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1.发明授权Catalyst for the selective hydrogenation of aromatic halonitro compounds to aromatic haloamines and a process for its production 失效用于将芳族卤代硝酸化合物选择性氢化成芳族卤代胺的催化剂及其制备方法
公开(公告)号：US5512529A
公开(公告)日：1996-04-30
申请号：US71250
申请日：1993-06-04
IPC分类号： B01J21/18 , B01J23/42 , B01J23/89 , C07B61/00 , C07C209/36 , C07C211/52 , B01J23/72
CPC分类号： B01J23/8926 , C07C209/365
摘要： A modified supported noble metal catalyst is disclosed for the selective hydrogenation of aromatic halonitro compounds to form aromatic haloamines. The support consists of active carbon. The active component is platinum modified with copper. The new catalyst is distinguished by good selectivity and a high yield.
摘要翻译： 公开了用于选择性氢化芳族卤代硝基化合物以形成芳族卤代胺的改性负载型贵金属催化剂。 载体由活性炭组成。 活性组分是用铜改性的铂。 新催化剂的选择性好，产率高。
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2.发明授权
公开(公告)号：US5132452A
公开(公告)日：1992-07-21
申请号：US626422
申请日：1990-12-14
IPC分类号： C07B61/00 , B01J23/644 , C07C51/31 , C07C59/105
CPC分类号： C07C51/313 , B01J23/6447
摘要： A process for making gluconic acid and its alkali metal salts by oxidizing glucose with oxygen or oxygen containing gas in an aqueous alkaline solution in the presence of an activated charcoal supported catalyst containing a platinum group metal component, e.g. platinum and palladium and bismuth wherein the platinum, palladium and bismuth are simultaneously deposited on the charcoal support.
摘要翻译： 在含有铂族金属组分的活性炭负载型催化剂存在下，通过在碱性水溶液中氧化含氧气体或含氧气体的葡萄糖酸及其碱金属盐的方法。 铂和钯和铋，其中铂，钯和铋同时沉积在木炭载体上。
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3.发明授权Process for uniform and reproducible shell impregnation of fixed bed catalyst supports in the form of loose particles 失效固定床催化剂载体以松散颗粒的形式均匀且可再现的壳浸渍方法
公开(公告)号：US5498590A
公开(公告)日：1996-03-12
申请号：US157233
申请日：1993-11-24
IPC分类号： B01J37/02
CPC分类号： B01J37/0223 , B01J37/0232
摘要： A process for uniform and reproducible impregnation of fixed bed catalyst supports in the form of loose particles with a desired shell volume, by applying atomized impregnating solutions of precursors of the catalytically active components onto the heap of catalyst supports circulated in a tank. By suitable selection of the spraying parameters, in particular the droplet size range, the quantity of solvent and the quantity of impregnating solution sprayed per rotation of the tank, the catalyst supports may be provided with shells with an excellent degree of uniformity.
摘要翻译： 通过将催化活性组分的前体的雾化浸渍溶液施加到在罐中循环的催化剂载体的堆上，使具有所需壳体积的松散颗粒形式的固定床催化剂载体均匀且可重复地浸渍的方法。 通过适当选择喷雾参数，特别是液滴尺寸范围，溶剂的量和每个罐的每转喷涂的浸渍溶液的量，催化剂载体可以具有优异的均匀度的壳。
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4.发明授权Metal-containing, shaped polymeric, tertiary and/or secondary organosiloxane amine compounds, method of their production and use 失效含金属，形状的聚合物，仲胺和/或次生有机硅氧烷化合物，其生产和使用方法
公开(公告)号：US5237019A
公开(公告)日：1993-08-17
申请号：US858415
申请日：1992-03-27
IPC分类号： B01J31/06 , B01J31/16 , B01J31/18 , C08G77/38 , C08G77/398 , C08G77/54 , C08G77/58 , C08K3/10 , C08L83/04 , C08L83/08
CPC分类号： C08G77/58 , B01J31/1675 , B01J31/1805 , C08G77/398 , C08G77/54 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828
摘要： Metal-containing, shaped, polymeric, tertiary and/or secondary organosiloxane amine compounds are introduced which contain the metals Pd, Pt, Ru, Rh individually or in combination as well as optional promotors and/or moderators. The organosiloxane amine functioning as carrier for the metals contains the units ##STR1## and/or units ##STR2## in which R.sup.1 to R.sup.5 are a group ##STR3## with R.sup.6 as a double-bonded group bound to N and Si (e.g. an alkylene group) and X is an amine group such as The carrier substance can be cross-linked with cross-linking agents containing Si, Ti, Zr or Al. The metal-containing product is spherical in form and is defined by the parameters of sphere diameter, specific surface and pore volume as well as bulk density. A method of production is disclosed which can be carried out in several variants as well as the use of the metal-containing product as catalyst for hydrogenation reactions and oxidation reactions.
摘要翻译： 引入含金属，成型，聚合，叔和/或次级有机硅氧烷胺化合物，其单独或组合地含有金属Pd，Pt，Ru，Rh以及任选的促进剂和/或调节剂。 有机硅氧烷胺作为载体发挥功能的金属包含单元
和/或单元 （II）其中R 1至R 5是一组 （III）与R6如与N-双键基团 和Si（例如亚烷基），X是胺基，例如载体物质可以与含有Si，Ti，Zr或Al的交联剂交联。 含金属产品的形状为球形，由球体直径，比表面积和孔体积以及堆积密度的参数定义。 公开了一种生产方法，其可以在几种变体中进行，以及使用含金属的产物作为氢化反应和氧化反应的催化剂。 -
5.发明授权Catalyst precursor for an activated raney metal fixed-bed catalyst, an activated raney metal fixed-bed catalyst and a process for its preparation and use, and a method of hydrogenating organic compounds using said catalyst 失效用于活化的金属固定床催化剂的催化剂前体，活化的金属固定床催化剂及其制备和使用方法，以及使用所述催化剂氢化有机化合物的方法
公开(公告)号：US5536694A
公开(公告)日：1996-07-16
申请号：US322290
申请日：1994-10-13
申请人： Peter Schuetz , Roland Burmeister , Bertrand Despeyroux , Hans Moesinger , Helmfried Krause , Klaus Deller
发明人： Peter Schuetz , Roland Burmeister , Bertrand Despeyroux , Hans Moesinger , Helmfried Krause , Klaus Deller
CPC分类号： B01J37/0009 , B01J25/00 , B01J25/02 , B01J35/0026 , B01J35/1014 , B01J35/1038 , B01J35/023
摘要： Shaped, activated Raney metal fixed-bed catalysts are obtained by molding a powder of at least one catalyst alloy, comprising at least one Raney process metal as catalytically active component and a leachable alloy component, and a powder of pure Raney process metal as binder with the addition of a shaping aid and pore-producer and subsequent calcination at temperatures below 850.degree. C. During calcination the shaping aid and pore-producer are burned away. Catalyst alloy powder and binder powder thereby sinter together to give a mechanically stable and porous molded item. This molded item thus consists of particles of catalyst alloys which are bonded by the powder of pure Raney process metal. It has no catalytically inactive, ceramic or glassy binder. The surface layer of the molded item is activated by leaching the leachable alloy component contained in the catalyst alloys with caustic soda solution.
摘要翻译： 成型的活性阮内金属固定床催化剂通过将至少一种催化剂合金的粉末成型为包含至少一种阮内工艺金属作为催化活性组分和可浸出的合金成分而获得，并将纯阮内工艺金属粉末作为粘合剂， 在低于850℃的温度下加入成型助剂和孔隙生产器并随后进行煅烧。在煅烧过程中，成型助剂和孔隙生产者被烧掉。 催化剂合金粉末和粘合剂粉末由此烧结在一起，得到机械稳定且多孔的模制品。 因此，该模制品由由纯阮内工艺金属的粉末结合的催化剂合金颗粒组成。 它没有催化惰性，陶瓷或玻璃状粘合剂。 模制品的表面层通过用苛性钠溶液浸出催化剂合金中所含的可浸出合金组分来活化。
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6.发明授权Catalyst for the production of a glyoxylic acid by catalytic oxidation of glyoxal and method of its production 失效通过乙二醛的催化氧化生产乙醛酸的催化剂及其生产方法
公开(公告)号：US5395965A
公开(公告)日：1995-03-07
申请号：US246402
申请日：1994-05-20
IPC分类号： B01J23/63 , B01J23/652 , C07B61/00 , C07C51/235 , C07C59/153 , B01J21/18 , C07C51/00 , C07C59/00
CPC分类号： B01J23/6525 , B01J23/63 , C07C51/235
摘要： A catalyst containing platinum on carbon as carrier for the catalytic oxidation of glyoxal to glyoxalic acid. Activity and selectivity of the catalyst can be considerably improved by modification with molybdenum and/or cerium.
摘要翻译： 一种催化剂，含有碳载铂，用于将乙二醛催化氧化成乙醛酸。 催化剂的活性和选择性可以通过用钼和/或铈进行改性而大大提高。
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公开(公告)号：US5366938A
公开(公告)日：1994-11-22
申请号：US508564
申请日：1990-04-13
CPC分类号： B01J21/063 , B01J37/0009 , C04B35/46 , C04B38/009 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/108
摘要： Pressed parts based on pyrogenically produced titanium dioxide with the following physico-chemical characteristics:______________________________________ Outer diameter 0.8-15 mm BET surface according 99.5% TiO.sub.2 ______________________________________ They are produced by mixing pyrogenically produced titanium dioxide with urea, graphite and water, compacting the mixture, optionally drying the resulting mass at 80.degree. C. to 120.degree. C. comminuting, subsequently extruding or tabletting to produce pressed parts and tempering the pressed parts at a temperature of 710.degree. C. to 1000.degree. C. for a period of 0.5 to 6 hours. The pressed parts can be used as catalyst or catalytic carrier.
摘要翻译： 基于热解产生的二氧化钛的压制零件，具有以下物理化学特性：-Out直径0.8-15mm -BET表面，根据<1-20m2 / g-至DIN 66131-孔体积0.01-0.29cm 3 / g - 孔 分布无孔<10nm - 至少90％的孔 - 在10-80nm的范围内 - 增强强度30-500N /压制部分-TiO 2相金红石100％ - 复合> 99.5％TiO 2 - 它们由 将热解产生的二氧化钛与尿素，石墨和水混合，将混合物压实，任选地将所得物质在80℃至120℃干燥，粉碎，随后挤出或压片以产生压制部件，并在 710℃至1000℃，时间为0.5至6小时。 压制零件可用作催化剂或催化载体。
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公开(公告)号：US5498585A
公开(公告)日：1996-03-12
申请号：US259677
申请日：1994-06-13
申请人： Karin Bartels , Klaus Deller , Bertrand Despeyroux , Jochen Simon
发明人： Karin Bartels , Klaus Deller , Bertrand Despeyroux , Jochen Simon
IPC分类号： B01J23/42 , B01J27/045 , B01J37/03 , B01J37/20 , C07B61/00 , C07C51/36 , C07C57/30 , C07C209/26
CPC分类号： B01J37/031 , B01J23/42 , B01J27/045 , B01J37/20 , C07C209/26 , C07C51/36
摘要： A sulphidized catalyst which contains platinum on activated carbon is described. The activity of the catalyst can be greatly improved, while retaining the same selectivity, when the platinum-containing impregnation solution contains an oxidizing agent.
摘要翻译： 描述了在活性炭上含有铂的硫化催化剂。 当含铂浸渍溶液含有氧化剂时，可以大大提高催化剂的活性，同时保持相同的选择性。
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9.发明授权Process for preparing hydrogenation catalysts which contain noble metals on activated carbon 失效制备在活性炭上含有贵金属的氢化催化剂的方法
公开(公告)号：US5449655A
公开(公告)日：1995-09-12
申请号：US212725
申请日：1994-03-14
IPC分类号： B01J21/18 , B01J23/40 , B01J37/02 , B01J37/12 , C07B61/00 , C07C51/36 , C07C57/30 , B01J23/38
CPC分类号： C07C51/36 , B01J37/0207 , B01J37/12
摘要： A process is described for preparing hydrogenation catalysts which contain noble metals, having at least one catalytically active component and optionally promoters and/or modifiers on a support consisting of activated carbon washed with nitric acid. The activated carbon is subjected to an oxidative pretreatment with an oxidizing agent before applying the catalytically active components, promoters and modifiers.
摘要翻译： 描述了一种制备含有贵金属的氢化催化剂的方法，所述贵金属具有至少一种催化活性组分，并且在由用硝酸洗涤的活性炭组成的载体上可选地使用助催化剂和/或改性剂。 在施加催化活性组分，助催化剂和改性剂之前，用氧化剂对活性炭进行氧化预处理。
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10.发明授权Shaped articles based on pyrogenically produced titanium dioxide, method of their production and their use 失效基于热解产生的二氧化钛的成型制品，其生产方法及其用途
公开(公告)号：US5231067A
公开(公告)日：1993-07-27
申请号：US773504
申请日：1991-10-09
CPC分类号： B01J21/063 , B01J35/023 , B01J35/1009 , B01J35/1038 , B01J35/1061 , B01J35/1085 , B01J37/0009 , C04B35/46 , C04B38/009 , Y10S502/509
摘要： Pressed parts based on pyrogenically produced titanium dioxide with the following physico-chemical characteristics:______________________________________ Outer diameter 0.8-15 mm BET surface according 99.5% TiO.sub.2 ______________________________________ They are produced by mixing pyrogenically produced titanium dioxide with urea, graphite and water, compacting the mixture, optionally drying the resulting mass at 80.degree. C. to 120.degree. C. comminuting, subsequently extruding or tabletting to produce pressed parts and tempering the pressed parts at a temperature of 710.degree. C. to 1000.degree. C. for a period of 0.5 to 6 hours.The pressed parts can be used as catalyst or catalytic carrier.
摘要翻译： 基于热解产生的二氧化钛的压制零件，具有以下物理化学特性：-Out直径0.8-15mm -BET表面，根据<1-20m2 / g-至DIN 66131-孔体积0.01-0.29cm 3 / g - 孔 分布无孔<10nm - 至少90％的孔 - 在10-80nm的范围内 - 增强强度30-500N /压制部分-TiO 2相金红石100％ - 复合> 99.5％TiO 2 - 它们由 将热解产生的二氧化钛与尿素，石墨和水混合，将混合物压实，任选地将所得物质在80℃至120℃干燥，粉碎，随后挤出或压片以产生压制部件，并在 710℃至1000℃，时间为0.5至6小时。 压制零件可用作催化剂或催化载体。
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