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    POLYESTER COMPOSITION AND POLYESTER MOLDED ARTICLE COMPRISING THE SAME
    3.
    发明申请
    POLYESTER COMPOSITION AND POLYESTER MOLDED ARTICLE COMPRISING THE SAME 审中-公开
    聚酯组合物和包含其的聚酯模塑制品

    公开(公告)号：US20110003100A1

    公开(公告)日：2011-01-06

    申请号：US12303230

    申请日：2007-05-30

    申请人： Keiichiro Togawa ,  Seiji Nakayama ,  Gaku Maruyama ,  Yoshiko Akitomo ,  Yoshinao Matsui ,  Yoshitaka Eto

    发明人： Keiichiro Togawa ,  Seiji Nakayama ,  Gaku Maruyama ,  Yoshiko Akitomo ,  Yoshinao Matsui ,  Yoshitaka Eto

    IPC分类号： C08L85/02 ,  B32B27/08

    CPC分类号： C08L67/02 ,  C08L77/00 ,  Y10T428/1352 ,  C08L2666/20

    摘要： A polyester composition comprising 99.9 to 80 wt % of a thermoplastic polyester containing an antimony compound and 0.1 to 20 wt % of a partially aromatic polyamide, wherein a 4 mm-thick molded plate formed by molding the thermoplastic polyester at 290° C. has a haze value of 10% or lower, and wherein the phosphorus atom content in the partially aromatic polyamide (P1), the partially aromatic polyamide content in the polyester composition (A), and the antimony atom content in the thermoplastic polyester (S) satisfy a specific formula, wherein a 4 mm-thick molded plate produced by molding the polyester composition at 290° C. has a haze value of 20% or lower. The polyester composition can be molded into a hollow molded article (e.g., a bottle) at a high productivity rate, which is not deteriorated in transparency or color, and which is excellent in flavor-conserving property, thermal stability and gas-barrier property.

    摘要翻译： 包含99.9〜80重量％的含有锑化合物的热塑性聚酯和0.1〜20重量％的部分芳香族聚酰胺的聚酯组合物，其中通过在290℃下成型所述热塑性聚酯而形成的4mm厚的模制板具有 雾度值为10％以下，其中，部分芳香族聚酰胺（P1）中的磷原子含量，聚酯组合物（A）中的部分芳香族聚酰胺含量和热塑性聚酯（S）中的锑原子含量满足 其中通过在290℃下成型聚酯组合物制成的4mm厚的模制板具有20％以下的雾度值。 聚酯组合物可以以高生产率成型为中空成型体（例如，瓶），其透明度或颜色不劣化，并且具有优良的风味保存性，热稳定性和气体阻隔性。

    HYDROLYSIS-RESISTANT POLYESTER FILM
    4.
    发明申请
    HYDROLYSIS-RESISTANT POLYESTER FILM 有权
    耐水解聚酯薄膜

    公开(公告)号：US20130139883A1

    公开(公告)日：2013-06-06

    申请号：US13817690

    申请日：2011-08-17

    申请人： Keiichiro Togawa ,  Hideto Ohashi ,  Toshifumi Unrinin ,  Hiroshi Shibano

    发明人： Keiichiro Togawa ,  Hideto Ohashi ,  Toshifumi Unrinin ,  Hiroshi Shibano

    IPC分类号： C09D5/00 ,  H01L31/0216

    CPC分类号： C09D5/00 ,  C08J5/18 ,  C08J2367/02 ,  C08K5/13 ,  H01L31/0216 ,  H01L31/0481 ,  H01L31/049 ,  Y02E10/50

    摘要： Provided is a hydrolysis-resistant polyester film having a low acid value due to suppression of acid value-increase during film formation. The hydrolysis-resistant polyester film of the present invention is a polyester film comprising a polyester resin composition, wherein the polyester resin composition that forms the films comprises 0.03 to 6.7 eq/ton of hindered phenol structural units, an acid value of a polyester that forms the film is less than 25 eq/ton, and an intrinsic viscosity of a polyester that forms the film is more than 0.64 dL/g and not less than 0.90 dL/g.

    摘要翻译： 提供由于抑制成膜期间的酸值增加而具有低酸值的耐水解聚酯膜。 本发明的耐水解聚酯膜是包含聚酯树脂组合物的聚酯膜，其中形成膜的聚酯树脂组合物包含0.03至6.7当量/位的受阻酚结构单元，形成聚酯的酸值 膜的含量小于25eq / ton，形成膜的聚酯的特性粘度大于0.64dL / g，不小于0.90dL / g。

    Aqueous polyester dispersion suitable for use as a coating composition
    5.
    发明授权
    Aqueous polyester dispersion suitable for use as a coating composition 失效
    适合用作涂料组合物的水性聚酯分散体

    公开(公告)号：US5510417A

    公开(公告)日：1996-04-23

    申请号：US334147

    申请日：1994-11-04

    申请人： Hiroshi Tachika ,  Keiichiro Togawa ,  Hiroshi Fujimoto

    发明人： Hiroshi Tachika ,  Keiichiro Togawa ,  Hiroshi Fujimoto

    IPC分类号： C08G63/672 ,  C08G63/688 ,  C08K5/00 ,  C09D167/02 ,  C08J3/03 ,  C08K3/20 ,  C08L77/00

    CPC分类号： C09D167/025 ,  C08G63/672 ,  C08G63/6886 ,  C08K5/0008

    摘要： An aqueous dispersion comprising (A) a polyester comprising an aromatic dicarboxylic acid, an addition product of bisphenol A with ethylene oxide and/or propylene oxide, and a dicarboxylic acid having a metal base of sulfonic acid and/or a polyol having a metal base of sulfonic acid, (B) a water-soluble organic compound having a boiling temperature of about 60.degree. C. to about 250.degree. C., (C) water and (D) a neutralizer; the amounts of the components A, B, C and D satisfying the following ratios of (1) to (3):(1) A/B/C being about 1% to about 70% by weight/about 0% to about 69% by weight/about 9% to about 99% by weight,(2) B/(B+C) being about 0 to about 0.7 (weight ratio), and(3) the equivalent ratio of D to A being about 0.1 to about 20.

    摘要翻译： 一种水分散体，其包含（A）包含芳族二羧酸，双酚A与环氧乙烷和/或环氧丙烷的加成产物的聚酯和具有磺酸金属碱和/或具有金属碱的多元醇的二羧酸 的磺酸，（B）沸点为约60℃至约250℃的水溶性有机化合物，（C）水和（D）中和剂; 组分A，B，C和D的量满足（1）至（3）的以下比例：（1）A / B / C为约1％至约70％重量/约0％至约69 重量％/约9％至约99％重量，（2）B /（B + C）为约0至约0.7（重量比），和（3）D与A的当量比为约0.1至 约20。

    Aqueous dispersion
    6.
    发明授权
    Aqueous dispersion 失效
    水分散体

    公开(公告)号：US5356989A

    公开(公告)日：1994-10-18

    申请号：US183136

    申请日：1994-01-18

    申请人： Hiroshi Tachika ,  Keiichiro Togawa ,  Hiroshi Fujimoto

    发明人： Hiroshi Tachika ,  Keiichiro Togawa ,  Hiroshi Fujimoto

    IPC分类号： C08G63/688 ,  C08J3/03 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C08G63/20

    CPC分类号： C08J3/03 ,  C08G63/6886 ,  C08J2367/02

    摘要： An aqueous dispersion suitable for use as various coatings is provided. The dispersion includes polyester resin (A), a water soluble organic compound (B), water (C), and a neutralizer (D). The polyester resin has an acid number of 50 equivalents/10.sup.6 g or more. The polycarboxylic acid component of the resin contains aromatic dicarboxylic acid having no metal sulfonate groups in an amount in the range of 50 to 99.99 mole percent, and dicarboxylic acid having a metal sulfonate group in an amount in the range of 0.01 to 20 mole percent based on the total moles of the polycarboxylic acid component. The polyol component of the resin contains diol in an amount in the range of 30 to 100 mole percent based on the total moles of the polyol component. The diol has an alkyl group with 1 to 3 carbon atoms on a side chain, and the total number of carbon atoms in the diol is 6 to 25. The water soluble organic compound has a boiling point in the range of 60.degree. to 250.degree. C. The components (A), (B), and (C) are contained in the dispersion in an amount in the range of 1 to 70 percent by weight, 0 to 69 percent by weight, and 9 to 99 percent by weight, respectively. Further, the components (A), (B), (C), and (D) satisfy the following expressions (1) and (2):B/(B+C) (weight ratio)=0-0.7 (1)D/A (equivalent ratio)=0.1-20 (2).

    摘要翻译： 提供适合用作各种涂层的水性分散体。 分散体包括聚酯树脂（A），水溶性有机化合物（B），水（C）和中和剂（D）。 聚酯树脂的酸值为50当量/ 106g以上。 树脂的多元羧酸成分含有金属磺酸盐基的芳香族二羧酸的量为50〜99.99摩尔％，金属磺酸盐基的二羧酸的量为0.01〜20摩尔％ 关于多元羧酸组分的总摩尔数。 树脂的多元醇成分含有相对于多元醇成分的总摩尔数为30〜100摩尔％的量的二醇。 二醇在侧链上具有1〜3个碳原子的烷基，二醇中的碳原子总数为6〜25。水溶性有机化合物的沸点为60〜250℃ C.分散体中的组分（A），（B）和（C）的含量范围为1-70重量％，0-69重量％和9-99重量％ 分别。 另外，组分（A），（B），（C）和（D）满足下列表达式（1）和（2）：B /（B + C）（重量比）= 0-0.7（1） D / A（当量比）= 0.1-20（2）。

    POLYESTER RESIN
    8.
    发明申请
    POLYESTER RESIN 审中-公开
    聚酯树脂

    公开(公告)号：US20130267674A1

    公开(公告)日：2013-10-10

    申请号：US13885482

    申请日：2011-11-15

    申请人： Toshiyuki Kita ,  Kunihiro Maeda ,  Keiichiro Togawa

    发明人： Toshiyuki Kita ,  Kunihiro Maeda ,  Keiichiro Togawa

    IPC分类号： C08G63/84

    CPC分类号： C08G63/84 ,  C08G63/87

    摘要： The present invention provides a polyester resin obtained by using an aluminum compound and a phosphorus compound as a polymerization catalyst, containing greater than or equal to 85% by mol of an ethylene terephthalate structural unit, wherein the content of an aluminum-based contaminant with respect to the mass of the polyester resin is less than or equal to 100 ppb, and the content of a phosphorus compound represented by a specific structure is 5 to 11 ppm. The present invention is able to provide a polyester resin capable of keeping high transparency of the molded body when it is sequentially polymerized and produced on a commercial scale, and having such characteristics that crystallization of a mouth plug part can be easily controlled when it is used for a heat resistant bottle, and whitening is less likely to occur at the time of heating in molding when it is used as a sheet for molding.

    摘要翻译： 本发明提供一种通过使用铝化合物和磷化合物作为聚合催化剂获得的聚酯树脂，其含有大于或等于85摩尔％的对苯二甲酸乙二醇酯结构单元，其中铝基污染物的含量相对于 相对于聚酯树脂的质量小于或等于100ppb，由特定结构表示的磷化合物的含量为5〜11ppm。 本发明能够提供一种在商业规模顺序地聚合和制造时能够保持成型体的高透明度的聚酯树脂，并且具有这样的特征，即当使用时可以容易地控制口塞部件的结晶 对于耐热瓶子，当成型时用于加热成型时，加热时不易发生白化。

    Coating resin compositions
    9.
    发明授权
    Coating resin compositions 失效
    涂料树脂组合物

    公开(公告)号：US5563223A

    公开(公告)日：1996-10-08

    申请号：US496557

    申请日：1995-06-29

    申请人： Hiroshi Tachika ,  Kenji Ohama ,  Keiichiro Togawa ,  Masami Oka

    发明人： Hiroshi Tachika ,  Kenji Ohama ,  Keiichiro Togawa ,  Masami Oka

    IPC分类号： C08G63/183 ,  C08G63/672 ,  C09D167/02 ,  C08F20/00

    CPC分类号： C08G63/183 ,  C08G63/672 ,  C09D167/02 ,  C09D167/025

    摘要： A coat resin composition comprising a polyester (A) comprising an acid component comprising an aromatic dicarboxylic acid in a proportion of 50-100% by mole relative to the entire acid component and other carboxylic acid(s) in a proportion of 50-0% by mole relative to the entire acid component, and a glycol component comprising 2-methyl-1,3-propanediol and/or 1,3-propanediol in a proportion of 1-25% by mole relative to the entire glycol component and an alkylene glycol having 5 to 10 carbon atoms in a proportion of 75-99% by mole relative to the entire glycol component, or an alicyclic glycol in a proportion of 20-85% by mole relative to the entire glycol component, an addition product of bisphenol A with alkylene oxide in a proportion of 80-15% by mole relative to the entire glycol component and other glycol(s) in a proportion of 0-50% by mole relative to the entire glycol component, wherein the total of the glycols is 100% by mole, the polyester (A) having a reduced viscosity of not less than 0.2 dl/g; and a curing agent (B) reactive with the polyester (A), in a proportion of (A)/(B)=99/1--50/50 (weight ratio). The present invention provides coating resin compositions capable of forming a coating film having superior processability, hardness, stain resistance, weatherability, resistance to staining by foodstuffs, or superior boiling water resistance, corrosion resistance, acid resistance and scratch property.

    摘要翻译： 一种涂料树脂组合物，其包含聚酯（A），其包含相对于全部酸成分为50-100摩尔％的比例为50〜100重量％的芳族二羧酸的酸成分， 和相对于整个二醇组分的1-25％摩尔比例的2-甲基-1,3-丙二醇和/或1,3-丙二醇的二元醇组分和亚烷基 相对于整个二醇组分为75-99摩尔％的碳原子数为5〜10的二元醇，相对于二醇成分为20〜85摩尔％的脂环族二醇，双酚的加成物 A相对于整个二醇组分和其它二元醇的比例为80-15摩尔％，相对于整个二醇组分为0-50摩尔％，其中二醇的总和​​为 100摩尔％，比较粘度不大的聚酯（A） 小于0.2dl / g; 和（A）/（B）= 99 / 1-50 / 50（重量比）的比例与聚酯（A）反应的固化剂（B）。 本发明提供能够形成具有优异的加工性，硬度，耐污染性，耐候性，耐食品性，耐沸水性，耐腐蚀性，耐酸性和耐划伤性的涂膜的涂料树脂组合物。