341
申请日：2011-04-21
申请人： Ömer Ünsal , Sigmar Bräuninger , Jörg Belack , Oliver Gronwald
发明人： Ömer Ünsal , Sigmar Bräuninger , Jörg Belack , Oliver Gronwald
CPC分类号： H01M8/103 , C08J5/2256 , H01M8/1027 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1081 , Y02E60/521 , Y02P70/56
摘要： Proton-conducting polymer electrolyte membrane based on a polyazole salt of an inorganic or organic acid which is doped with an acid as electrolyte, wherein the polyazole salt of the organic or inorganic acid has a lower solubility in the acid used as electrolyte than the polyazole salt of the acid used as electrolyte, a process for producing the inventive proton-conducting polymer electrolyte membrane, a membrane-electrode assembly comprising at least two electrochemically active electrodes which are separated by a polymer electrolyte membrane, wherein the polymer electrolyte membrane is a proton-conducting polymer electrolyte membrane according to the invention, and a fuel cell comprising at least one membrane-electrode assembly according to the invention.
摘要翻译： 基于掺杂有酸作为电解质的无机或有机酸的多唑盐的质子导电聚合物电解质膜，其中有机或无机酸的聚唑盐在作为电解质的酸中的溶解度低于多唑盐 的用作电解质的酸，制造本发明的导电聚合物电解质膜的方法，包括由聚合物电解质膜分离的至少两个电化学活性电极的膜 - 电极组件，其中所述聚合物电解质膜是质子 - 根据本发明的导电聚合物电解质膜，以及包括至少一个根据本发明的膜 - 电极组件的燃料电池。
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公开(公告)号：US20120251884A1
公开(公告)日：2012-10-04
申请号：US13437291
申请日：2012-04-02
CPC分类号： H01M10/0525 , H01M2/166 , H01M4/386 , H01M4/387 , H01M4/505
摘要： The present invention relates to electrochemical cells comprising (A) at least one cathode comprising at least one lithium ion-containing transition metal oxide comprising manganese as a transition metal, (B) at least one anode, and (C) at least one layer comprising (a) at least one ion exchanger in particulate form, (b) at least one binder.
摘要翻译： 本发明涉及电化学电池，其包括（A）至少一个阴极，其包含至少一种含有锂离子的过渡金属氧化物，其包含锰作为过渡金属，（B）至少一个阳极，和（C）至少一层包含 （a）至少一种颗粒形式的离子交换剂，（b）至少一种粘合剂。
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公开(公告)号：US20050209421A1
公开(公告)日：2005-09-22
申请号：US11038571
申请日：2005-01-21
摘要： The object of the present invention is to provide a vinyl monomer containing a superacidic ester group useful in the production of ionomers for polymer electrolyte fuel cells, and its production process. In addition, another object of the present invention is to provide a polymer produced from said vinyl monomer and its production process, as well as a process for producing a polymer containing a superacidic group from said polymer. The inventive vinyl monomer contains a haloalkyl ester group of a superacid, wherein the number of carbon atoms of the haloalkyl ester group is no more than 10, and the halogen in the haloalkyl group is chlorine and/or fluorine. A polymer containing said vinyl monomer as a repeating unit can be converted to a polymer containing a superacid group using at least one procedure of 1) heat treating at 50° C. to 350° C., and 2) contacting with a protic compound.
摘要翻译： 本发明的目的是提供一种含有用于生产聚合物电解质燃料电池用离聚物的超酸酯基的乙烯基单体及其制造方法。 此外，本发明的另一个目的是提供由所述乙烯基单体制备的聚合物及其制备方法，以及从所述聚合物制备含有超酸基团的聚合物的方法。 本发明的乙烯基单体含有超酸的卤代烷基酯基，其中卤代烷基酯基的碳原子数不超过10，卤代烷基中的卤素是氯和/或氟。 含有所述乙烯基单体作为重复单元的聚合物可以使用至少一种如下步骤转化成含有超强酸基团的聚合物：1）在50℃至350℃下进行热处理，和2）与质子化合物接触。
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