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1.发明申请Adamantane derivatives and resin compositions using the same as raw material 有权金刚烷衍生物和使用与原料相同的树脂组合物公开(公告)号：US20050158662A1
公开(公告)日：2005-07-21
申请号：US11032095
申请日：2005-01-11
IPC分类号： C07C69/00 , C08F220/28 , G03C1/76 , G03F7/039
CPC分类号： C07C69/54 , C07C2603/74 , C08F220/28 , G03F7/0397
摘要： The adamantane derivatives of the present invention which are represented by the general formula (1): wherein X is a hydrogen atom, alkyl, halogen-containing alkyl, halogen, or hydroxyl-, halogen-, nitrile- or ether-containing hydrocarbyl, and a plurality of X groups, if any, may be the same or different from each other; n1 is an integer of 1 to 14; R1 to R4 may be the same or different from each other and are independently alkyl or halogen-containing alkyl; and Y1 and Y2 may be the same or different from each other and are independently a hydrogen atom or a group represented by the general formula (2): wherein R5 to R7 may be the same or different from each other and are independently a hydrogen atom, alkyl, halogen or halogen-containing alkyl, are excellent in optical properties, heat resistance and acid-dissociating property, and useful as crosslinking-type resins, optical materials such as optical fibers, light wave guides, optical disk substrates and photoresists as well as raw materials thereof, intermediate products of medicines or agricultural chemicals, and various other industrial products.
摘要翻译： 由通式（1）表示的本发明的金刚烷衍生物：其中X是氢原子，烷基，含卤素的烷基，卤素或羟基，卤素，腈或醚的烃基，和 多个X组（如果有的话）可以相同或不同; n 1是1至14的整数; R 1至R 4可以彼此相同或不同，并且独立地为烷基或含卤素的烷基; 和Y 1和Y 2可以彼此相同或不同，并且独立地为氢原子或由通式（2）表示的基团：其中R' R 5和R 7可以相同或不同，并且独立地为氢原子，烷基，卤素或含卤素的烷基，光学性能，耐热性均优异 和酸解离性，并且可用作交联型树脂，光学材料如光纤，光波导，光盘基片和光致抗蚀剂以及其原料，药物或农药的中间产物，以及各种其它工业产品 。
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2.发明授权Adamantane derivatives and resin compositions using the same as raw material 有权金刚烷衍生物和使用与原料相同的树脂组合物公开(公告)号：US07078562B2
公开(公告)日：2006-07-18
申请号：US11032095
申请日：2005-01-11
IPC分类号： C07C69/62
CPC分类号： C07C69/54 , C07C2603/74 , C08F220/28 , G03F7/0397
摘要： The adamantane derivatives of the present invention which are represented by the general formula (1): wherein X is a hydrogen atom, alkyl, halogen-containing alkyl, halogen, or hydroxyl-, halogen-, nitrile- or ether-containing hydrocarbyl, and a plurality of X groups, if any, may be the same or different from each other; n1 is an integer of 1 to 14; R1 to R4 may be the same or different from each other and are independently alkyl or halogen-containing alkyl; and Y1 and Y2 may be the same or different from each other and are independently a hydrogen atom or a group represented by the general formula (2): wherein R5 to R7 may be the same or different from each other and are independently a hydrogen atom, alkyl, halogen or halogen-containing alkyl, are excellent in optical properties, heat resistance and acid-dissociating property, and useful as crosslinking-type resins, optical materials such as optical fibers, light wave guides, optical disk substrates and photoresists as well as raw materials thereof, intermediate products of medicines or agricultural chemicals, and various other industrial products.
摘要翻译： 由通式（1）表示的本发明的金刚烷衍生物：其中X是氢原子，烷基，含卤素的烷基，卤素或羟基，卤素，腈或醚的烃基，和 多个X组（如果有的话）可以相同或不同; n 1是1至14的整数; R 1至R 4可以彼此相同或不同，并且独立地为烷基或含卤素的烷基; 和Y 1和Y 2可以彼此相同或不同，并且独立地为氢原子或由通式（2）表示的基团：其中R' R 5和R 7可以相同或不同，并且独立地为氢原子，烷基，卤素或含卤素的烷基，光学性能，耐热性均优异 和酸解离性，并且可用作交联型树脂，光学材料如光纤，光波导，光盘基片和光致抗蚀剂以及其原料，药物或农药的中间产物，以及各种其它工业产品 。
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公开(公告)号：US07067692B2
公开(公告)日：2006-06-27
申请号：US10825118
申请日：2004-04-16
IPC分类号： C00C67/26
CPC分类号： C07C67/03 , C07C2603/74 , C07C69/54
摘要： In the present invention, an adamantyl acrylate compound is produced by a process comprising a first step and a second step without using acid halide. In the first step, a 2-adamantanone compound is reacted with a hydrocarbyl halide in the presence of lithium metal to form an adamantanolate intermediate that is then reacted with an acrylic ester compound in the second step to produce the aimed adamantyl acrylate compound.
摘要翻译： 在本发明中，通过包括不使用酰卤的第一步骤和第二步骤的方法制备丙烯酸金刚烷基酯化合物。 在第一步中，在金属锂存在下，使2-金刚烷酮化合物与烃基卤化物反应，形成金刚烷醇酸盐中间体，然后在第二步中与丙烯酸酯化合物反应，生成目标金刚烷基丙烯酸酯化合物。
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4.发明授权Adamantyl (meth)acrylic monomer and (meth)acrylic polymer containing the same as repeating unit 有权（甲基）丙烯酸单体和含有与重复单元相同的（甲基）丙烯酸聚合物公开(公告)号：US08846840B2
公开(公告)日：2014-09-30
申请号：US13637764
申请日：2011-03-29
IPC分类号： C08F220/18 , C08F220/28 , C07C69/54 , C07C67/48 , C07C67/08 , G03F7/039 , C08F4/04
CPC分类号： C07C69/54 , C07C2603/74 , C08F220/18 , C08F220/28 , G03F7/0397
摘要： Provided according to the present invention are an adamantyl (meth)acrylate represented by formula (1), having a formazin standard turbidity of less than 1.7 NTU (Nephelometric Turbidity Unit) in methylethylketone or tetrahydrofuran, and also a (meth)acrylic copolymer comprising the adamantyl (meth)acrylate as a repeating unit: (in the formula, R1 represents hydrogen or a methyl group; R2 through R4 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group having a carbon number of 1 to 3, an aryl group, an alkoxy group, an aryloxy group, a halogen group, an alkyl halide group, or a hydroxyalkyl group; and n1 represents 0 or 1).
摘要翻译： 根据本发明提供的是由式（1）表示的（甲基）丙烯酸金刚烷酯，甲基乙基酮或四氢呋喃中具有小于1.7NTU（比浊法浊度单位）的甲萘醌标准浊度，以及包含 金刚烷基（甲基）丙烯酸酯作为重复单元：（式中，R1表示氢或甲基; R2至R4各自独立地表示氢原子，羟基，碳数为1至3的烷基， 芳基，烷氧基，芳氧基，卤素基，烷基卤基或羟烷基; n1表示0或1）。
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5.发明申请ADAMANTYL (METH)ACRYLIC MONOMER AND (METH)ACRYLIC POLYMER CONTAINING THE SAME AS REPEATING UNIT 有权丙烯酸（甲基）丙烯酸单体和（甲基）丙烯酸聚合物，含有它们作为重复单元公开(公告)号：US20130023638A1
公开(公告)日：2013-01-24
申请号：US13637764
申请日：2011-03-29
IPC分类号： C07C69/54 , C08F220/68 , C07C67/08 , C08F20/68
CPC分类号： C07C69/54 , C07C2603/74 , C08F220/18 , C08F220/28 , G03F7/0397
摘要： Provided according to the present invention are an adamantyl (meth)acrylate represented by formula (1), having a formazin standard turbidity of less than 1.7 NTU (Nephelometric Turbidity Unit) in methylethylketone or tetrahydrofuran, and also a (meth)acrylic copolymer comprising the adamantyl (meth)acrylate as a repeating unit: (in the formula, R1 represents hydrogen or a methyl group; R2 through R4 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group having a carbon number of 1 to 3, an aryl group, an alkoxy group, an aryloxy group, a halogen group, an alkyl halide group, or a hydroxyalkyl group; and n1 represents 0 or 1).
摘要翻译： 根据本发明提供的是由式（1）表示的（甲基）丙烯酸金刚烷酯，甲基乙基酮或四氢呋喃中具有小于1.7NTU（比浊法浊度单位）的甲萘醌标准浊度，以及包含 金刚烷基（甲基）丙烯酸酯作为重复单元：（式中，R1表示氢或甲基; R2至R4各自独立地表示氢原子，羟基，碳数为1至3的烷基， 芳基，烷氧基，芳氧基，卤素基，烷基卤基或羟烷基; n1表示0或1）。
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公开(公告)号：US08912366B2
公开(公告)日：2014-12-16
申请号：US13988559
申请日：2011-11-15
申请人： Takashi Ouchi , Yoshio Nishimura
发明人： Takashi Ouchi , Yoshio Nishimura
IPC分类号： C07C29/48 , C07C35/44 , B01J23/96 , B01J20/34 , B01J20/16 , B01J20/00 , B01J20/02 , B01J20/04
CPC分类号： C07C29/48 , B01J20/0225 , B01J20/041 , B01J20/048 , B01J20/16 , B01J20/34 , B01J20/3408 , B01J20/3433 , B01J20/3475 , B01J23/462 , B01J23/96 , B01J27/1856 , C07C2603/74 , C07C35/44 , C07C35/37
摘要： The present invention provides a process for preparing an adamantane polyol by reacting an adamantane with a ruthenium compound and a hypochlorite in a biphasic water/organic solvent system. The process includes the steps of adding an inorganic adsorbent to a reaction system; and adding an alkali to a reaction mixture to separate the ruthenium compound together with the inorganic adsorbent, and reusing the separated ruthenium compound and inorganic adsorbent in a subsequent reaction.
摘要翻译： 本发明提供了通过在双相水/有机溶剂体系中使金刚烷与钌化合物和次氯酸盐反应来制备金刚烷多元醇的方法。 该方法包括将无机吸附剂加入到反应体系中的步骤; 并向反应混合物中加入碱以将钌化合物与无机吸附剂一起分离，并在随后的反应中重新使用分离的钌化合物和无机吸附剂。
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7.发明授权Sewing machine and computer-readable recording medium with recorded sewing machine control program 有权缝纫机和计算机可读记录介质，配有记录缝纫机控制程序公开(公告)号：US08146521B2
公开(公告)日：2012-04-03
申请号：US12076627
申请日：2008-03-20
申请人： Yoshinori Nakamura , Hirokazu Hirose , Yoshio Nishimura , Akie Ukai , Satoru Makino , Masaki Shimizu , Kazumi Sai
发明人： Yoshinori Nakamura , Hirokazu Hirose , Yoshio Nishimura , Akie Ukai , Satoru Makino , Masaki Shimizu , Kazumi Sai
IPC分类号： D05B21/00
摘要： A sewing machine that enables a user to perform sewing while moving a piece of work cloth, the sewing machine including: a main shaft that drives a needle bar equipped with a sewing needle, a sewing machine motor that rotary-drives the main shaft, a detection device that detects an actual movement distance of the piece of work cloth, a target pitch storage device that stores a predetermined length as a target pitch, which is a target value of stitch pitches of the piece of work cloth, an agreement degree calculation device that calculates an agreement degree between the target pitch and a stitch pitch in actual sewing that is to be determined based on the actual movement distance of the piece of work cloth which is detected by the detection device; and a notification device that notifies of the agreement degree calculated by the agreement degree calculation device.
摘要翻译： 一种能够使用户在移动一件工布的同时进行缝制的缝纫机，所述缝纫机包括：驱动装有缝纫针的针杆的主轴，旋转驱动主轴的缝纫机马达， 检测工件布的实际移动距离的检测装置，存储作为工件布的针脚间距的目标值的作为目标间距的预定长度的目标俯仰存储装置，协议度计算装置 其根据由所述检测装置检测出的所述工件布的实际移动距离来确定实际缝制中的目标间距和线圈间距之间的一致程度; 以及通知协议书计算装置计算出的协商程度的通知装置。
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8.发明授权Sewing machine and computer-readable recording medium with recorded sewing machine control program 失效缝纫机和计算机可读记录介质，配有记录缝纫机控制程序公开(公告)号：US07836838B2
公开(公告)日：2010-11-23
申请号：US12071368
申请日：2008-02-20
申请人： Satoru Makino , Hirokazu Hirose , Yoshio Nishimura , Masaki Shimizu , Akie Ukai , Yoshinori Nakamura , Kazumi Sai
发明人： Satoru Makino , Hirokazu Hirose , Yoshio Nishimura , Masaki Shimizu , Akie Ukai , Yoshinori Nakamura , Kazumi Sai
摘要： A sewing machine includes a needle bar that is equipped with a sewing needle at a lower end of the needle bar, a presser bar that is equipped with a presser foot at a lower end of the presser bar, which holds down a work cloth, a sewing machine motor which is a driving source that drives the needle bar in an up and down direction, and a switching device that switches between a normal mode in which the needle bar is driven in the up and down direction to form stitches and a practice mode in which the sewing machine is operated in a condition where at least the needle bar is not driven.
摘要翻译： 缝纫机包括在针杆的下端配备缝纫针的针杆，在压脚的下端装有压脚的压脚，压脚压住工布， 缝纫机电动机，其是沿上下方向驱动针杆的驱动源，以及切换装置，其在针杆沿上下方向驱动的正常模式之间切换以形成线圈，并且练习模式 其中缝纫机在至少针杆未被驱动的状态下操作。
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9.发明申请Sewing machine and computer-readable recording medium with recorded sewing machine control program 有权缝纫机和计算机可读记录介质，配有记录缝纫机控制程序公开(公告)号：US20080229991A1
公开(公告)日：2008-09-25
申请号：US12076414
申请日：2008-03-18
申请人： Satoru Makino , Hirokazu Hirose , Yoshio Nishimura , Masaki Shimizu , Akie Ukai , Yoshinori Nakamura , Kazumi Sai
发明人： Satoru Makino , Hirokazu Hirose , Yoshio Nishimura , Masaki Shimizu , Akie Ukai , Yoshinori Nakamura , Kazumi Sai
IPC分类号： D05B19/10
摘要： A sewing machine for a user to perform sewing while moving a work cloth includes: a detecting device that detects the work cloth; a movement calculating device that calculates, by two-dimensional coordinate data, a movement direction and a movement quantity of the work cloth between previous detection and current detection of the work cloth when the work cloth is detected; a movement data storage device that stores movement data serving as two-dimensional coordinate data indicative of the movement direction and the movement quantity; a movement data creating device that detects the work cloth on a one by one needle basis of sewing, calculates the movement data, and stores the calculated data in the movement data storage device; a cloth feed mechanism that moves the work cloth; and a reproduction sewing control device that performs sewing while moving the work cloth based on the movement data stored in the movement data storage device.
摘要翻译： 用于使用者在移动工作时进行缝制的缝纫机包括：检测工作布的检测装置; 运动计算装置，当检测到工布时，通过二维坐标数据计算工布的先前检测和当前检测之间的移动方向和移动量; 运动数据存储装置，存储用作指示运动方向和移动量的二维坐标数据的运动数据; 移动数据生成装置，其以逐个针为基准的缝合检测工布，计算移动数据，并将计算出的数据存储在移动数据存储装置中; 移动工作布的送布机构; 以及再现缝制控制装置，其基于存储在移动数据存储装置中的移动数据，在移动工作布的同时进行缝制。
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10.发明申请Sewing machine and computer-readable recording medium storing sewing machine control program 有权缝纫机和计算机可读记录介质，存储缝纫机控制程序公开(公告)号：US20080210147A1
公开(公告)日：2008-09-04
申请号：US12071372
申请日：2008-02-20
申请人： Hirokazu Hirose , Yoshinori Nakamura , Akie Ukai , Masaki Shimizu , Yoshio Nishimura , Kazumi Sai , Satoru Makino
发明人： Hirokazu Hirose , Yoshinori Nakamura , Akie Ukai , Masaki Shimizu , Yoshio Nishimura , Kazumi Sai , Satoru Makino
IPC分类号： D05B19/10
摘要： A sewing machine that sews a work cloth being moved by a user includes a detection device that detects the work cloth, a movement calculation device that calculates movement data of the work cloth, a movement data storage device that stores the movement data, a movement data creation device that causes the detection device and the movement calculation device to respectively detect the work cloth and calculate the movement data for each stitch, and that stores the movement data into the movement data storage device, a line segment specification device that specifies a line segment based on the movement data, a determination device that determines whether a stitch to be formed next will overlap with an already formed stitch corresponding to the specified line segment, and an error control device that performs an error correction operation based on a determination result.
摘要翻译： 缝制被用户移动的工布的缝纫机包括检测工布的检测装置，计算工布的移动数据的移动计算装置，存储移动数据的移动数据存储装置，移动数据 创建装置，其使所述检测装置和所述移动计算装置分别检测所述工布，并计算每个针迹的移动数据，并将所述移动数据存储到所述移动数据存储装置中;线段指定装置，其指定线段 基于运动数据，确定下一个要形成的针迹是否与已经形成的与指定线段对应的针迹重叠的判定装置，以及基于确定结果执行错误校正操作的错误控制装置。
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